TIAN Zhizhang, LI Yifan, JIANG Zhongyi, et al. Facilitated transport membranes for biogas upgrading[J]. CIESC Journal, 2014, (5).DOI: 10.3969/j.issn.0438-1157.2014.05.006.
can be utilized as substitute for natural gas owing to its high calorific value (HCV). Typically biogas contains 60%—65% CH4
35%—40% CO2
small amounts of hydrogen sulfide
water vapor and trace amounts of other gases. Treatment of raw biogas must be implemented in order to convert biogas into HCV biomethane. Membrane separation process exhibits many distinct advantages
including low energy consumption
high efficiency
high process flexibility and environment friendliness. Particularly
facilitated transport membrane exhibits predominant features for biogas upgrading because of its unique transport mechanism. Materials for facilitated transport membrane and corresponding preparation methods/technologies are summarized. Influences of impurities
such as water and hydrogen sulfide on membrane separation as well as some techno- economic issues are discussed. Finally
prospects on membrane separation technology in biogas upgrading are presented.