CHEN Yuefang, JI Zhen, LIN Hai, et al. Removal mechanism of emulsified oil in wastewater by biologic materials modified with lauric acid[J]. CIESC Journal, 2014, (6): 2276-2284.
CHEN Yuefang, JI Zhen, LIN Hai, et al. Removal mechanism of emulsified oil in wastewater by biologic materials modified with lauric acid[J]. CIESC Journal, 2014, (6): 2276-2284.DOI: 10.3969/j.issn.0438-1157.2014.06.044.
Oil pollution results in detrimental effects on the environment
living organisms and economy. Currently
a lot of attempt is devoted to provide an efficient
easy and cheap method for cleaning-up oil pollution. To improve the efficiency cleaning-up emulsified oil in wastewater
lauric acid was employed to modify corn cob and peanut shell
and these materials were characterized by scanning electron microscope (SEM)
Brunauer-Emmett-Teller (BET) method and Fourier transform infrared spectrometer (FTIR). The results indicate that the modification of lauric acid is taken place by the esterification reaction between carboxyl in lauric acid and hydroxyl in cellulose
hemicellulose and lignin of biologic materials
and ester group formed is connected to alkyl chain
not only increasing the oleophylic and decreasing hydrophobic property of absorbents
but also creating micro-porosity. So
it can be expected that if the modified materials are employed for removal of emulsified oil
the oil adsorption capacity can be enhanced
because of the combined action of alkyl chain and micro-pore. In order to measure the removal efficiency of emulsified oil
in the present study
petroleum ether is used to extract oil from water sample
and ultraviolet spectroscopy employs for measuring oil concentration. The results show that the oil adsorption capacity is 6.86 mg·g-1 and 5.21 mg·g-1 for raw corn cob and peanut shell
and goes up 10.79 mg·g-1 and 7.44 mg·g-1 for the modified samples by lauric acid
respectively. Therefore
when biologic materials modified by lauric acid are applied to treat emulsified oily water
not only removal efficiency is high
but also the waste is controled by another waste. It is a very environmental protection measure.