单螺杆挤出机连续脱硫制备再生胶的结构与性能

吕晓龙; 吕柏源; 黄汉雄; 姜庆岩

doi:10.3969/j.issn.0438-1157.2014.11.057

您当前的位置：

首页 >

文章列表页 >

单螺杆挤出机连续脱硫制备再生胶的结构与性能

材料化学工程与纳米技术 | 更新时间：2025-12-10

- 单螺杆挤出机连续脱硫制备再生胶的结构与性能
- Structure and properties of continuously devulcanized ground tire rubber using independently designed single screw extruder
- 化工学报 2014年第11期页码：4614-4619
- 作者机构：
  
  1. 华南理工大学塑料橡胶装备及智能化研究中心,广东,广州,510640
  2. 青岛科技大学机电工程学院,山东,青岛,266061
- 作者简介：
- 基金信息：
- DOI：10.3969/j.issn.0438-1157.2014.11.057
  中图分类号： Q335+.2
- 网络首发：2014-11-05，
  
  纸质出版：2014-11-05
- 稿件说明：
移动端阅览
吕晓龙, 吕柏源, 黄汉雄, 等. 单螺杆挤出机连续脱硫制备再生胶的结构与性能[J]. 化工学报, 2014,(11):4614-4619.

LÜ Xiaolong, LÜ Baiyuan, HUANG Hanxiong, et al. Structure and properties of continuously devulcanized ground tire rubber using independently designed single screw extruder[J]. CIESC Journal, 2014, (11): 4614-4619.
吕晓龙, 吕柏源, 黄汉雄, 等. 单螺杆挤出机连续脱硫制备再生胶的结构与性能[J]. 化工学报, 2014,(11):4614-4619. DOI： 10.3969/j.issn.0438-1157.2014.11.057.

LÜ Xiaolong, LÜ Baiyuan, HUANG Hanxiong, et al. Structure and properties of continuously devulcanized ground tire rubber using independently designed single screw extruder[J]. CIESC Journal, 2014, (11): 4614-4619. DOI： 10.3969/j.issn.0438-1157.2014.11.057.

摘要

利用本课题组研制的单螺杆挤出机

对废旧轮胎胶(GTR)粉进行连续脱硫制备再生胶(DGTR)

并对DGTR进行再硫化制成DGTR硫化试样.结果显示

随螺杆转速增加

DGTR凝胶含量和DGTR硫化试样交联密度逐渐降低

DGTR硫化试样的拉伸强度和拉断伸长率有所提高;螺杆转速设定为40 r·min-1时

在205℃脱硫温度下取得了最好的脱硫效果

DGTR硫化试样的拉伸强度和拉断伸长率分别约为11 MPa和386%.从红外光谱和光电子能谱的分析结果推测

在单螺杆挤出机的剪切和热等的共同作用下

GTR粉中部分S—S键和C—S键发生了断裂.

Abstract

Using independently designed single screw extruder

ground tire rubber (GTR) powder was devulcanized continuously to prepare devulcanized ground tire rubber (DGTR). The DGTR was further revulcanized to prepare revulcanized DGTR samples. The gel fractions of the DGTR and the crosslink densities of the revulcanized DGTR samples decreased and the tensile strengths and elogations at break of the revulcanized DGTR samples increased gradually with increasing screw speed. The best devulcanization effectiveness was achieved under 40 r·min-1 screw speed and 205℃ devulcanization temperature. The revulcanized DGTR sample prepared under this condition exhibited tensile strength and elogation at break of about 11 MPa and 386% respectively. Inferring from the Fourier transform infrared spectroscopy and X-ray photoelectron spectroscopy analyses

parts of S—S and C—S bonds in the GTR powder were broken under both shearing and heating in the independently designed single screw extruder.

关键词

Keywords

references

浏览量

444

下载量

CSCD

文章被引用时，请邮件提醒。

提交

工具集

关联资源

阳离子淀粉染料吸附材料的制备及表征

氨基功能型离子液体吸收CO2的性能

Ti-Si-O双功能催化吸附材料的汽油光催化-吸附耦合脱硫性能

Zn3-MOF用于硝基苯的高效荧光识别

基于预辐射接枝法的DMAPS改性PVDF超亲水膜的制备及其油/水乳液分离性能