PAA-g-ZrO<sub>2</sub>复合膜过滤牛血清蛋白过程的污染阻力分析

周守勇; 张艳; 薛爱莲; 王辉; 李梅生; 赵宜江; 邢卫红

doi:10.3969/j.issn.0438-1157.2014.03.027

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PAA-g-ZrO₂复合膜过滤牛血清蛋白过程的污染阻力分析

分离工程 | 更新时间：2025-12-10

- PAA-g-ZrO₂复合膜过滤牛血清蛋白过程的污染阻力分析
- Analysis of fouling resistance of PAA-g-ZrO₂ composite membrane in filtrating BSA solution
- 化工学报 2014年第3期页码：954-959
- 作者机构：
  
  1. 淮阴师范学院化学化工学院, 淮安市新型环境功能材料重点实验室,江苏,淮安,223300
  2. 南京工业大学化学化工学院, 材料化学工程国家重点实验室,江苏,南京,210009
- 作者简介：
  
  周守勇（1973—），男，博士，副教授.
- 基金信息：
- DOI：10.3969/j.issn.0438-1157.2014.03.027
  中图分类号： Q028.8
- 网络首发：2014-03-05，
  
  纸质出版：2014-03-05
- 稿件说明：
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周守勇, 张艳, 薛爱莲, 等. PAA-g-ZrO₂复合膜过滤牛血清蛋白过程的污染阻力分析[J]. 化工学报, 2014,(3):954-959. DOI: 10.3969/j.issn.0438-1157.2014.03.027.

ZHOU Shouyong, ZHANG Yan, XUE Ailian, et al. Analysis of fouling resistance of PAA-g-ZrO₂ composite membrane in filtrating BSA solution[J]. CIESC Journal, 2014, (3): 954-959. DOI: 10.3969/j.issn.0438-1157.2014.03.027.
周守勇, 张艳, 薛爱莲, 等. PAA-g-ZrO₂复合膜过滤牛血清蛋白过程的污染阻力分析[J]. 化工学报, 2014,(3):954-959. DOI: 10.3969/j.issn.0438-1157.2014.03.027. DOI：

ZHOU Shouyong, ZHANG Yan, XUE Ailian, et al. Analysis of fouling resistance of PAA-g-ZrO₂ composite membrane in filtrating BSA solution[J]. CIESC Journal, 2014, (3): 954-959. DOI: 10.3969/j.issn.0438-1157.2014.03.027. DOI：

摘要

通过对PAA-g-ZrO2复合膜过滤牛血清蛋白过程的污染阻力及其分布分析揭示接枝聚丙烯酸（PAA）对ZrO2膜抗污染性能的影响规律。结果表明：PAA-g-ZrO2复合膜和ZrO2膜的总阻力均随着过滤时间的延长而增加，但是PAA-g-ZrO2复合膜总阻力的增加趋势明显低于原ZrO2膜，同时，PAA-g-ZrO2复合膜的内部污染阻力Rif所占比例下降为原ZrO2膜的一半，这表明PAA接枝到ZrO2膜表面明显降低了膜孔内堵塞的内部污染，提高了膜的抗污染和易清洗性能。此外，溶液的pH值对PAA-g-ZrO2复合膜的污染阻力及其分布有着明显影响，当溶液pH值为8.0时，PAA-g-ZrO2复合膜几乎不存在膜孔堵塞污染。

Abstract

Fouling of PAA-g-ZrO2 composite membrane by BSA solution was investigated in conjunction with analysis of membrane total resistances and resistances distribution. The total resistances of the PAA-g-ZrO2 composite membrane and ZrO2 membrane increased with increasing filtration time

but the growth trend of the PAA-g-ZrO2 composite membrane total resistances was lower than that of the ZrO2 membrane. The fouling resistance of the ZrO2 membrane was Rcp (concentration polarization resistance)-dominant

while Rcp and Rm (membrane resistance) controlled the PAA-g-ZrO2 composite membrane separation process. The internal plugging resistance (Rif) of the PAA-g-ZrO2 composite membrane was just half of that of the ZrO2 membrane. The membrane resistance of PAA-g-ZrO2 composite membrane increased with increasing pH. The densely packed brush-shaped structure of the PAA chains was considered to be responsible for reducing the protein adsorption on the membrane surface. Furthermore

the PAA-g-ZrO2 composite membrane displayed high pH-sensitivity for BSA solutions

and could resist protein fouling in high pH applications.

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PAA-g-ZrO2复合膜过滤牛血清蛋白过程的污染阻力分析

Analysis of fouling resistance of PAA-g-ZrO2 composite membrane in filtrating BSA solution

DOI：10.3969/j.issn.0438-1157.2014.03.027

摘要

Abstract

关键词

Keywords

references

PAA-g-ZrO₂复合膜过滤牛血清蛋白过程的污染阻力分析

Analysis of fouling resistance of PAA-g-ZrO₂ composite membrane in filtrating BSA solution