介质阻挡放电等离子体处理载体对CO甲烷化Ni/SiO<sub>2</sub>催化剂性能的改进

赵化龙; 赵彬然; 闫晓亮; 刘媛; 王勇; 刘昌俊

doi:10.3969/j.issn.0438-1157.2013.01.031

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介质阻挡放电等离子体处理载体对CO甲烷化Ni/SiO₂催化剂性能的改进

催化、动力学与反应器 | 更新时间：2025-12-10

- 介质阻挡放电等离子体处理载体对CO甲烷化Ni/SiO₂催化剂性能的改进
- Ni/SiO₂ catalyst for CO methanation with support treated by dielectric barrier discharge plasma
- 化工学报 2013年第1期页码：283-288
- 作者机构：
  
  1. 天津大学化工学院先进纳米技术中心,天津,300072
  2. 北京低碳清洁能源研究所,北京,102209
- 作者简介：
  
  赵化龙(1986—),男,硕士研究生.
- 基金信息：
- DOI：10.3969/j.issn.0438-1157.2013.01.031
  中图分类号： 643
- 网络首发：2013-01-05，
  
  纸质出版：2013-01-05
- 稿件说明：
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赵化龙, 赵彬然, 闫晓亮, 等. 介质阻挡放电等离子体处理载体对CO甲烷化Ni/SiO₂催化剂性能的改进[J]. 化工学报, 2013,(1):283-288. DOI: 10.3969/j.issn.0438-1157.2013.01.031.

ZHAO Hualong, ZHAO Binran, YAN Xiaoliang, et al. Ni/SiO₂ catalyst for CO methanation with support treated by dielectric barrier discharge plasma[J]. CIESC Journal, 2013, (1): 283-288. DOI: 10.3969/j.issn.0438-1157.2013.01.031.
赵化龙, 赵彬然, 闫晓亮, 等. 介质阻挡放电等离子体处理载体对CO甲烷化Ni/SiO₂催化剂性能的改进[J]. 化工学报, 2013,(1):283-288. DOI: 10.3969/j.issn.0438-1157.2013.01.031. DOI：

ZHAO Hualong, ZHAO Binran, YAN Xiaoliang, et al. Ni/SiO₂ catalyst for CO methanation with support treated by dielectric barrier discharge plasma[J]. CIESC Journal, 2013, (1): 283-288. DOI: 10.3969/j.issn.0438-1157.2013.01.031. DOI：

摘要

以经介质阻挡放电等离子体处理的SiO2为载体

用浸渍法制备了Ni/SiO2催化剂

并进行了CO甲烷化反应评价。与载体未经处理的常规Ni/SiO2催化剂相比

载体经处理的催化剂在400℃下的CO与H2转化率均提高了约6%

且在经700℃烧结6 h后

活性仍高于常规催化剂。XRD、TEM和H2-TPR结果表明

载体经处理的催化剂

Ni颗粒粒径更小、粒径分布更集中

Ni与SiO2之间的相互作用更强

证明等离子体处理使SiO2更有利于促进Ni的分散。

Abstract

Ni/SiO2 catalyst was prepared for CO methanation using SiO2 treated by dielectric barrier discharge plasma before impregnation.Compared with the conventional Ni/SiO2 catalyst without the treatment

the CO and H2 conversions at 400℃ were both approximately 6% higher for the support-treated catalyst.After the high temperature reaction at 700℃ for 6 h

the support-treated catalyst was still more active than conventional Ni/SiO2 catalyst.XRD

TEM and H2-TPR results showed that the support-treated catalyst had smaller Ni particle size and stronger interaction between Ni and SiO2

which confirmed that plasma treatment made SiO2 more favorable for Ni dispersion.

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介质阻挡放电等离子体处理载体对CO甲烷化Ni/SiO2催化剂性能的改进

Ni/SiO2 catalyst for CO methanation with support treated by dielectric barrier discharge plasma

DOI：10.3969/j.issn.0438-1157.2013.01.031

摘要

Abstract

关键词

Keywords

references

介质阻挡放电等离子体处理载体对CO甲烷化Ni/SiO₂催化剂性能的改进

Ni/SiO₂ catalyst for CO methanation with support treated by dielectric barrier discharge plasma