酚醛树脂基板真空热解炭制备高性能活性炭

易牡丹; 丘克强

doi:10.3969/j.issn.0438-1157.2012.11.049

您当前的位置：

首页 >

文章列表页 >

酚醛树脂基板真空热解炭制备高性能活性炭

材料化学工程与纳米技术 | 更新时间：2025-12-10

- 酚醛树脂基板真空热解炭制备高性能活性炭
- Preparation of high quality activated carbon from vacuum pyrolysis residue of phenolic resin laminated board
- 化工学报 2012年第11期页码：3716-3722
- 作者机构：
  
  中南大学化学化工学院,湖南,长沙,410083
- 作者简介：
  
  易牡丹(1986-),女,硕士研究生.
- 基金信息：
- DOI：10.3969/j.issn.0438-1157.2012.11.049
  中图分类号： Q424.1
- 网络首发：2012-11-05，
  
  纸质出版：2012-11-05
- 稿件说明：
移动端阅览
易牡丹, 丘克强. 酚醛树脂基板真空热解炭制备高性能活性炭[J]. 化工学报, 2012,(11):3716-3722.

YI Mudan, QIU Keqiang. Preparation of high quality activated carbon from vacuum pyrolysis residue of phenolic resin laminated board[J]. CIESC Journal, 2012, (11): 3716-3722.
易牡丹, 丘克强. 酚醛树脂基板真空热解炭制备高性能活性炭[J]. 化工学报, 2012,(11):3716-3722. DOI： 10.3969/j.issn.0438-1157.2012.11.049.

YI Mudan, QIU Keqiang. Preparation of high quality activated carbon from vacuum pyrolysis residue of phenolic resin laminated board[J]. CIESC Journal, 2012, (11): 3716-3722. DOI： 10.3969/j.issn.0438-1157.2012.11.049.

摘要

以一种全新的物质——阻燃的FR-1型酚醛树脂电路板基板的真空热解炭渣为原料

采用CO2和KOH活化法制备高性能的活性炭。分别研究了CO2活化法中的活化温度和KOH活化法中的碱炭比对活性炭产品性能的影响。用氮气吸附表征了活性炭的孔结构性质

并检测了产品的亚甲基蓝值和碘值。结果表明

KOH活化所得活性炭有更高的亚甲基蓝值(928.3 mg·g-1 vs 231.5 mg·g-1)、碘值(2442.2 mg·g-1 vs 946.6 mg·g-1)、比表面积(2289 m2·g-1 vs 1198 m2·g-1)和孔体积(1.317 cm3·g-1 vs 0.703 cm3·g-1)。所得产品均达到国家一级品标准。用这种原料制备高性能活性炭不仅解决了废弃物资源化的问题

还开发出一种新的、廉价的制备高性能活性炭的原料和方法工艺。

Abstract

Vacuum pyrolysis residue of flame retardant FR-1 phenolic resin laminated board was used to prepare high quality activated carbons(ACs)by CO2 and KOH activation

respectively.The effects of activation temperature by CO2 activation and KOH/char ratio by KOH activation on the properties of obtained ACs were investigated.The pore structures were characterized by N2 adsorption.Methylene blue(MB)and iodine(I2)adsorption capacities were also measured.The results showed that ACs obtained by KOH activation had a higher I2 adsorption value(2442.2 mg穏-1 vs 946.6 mg穏-1)

MB adsorption value(928.3 mg穏-1 vs 231.5 mg穏-1)

specific surface area(2289 m2穏-1 vs 1198 m2穏-1)

and larger total pore volume(1.317 cm3穏-1 vs 0.703 cm3穏-1).All the products reached the national first class standard.A double benefit may be obtained by this study

for it not only achieves the purpose of utilization of pyrolysis residue of waste printed circuit board

but also finds a novel and cheap material for the preparation of high quality ACs.

关键词

Keywords

references

浏览量

410

下载量

CSCD

文章被引用时，请邮件提醒。

提交

工具集

关联资源

活性炭催化热解纤维素协同制备酚类和合成气

9种树叶生物炭作为染料敏化太阳电池对电极的光电性能

过渡金属基氮掺杂炭的构筑及其脱硫性能研究

退役光伏组件TPT背板热氧化降解特性研究

用于软包装生物基聚氨酯胶黏剂的制备及耐水热性能研究