许银. Preparation and activity of Mo-Mn-Al-O catalyst for catalytic wet air oxidation under room conditions[J]. CIESC Journal, 2012, (5): 1415-1421.DOI: 10.3969/j.issn.0438-1157.2012.05.014.
To overcome some drawbacks of catalytic wet air oxidation(CWAO)
higher temperature pressure is required. Mo-Mn-Al-O catalyst was prepared by co-precipitation and impregnation with Mn-Al-O as carrier and molybdate as precursor
and its catalytic activity for degradation of cationic dye wastewater under room temperature and atmospheric pressure was investigated.ICP-OES
BET
XRD and XPS were employed to characterize the Mo-Mn-Al-O catalyst.The results showed that the optimal preparation parameters were as follow:salts concentration was 1.5 mol·L-1
dipping temperature 55℃
calcination time and temperature 3 h and 400℃ respectively.Furthermore
the degradation performance obtained for cationic dyes in wastewater cationic red GTL
cationic red X-GRL
cationic yellow X-GL and cationic blue X-BL showed that the catalytic activity of Mo-Mn-Al-O catalyst was good when amount of Mo-Mn-Al-O catalyst was 2.72 g·L-1
it can be removed 74.8% of cationic red GTL and 64.5% of TOC after 1 h oxidation.