WANG Weiwen, ZHENG Xiaodan, LI Ping, et al. Synthesis of ultrafine copper chromite black pigment by chemical coprecipitation using SBDS-assisted urea[J]. CIESC Journal, 2013, (5): 1847-1854.
WANG Weiwen, ZHENG Xiaodan, LI Ping, et al. Synthesis of ultrafine copper chromite black pigment by chemical coprecipitation using SBDS-assisted urea[J]. CIESC Journal, 2013, (5): 1847-1854.DOI: 10.3969/j.issn.0438-1157.2013.05.047.
The ultrafine copper chromite black pigment(CuCr2O4)with spinel structure was prepared from chromium and copper nitrates by the chemical coprecipitation method
using sodium dodecyl benzene sulfonate(SDBS)as surface active agent and urea as precipitation agent.The effect of processing parameters
such as precipitation agent
calcination temperature and surface active agent on crystal structure
grain size and morphology of the CuCr2O4 was investigated
and the effect of processing parameters on its tinting strength was discussed.The results showed that urea and SDBS could effectively control grain size
morphology and crystal structure of the pigment.Ultrafine CuCr2O4 300 nm in size and with hexagonal structure was synthesized under the conditions of 400% theoretical amount of urea
5% SDBS and 800℃ of calcination temperature
and exhibited excellent tinting strength compared with commercial samples.