1.沈阳化工大学机械与动力工程学院,辽宁 沈阳 110142
2.沈阳化工大学资源化工与材料教育部重点实验室,辽宁 沈阳 110142
2.鄂尔多斯实验室,内蒙古 鄂尔多斯 017010
张庆瑾(1993—),男,博士研究生,zqj785075@163.com
许光文(1966—),男,博士,教授,gwxu@syuct.edu.cn
白丁荣(1959—),男,博士,教授,drbai@syuct.edu.cn
收稿:2026-06-12,
修回:2026-08-20,
录用:2026-08-21,
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张庆瑾, 郭昊, 付亮亮, 等. 高温煅烧菱镁矿制备烧结镁砂工艺研究进展[J/OL]. 化工学报, 2026.
ZHANG Qingjin, GUO Hao, FU Liangliang, et al. Research progress on preparation of sintered magnesia by high temperature calcination of magnesite[J/OL]. CIESC Journal, 2026.
张庆瑾, 郭昊, 付亮亮, 等. 高温煅烧菱镁矿制备烧结镁砂工艺研究进展[J/OL]. 化工学报, 2026. DOI: 10.11949/0438-1157.20260807.
ZHANG Qingjin, GUO Hao, FU Liangliang, et al. Research progress on preparation of sintered magnesia by high temperature calcination of magnesite[J/OL]. CIESC Journal, 2026. DOI: 10.11949/0438-1157.20260807.
烧结镁砂作为生产碱性耐火材料的基础原料,广泛应用于钢铁、有色、建材、化工等高温工业以及国防军工、航空航天等高科技领域。竖窑高温煅烧菱镁矿制备烧结镁砂工艺存在传热传质速率低、温度分布不均等技术缺陷,导致所生产的烧结镁砂致密性差、能耗高,促使我国高密度优质烧结镁砂高度依赖进口,严重制约了高温工业及高科技产业的发展。为此,本综述在概述高温竖窑煅烧菱镁矿制备烧结镁砂工艺的基础上,分析了煅烧方式、烧结温度、坯料活性、成型压力及添加剂等因素对烧结镁砂致密度的影响;剖析了传统竖窑高温煅烧大球团工艺难以制备高密度烧结镁砂的技术原因,提出了高温流态化技术制备高密度烧结镁砂的新方法;并展望了传统竖窑高温煅烧菱镁矿及高温流态化制备高密度烧结镁砂的未来研究方向,以期为高效、低能耗生产高密度优质烧结镁砂提供理论依据和技术参考。
As a fundamental raw material for basic refractory production
sintered magnesia has been widely utilized in high-temperature industries such as steel
non-ferrous metals
building materials
and chemicals
as well as in defense
aerospace
and other high-tech sectors. The production of sintered magnesia via shaft-kiln calcination of magnesite suffers from inherent technical drawbacks
including low heat and mass transfer rates and non-uniform gas-solid flow and temperature distribution
which lead to poor densification of the final product and excessive energy consumption. These limitations have rendered China heavily dependent on imports of high-density premium sintered magnesia
severely restricting the development of high-temperature industries and advanced manufacturing sectors. To address these challenges
this review first provides an overview of the high-temperature calcination process for sintered magnesia production from magnesite
and then systematically analyzes the effects of calcination mode
sintering temperature
raw material reactivity
compaction pressure
and additives on the densification behavior of sintered magnesia. The underlying technical barriers that hinder the production of high-density sintered magnesia in conventional shaft kilns employing large pellets are critically examined
based on which a novel approach utilizing high-temperature fluidization technology is proposed. Finally
future research directions are outlined for both conventional shaft-kiln calcination and the emerging high-temperature fluidization route
with the aim of providing theoretical basis and technical guidance for the energy-efficient production of high-density premium sintered magnesia.
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