LI Yinglin, TAN Laizai, ZHANG Xiaosong. Simulation of oil-vapor condensing recovery process based on several state equation models[J]. CIESC Journal, 2014, (3): 785-791.
LI Yinglin, TAN Laizai, ZHANG Xiaosong. Simulation of oil-vapor condensing recovery process based on several state equation models[J]. CIESC Journal, 2014, (3): 785-791.DOI: 10.3969/j.issn.0438-1157.2014.03.003.
The selection of state equation for simulation of condensing oil-gas recovery is still questionable. In this study
by establishing the phase equilibrium model and thermodynamic parameter models
simulation results of condensing oil-vapor recovery process are compared. The phase equilibrium model is composed of state equations
substance balance equation
and thermodynamic equilibrium equation
with model iteration steps. State equations include SRK
PR
TJS and ideal-gas state equation. The simulations present following results. (1) The simulation results are verified by existing test data. For TJS equation
average deviations of gas and liquid mole fractions are 4.03% and 3.54%
respectively
meeting the precision requirement. For SRK equation
at mole fractions of component higher than 5%
average deviations of CH4 and C2H6 are 2.8% and 3.5%
respectively
while at mole fractions less than 5%
average deviation of C3H8 is 18.5%
meeting the precision requirement. (2) When the oil-gas mixture is considered as ideal gas
the simulation results differ greatly from those with the real-gas state equations
such as SRK
PR or TJS equation
so for the oil-vapor mixture can not be treated as ideal gas
and SRK and TJS equations are preferred. (3) The simulation results of SRK
PR
TJS and Aspen Plus software are equivalent
while the simulation result of PR model is slightly worse. The mathematical model and simulation analysis on condensing oil-vapor recovery process provide theoretical references for future experiment.