YE Dingding, XIANG Wei, ZHU Xun, et al. Visualization experiments of bubble growth and detachment on catalytic surface in a microchannel[J]. CIESC Journal, 2014, (12): 4678-4683.
YE Dingding, XIANG Wei, ZHU Xun, et al. Visualization experiments of bubble growth and detachment on catalytic surface in a microchannel[J]. CIESC Journal, 2014, (12): 4678-4683.DOI: 10.3969/j.issn.0438-1157.2014.12.005.
A rectangular microchannel was fabricated with polydimethylsiloxane (PDMS) material and MnO2 catalysts were deposited on the wall of the microchannel. The growth and detachment process of oxygen bubbles generated by the catalytic reaction of H2O2 solution were recorded by a high speed camera. The effects of reactant concentration and flow rate on bubble growth rate and detachment diameter were also analyzed. The growth and detachment process of bubbles generated on the catalytic surface in the microchannel occurred periodically. Moreover
the bubble growth consisted of two processes
the initial fast growth process and the later slow growth process. Before 3 s
the generated bubbles were in a fast growth period
and reaction kinetics dominated the process. However
after 3s
reaction rate was controlled by diffusion
resulting in the fact that bubble growth rate increased with increasing reactant concentration. In addition
bubble detachment diameter was slightly affected by reactant concentration
while it was significantly affected by reactant flow rate and dropped linearly as Reynolds number increased.