氯甲基笼型倍半硅氧烷改性双酚A环氧树脂性能

谭军; 王华金; 沙宝祥; 韦晓燕; 俞强

doi:10.3969/j.issn.0438-1157.2013.11.052

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氯甲基笼型倍半硅氧烷改性双酚A环氧树脂性能

材料化学工程与纳米技术 | 更新时间：2025-12-10

- 氯甲基笼型倍半硅氧烷改性双酚A环氧树脂性能
- Properties of biphenyl A epoxy resin modified by choromethyl polyhedral silsesquioxane
- 化工学报 2013年第11期页码：4269-4273
- 作者机构：
  
  1. 嘉兴学院生物与化学工程学院,浙江,嘉兴,314001
  2. 嘉兴学院材料与纺织工程学院,浙江,嘉兴,314001
  3. 常州大学材料科学与工程学院,江苏,常州,213164
- 作者简介：
- 基金信息：
- DOI：10.3969/j.issn.0438-1157.2013.11.052
  中图分类号： Q323.5TQ351.47
- 网络首发：2013-11-05，
  
  纸质出版：2013-11-05
- 稿件说明：
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谭军, 王华金, 沙宝祥, 等. 氯甲基笼型倍半硅氧烷改性双酚A环氧树脂性能[J]. 化工学报, 2013,(11):4269-4273.

TAN Jun, WANG Huajin, SHA Baoxiang, et al. Properties of biphenyl A epoxy resin modified by choromethyl polyhedral silsesquioxane[J]. CIESC Journal, 2013, (11): 4269-4273.
谭军, 王华金, 沙宝祥, 等. 氯甲基笼型倍半硅氧烷改性双酚A环氧树脂性能[J]. 化工学报, 2013,(11):4269-4273. DOI： 10.3969/j.issn.0438-1157.2013.11.052.

TAN Jun, WANG Huajin, SHA Baoxiang, et al. Properties of biphenyl A epoxy resin modified by choromethyl polyhedral silsesquioxane[J]. CIESC Journal, 2013, (11): 4269-4273. DOI： 10.3969/j.issn.0438-1157.2013.11.052.

摘要

Abstract

Hybrid epoxy resin composite materials were prepared from choromethyl polyhedral silsesquioxane(CM-POSS)

bisphenol epoxy(E-51)

MeTHPA and TEA.The curing reaction of hybrid epoxy

and mechanical and thermal properties of the cured epoxy were characterized by Fourier transform infrared spectroscopy(FT-IR)

differential scanning calorimetry(DSC)

thermogravimetric analysis(TGA)and heat distortion temperature tester.CM-POSS was connected in cross-linked epoxy resin system by chemical reaction in the curing reaction process.Thermal properties

tensile

bending and impact strengthes of the cured hybrid resin were improved with increased content of CM-POSS.Addition of CM-POSS could make the Tg and rigidity of epoxy resin increase but had little effect on tenacity.

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