不同淀粉类型TPS/PBS共混体系的形貌与黏弹行为

李纪伟; 罗学刚; 林晓艳; 黄永华

doi:10.3969/j.issn.0438-1157.2013.06.053

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不同淀粉类型TPS/PBS共混体系的形貌与黏弹行为

材料化学工程与纳米技术 | 更新时间：2025-12-10

- 不同淀粉类型TPS/PBS共混体系的形貌与黏弹行为
- Morphology and viscoelastic behavior of PBS/TPS blends containing varying amylose contents
- 化工学报 2013年第6期页码：2300-2305
- 作者机构：
  
  1. 西南科技大学材料科学与工程学院,四川,绵阳,621010
  2. 西南科技大学生物质材料教育部工程研究中心,四川,绵阳,621010
- 作者简介：
  
  李纪伟(1988—),男,硕士研究生.
- 基金信息：
- DOI：10.3969/j.issn.0438-1157.2013.06.053
  中图分类号： K02
- 网络首发：2013-06-05，
  
  纸质出版：2013-06-05
- 稿件说明：
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李纪伟, 罗学刚, 林晓艳, 等. 不同淀粉类型TPS/PBS共混体系的形貌与黏弹行为[J]. 化工学报, 2013,(6):2300-2305.

LI Jiwei, LUO Xuegang, LIN Xiaoyan, et al. Morphology and viscoelastic behavior of PBS/TPS blends containing varying amylose contents[J]. CIESC Journal, 2013, (6): 2300-2305.
李纪伟, 罗学刚, 林晓艳, 等. 不同淀粉类型TPS/PBS共混体系的形貌与黏弹行为[J]. 化工学报, 2013,(6):2300-2305. DOI： 10.3969/j.issn.0438-1157.2013.06.053.

LI Jiwei, LUO Xuegang, LIN Xiaoyan, et al. Morphology and viscoelastic behavior of PBS/TPS blends containing varying amylose contents[J]. CIESC Journal, 2013, (6): 2300-2305. DOI： 10.3969/j.issn.0438-1157.2013.06.053.

摘要

Abstract

Thermoplastic waxy corn starch (WTPS) and maise starch (MTPS) were prepared by melt blending.Furthermore

WTPS/poly (butylenes succinate) (PBS) blends and MTPS/PBS blends were prepared for investigating the effects of starch type on the morphology and viscoelastic behavior of the blends.The results showed that plasticization of waxy corn starch was more easily performed than that of maise starch and WTPS had a lower melt viscosity than that of MTPS.The WTPS/PBS blends had a better homogeneous fracture surface than that of MTPS/PBS blends.When blending ratio of TPS/PBS was 60/40

dynamic rheological behavior of the blends was mainly attributed to TPS phase and MTPS/PBS blends had higher storage modulus and complex viscosity than those of WTPS/PBS blends.When blending ratio of TPS/PBS was 40/60

PBS phase played an important role in dynamic rheological behavior of the blends and the MTPS/PBS blends in low shear rates (ω<1 r·s-1) showed more apparent solid-like dynamic rheological behavior.

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