CO燃烧状况可调的催化裂化装置多稳态分析

王锐; 罗雄麟; 许锋

doi:10.3969/j.issn.0438-1157.2013.08.033

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CO燃烧状况可调的催化裂化装置多稳态分析

过程系统工程 | 更新时间：2025-12-10

- CO燃烧状况可调的催化裂化装置多稳态分析
- Multiple steady states of FCCU with varying CO concentration
- 化工学报 2013年第8期页码：2930-2937
- 作者机构：
  
  中国石油大学自动化研究所,北京,102249
- 作者简介：
  
  王锐(1985- ),男,博士研究生.
- 基金信息：
- DOI：10.3969/j.issn.0438-1157.2013.08.033
  中图分类号： E624
- 网络首发：2013-08-05，
  
  纸质出版：2013-08-05
- 稿件说明：
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王锐, 罗雄麟, 许锋. CO燃烧状况可调的催化裂化装置多稳态分析[J]. 化工学报, 2013,(8):2930-2937.

WANG Rui, LUO Xionglin, XU Feng. Multiple steady states of FCCU with varying CO concentration[J]. CIESC Journal, 2013, (8): 2930-2937.
王锐, 罗雄麟, 许锋. CO燃烧状况可调的催化裂化装置多稳态分析[J]. 化工学报, 2013,(8):2930-2937. DOI： 10.3969/j.issn.0438-1157.2013.08.033.

WANG Rui, LUO Xionglin, XU Feng. Multiple steady states of FCCU with varying CO concentration[J]. CIESC Journal, 2013, (8): 2930-2937. DOI： 10.3969/j.issn.0438-1157.2013.08.033.

摘要

考虑到一氧化碳(CO)助燃剂作为调控系统CO燃烧状况的操作手段会影响催化裂化装置的多稳态

在已有的烧焦罐式高效再生催化裂化装置反应-再生系统动态机理模型的基础上

扩展了再生器内CO燃烧的机理模型

并将CO助燃剂的添加量与再生器内CO的燃烧状态进行定量的关联。在对再生器进行热量衡算的基础上

绘制出再生器的放出-移出热量曲线

确定了系统的3个稳态操作点

并根据放热反应器稳态热稳定性斜率条件分析了稳态点的热稳定性。针对炼厂CO助燃剂添加量设计较为保守的问题

分析了减少助燃剂添加量对系统操作的影响

指出CO助燃剂的添加量会影响到系统两个高温稳态点之间的操作空间从而影响到装置控制系统设计的苛刻度。

Abstract

An improved fluid catalytic cracking unit(FCCU)riser-regenerator model combined with carbon-monoxide(CO)combustion was proposed

since multiple steady states of FCCU would change as CO conversion changed with different amounts of CO combustion promoter added.Due to the conservative consumption of CO combustion promoter which contains Pt as the active component in refineries

the amount of the added combustion promoter would significantly affect the economics.Thus

based on the heat balance of the high-efficiency regenerator

heat generation and removal curves were determined and three steady states were found

two of which were thermally stable satisfying the slope condition.From the analysis of the influence of different amounts of CO promoter on the multiple steady states

it was pointed out that the varying distance between the two high steady states resulting from different amounts of CO combustion promoter added would influence the severity of the control system design.

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