LIU Xin, KE Yihu, WANG Yin, et al. Influence of additives on pyrolysis-debromination of NMFs resin in WPCB[J]. CIESC Journal, 2012, (12): 4028-4033.DOI: 10.3969/j.issn.0438-1157.2012.12.041.
Influence of various additives on pyrolysis-debromination of resin in non-metal components(NMFs)in wasted printed circuit boards(WPCB)was investigated.The results show that urea additive can effectively promote removal of Br-containing flame retardant and the formation of gas phase HBr
bromomethane and bromoethane
increase amount of phenol and its derivative in pyrolysis-residue oil; and reduce amount of Br content in solid residue C.However
for DDM(4
4'-diaminodiphenylmethane)additive
although it can promote formation of phenol and its derivative
decrease gas products and increases liquid and solid products
it can not remove Br in NMFs resin of WPCB.For hexamethylenetetramine
in spite of removing Br-containing flame retardant and forming gas phase products such as HBr
methyl bromide
and ethyl bromide
decreases obviously liquid products such as phenol and its derivative
but find large amount of N-methylacetamide and N
N-dimethylformamide in liquid products.Besides
hexamethylenetetramine makes amount of liquid and solid products increase and that of gas products decrease.