层层沉积热处理法制备超薄Cu<sub>3</sub>(BTC)<sub>2</sub>膜

仇龙云; 李力成; 冯新; 付双钦; 张所瀛; 陆小华; 杨祝红

doi:10.3969/j.issn.0438-1157.2013.11.050

您当前的位置：

首页 >

文章列表页 >

层层沉积热处理法制备超薄Cu₃(BTC)₂膜

材料化学工程与纳米技术 | 更新时间：2025-12-10

- 层层沉积热处理法制备超薄Cu₃(BTC)₂膜
- Preparation of ultrathin Cu₃(BTC)₂ film by heat treatment of layer-by-layer deposition
- 化工学报 2013年第11期页码：4255-4261
- 作者机构：
  
  南京工业大学化学化工学院, 材料化学工程国家重点实验室,江苏,南京,210009
- 作者简介：
  
  仇龙云(1988-),女,硕士研究生.
- 基金信息：
  
  国家重点基础研究发展计划项目(2013CB733503);国家自然科学基金项目(21136001,21136004);国家高技术研究发展计划项目(2006AA03Z455)。
- DOI：10.3969/j.issn.0438-1157.2013.11.050
  中图分类号： 647
- 网络首发：2013-11-05，
  
  纸质出版：2013-11-05
- 稿件说明：
移动端阅览
仇龙云, 李力成, 冯新, 等. 层层沉积热处理法制备超薄Cu₃(BTC)₂膜[J]. 化工学报, 2013,(11):4255-4261. DOI: 10.3969/j.issn.0438-1157.2013.11.050.

QIU Longyun, LI Licheng, FENG Xin, et al. Preparation of ultrathin Cu₃(BTC)₂ film by heat treatment of layer-by-layer deposition[J]. CIESC Journal, 2013, (11): 4255-4261. DOI: 10.3969/j.issn.0438-1157.2013.11.050.
仇龙云, 李力成, 冯新, 等. 层层沉积热处理法制备超薄Cu₃(BTC)₂膜[J]. 化工学报, 2013,(11):4255-4261. DOI: 10.3969/j.issn.0438-1157.2013.11.050. DOI：

QIU Longyun, LI Licheng, FENG Xin, et al. Preparation of ultrathin Cu₃(BTC)₂ film by heat treatment of layer-by-layer deposition[J]. CIESC Journal, 2013, (11): 4255-4261. DOI: 10.3969/j.issn.0438-1157.2013.11.050. DOI：

摘要

基于层层沉积法

引入简单易控的热处理方式在玻璃基底表面制备出高结晶度且致密无裂缝的Cu3(BTC)2膜

并详细探讨热处理温度、组装时间和组装溶剂对Cu3(BTC)2成膜的影响。FESEM分析结果显示:膜层的厚度仅为200 nm;热处理有利于获得完整的晶体结构

且高温下膜层不会产生裂纹;组装时间为5 min或10 min

Cu3(BTC)2 颗粒尺寸小且均一。然而

当组装时间延长至20 min

尺寸变得不均一

膜层表面变粗糙;通过改变组装溶剂环境

可以制备出不同维数的晶体膜。

Abstract

Based on layer-by-layer deposition

heat treatment was introduced to prepare continuous and defect-free Cu3(BTC)2 film on glass substrate.The effects of some parameters including heat treatment temperature

assembly time and solvent were investigated with field emission scanning electron microscopy(FESEM).The results showed that film thickness was only about 200 nm which was much thinner than those previously reported.Heat treatment was fantastically beneficial for high crystallinity Cu3(BTC)2 film formation and no crack was found in the film even at a high heat treatment temperature. At the assembly time about 5 min or 10 min

small crystal particles with uniform size were obtained. However

at a longer assembly time of 20 min

particle size became non-uniform

leading to film unevenness. Moreover

by changing the assembly solvent environment

films with different dimensions were formed.

关键词

Keywords

references

浏览量

526

下载量

CSCD

文章被引用时，请邮件提醒。

提交

工具集

关联资源

硅橡胶用纳米二氧化硅表面有机修饰及补强机理研究进展

超疏水、自清洁氟化石墨改性不锈钢网的油水分离研究

不锈钢网负载Al-beta分子筛涂层的制备及其在油水分离中的应用

全氟聚醚分子量及其分布表征研究

带束层结构设计对全钢子午线轮胎硫化特性的影响

层层沉积热处理法制备超薄Cu3(BTC)2膜

Preparation of ultrathin Cu3(BTC)2 film by heat treatment of layer-by-layer deposition

DOI：10.3969/j.issn.0438-1157.2013.11.050

摘要

Abstract

关键词

Keywords

references

层层沉积热处理法制备超薄Cu₃(BTC)₂膜

Preparation of ultrathin Cu₃(BTC)₂ film by heat treatment of layer-by-layer deposition