Pt催化丙烷脱氢过程中结焦反应的粒径效应与Sn的作用

李庆; 隋志军; 朱贻安; 周兴贵; Chen De

doi:10.3969/j.issn.0438-1157.2013.02.016

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Pt催化丙烷脱氢过程中结焦反应的粒径效应与Sn的作用

催化、动力学与反应器 | 更新时间：2025-12-10

- Pt催化丙烷脱氢过程中结焦反应的粒径效应与Sn的作用
- Formation of coke on Pt catalysts during propane dehydrogenation: effect of Pt particle size and Sn addition
- 化工学报 2013年第2期页码：524-531
- 作者机构：
  
  1. 华东理工大学,化学工程联合国家重点实验室,上海,200237
  2. 挪威科技大学化学工程系,挪威特隆德霍姆N,7491
- 作者简介：
  
  李庆(1984—),男,博士研究生.
- 基金信息：
- DOI：10.3969/j.issn.0438-1157.2013.02.016
  中图分类号： Q323.8
- 网络首发：2013-02-05，
  
  纸质出版：2013-02-05
- 稿件说明：
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李庆, 隋志军, 朱贻安, 等. Pt催化丙烷脱氢过程中结焦反应的粒径效应与Sn的作用[J]. 化工学报, 2013,(2):524-531.

LI Qing, SUI Zhijun, ZHU Yi, et al. Formation of coke on Pt catalysts during propane dehydrogenation: effect of Pt particle size and Sn addition[J]. CIESC Journal, 2013, (2): 524-531.
李庆, 隋志军, 朱贻安, 等. Pt催化丙烷脱氢过程中结焦反应的粒径效应与Sn的作用[J]. 化工学报, 2013,(2):524-531. DOI： 10.3969/j.issn.0438-1157.2013.02.016.

LI Qing, SUI Zhijun, ZHU Yi, et al. Formation of coke on Pt catalysts during propane dehydrogenation: effect of Pt particle size and Sn addition[J]. CIESC Journal, 2013, (2): 524-531. DOI： 10.3969/j.issn.0438-1157.2013.02.016.

摘要

用乙二醇还原法制备了Pt颗粒平均粒径分别为2.0、4.6、12.1 nm的Pt/Al2O3催化剂

同时用浸渍法制备了PtSn/Al2O3双金属催化剂

并考察了各催化剂在丙烷脱氢过程中的结焦行为。分别用H2化学吸附、透射电镜、热重分析、元素分析、红外光谱、拉曼光谱等手段对催化剂进行了表征。表征结果显示

催化剂金属上的结焦速率与Pt金属颗粒粒径密切相关。具有较小Pt颗粒的催化剂金属上的结焦速率明显大于具有较大Pt颗粒的催化剂。具有较小Pt颗粒的催化剂上生成的焦含有较少的氢

其石墨化程度也较高。本研究中PtSn/Al2O3催化剂金属上的结焦速率高于Pt/Al2O3催化剂

并且在双金属上生成的焦具有更高的石墨化程度。结合Pt/Al2O3催化剂上的结焦机理

对高性能丙烷脱氢催化剂提出了新的概念设计。

Abstract

Pt/Al2O3 catalysts with Pt particle sizes of 2.0

4.6 and 12.1 nm were prepared by the ethylene reduction method and used to study the effect of Pt particle size on coking rate and nature of coke formed.Meanwhile

a PtSn/Al2O3 catalyst was also prepared by the impregnation method in order to elucidate the effect of Sn addition on coking properties of Pt catalyst.The catalysts were characterized by H2 chemisorption

TEM

thermogravimetric analysis

elemental analysis

infrared spectroscopy and Raman spectroscopy

respectively.The experimental results showed that coking rate on Pt metal decreased with increasing size of Pt particle.The coke formed on smaller Pt particles was of higher degree of graphitization and lower content of hydrogen.Moreover

for PtSn/Al2O3 catalyst

its coking rate on Pt metal was higher than that of Pt/Al2O3 catalyst

and the coke formed was also of higher graphitization. Using coke formation mechanism obtained

a conceptual design of catalyst with high performance for propane dehydrogenation was then tentatively proposed.

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