呈和科技股份有限公司,广东 广州 510540
赵文林(1964—),男,高级工程师,zhaowl@gchchem.com
何洁冰(1964—),女,高级工程师,hejb@ gchchem.com
收稿:2019-01-18,
修回:2019-02-20,
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赵文林, 何洁冰. 羧酸金属盐β晶型成核剂合成及应用研究[J]. 化工学报, 2019, 70(S1): 211-216
ZHAO Wenlin, HE Jiebing. Synthesis and application of carboxylic acid metal salt beta crystal nucleating agent[J]. CIESC Journal, 2019, 70(S1): 211-216
赵文林, 何洁冰. 羧酸金属盐β晶型成核剂合成及应用研究[J]. 化工学报, 2019, 70(S1): 211-216 DOI: 10.11949/j.issn.0438-1157.20190062.
ZHAO Wenlin, HE Jiebing. Synthesis and application of carboxylic acid metal salt beta crystal nucleating agent[J]. CIESC Journal, 2019, 70(S1): 211-216 DOI: 10.11949/j.issn.0438-1157.20190062.
研究开发了一种新型的羧酸金属盐β晶型成核剂。此成核剂不仅高效诱导β-PP形成,而且成核效率高
β-成核PP的冲击强度可提高2~4倍,并且大幅提高PP热变形温度,有效缓解了聚丙烯制品的冲击强度和热变形温度二者之间的矛盾。目前已在PPR管材和PPH板材、大注件制品以及锂电池隔膜方面得到广泛的应用。
A new type of carboxylic acid metal salt β-crystalline nucleating agent is developed. It is a new compound. This nucleating agent not only efficiently induces the formation of β-PP
but also has a high nucleation efficiency. The impact strength of β-nucleating PP can be increased by 2 to 4 times
and the heat deformation temperature of PP can be greatly increased. The contradiction between the impact strength and the thermal deformation temperature of polypropylene products is effectively relieved. At present
it has been widely used in PPR tubes and PPH plates
large injection products
and lithium battery diaphragm.
Zhang P , Liu X , Li Y . Influence of β-nucleating agent on the mechanics and crystallization characteristics of polypropylene [J]. Materials Science and Engineering: A, 2 006 , 434 ( 1 / 2 ): 310 - 313 .
Zhang Y F , Luo X Z , Chang Y , et al . Non-isothermal crystallization behaviors of isotactic polypropylene with and without 1, 3: 2, 4-bis( 3, 4-dimethylbenzylidene) sorbitol as a nucleating agent [J]. International Journal of Polymer Analysis and Characterization , 2010 , 15 ( 7 ): 450 - 459 .
谢飞 , 张祥福 , 方舫 , 等 . 成核剂对增韧聚丙烯力学性能的影响 [J]. 中国塑料 , 2000 , 14 ( 11 ): 76 - 80 .
Xie F , Zhang X F , Fang F , et al . Effect of nucleating agent on mechanical properties of toughened polypropylene [J]. China Plastics , 2000 , 14 ( 11 ): 76 - 80 .
Kotek J , Kelnar I , Baldrian J , et al . Tensile behaviour of isotactic polypropylene modified by specific nucleation and active fillers [J]. European Polymer Journal , 2004 , 40 ( 4 ): 679 - 684 .
Varga J . β-Modification of isotactic polypropylene: preparation, structure, processing, properties, and application [J]. Journal of Macromolecular Science , Part B: Physics , 2002 , 41 ( 4 / 5 / 6 ): 1121 - 1171 .
Jones A T , Aizlewood J M , Beckett D R . Crystalline forms of isotactic polypropylene [J]. Macromolecular Chemistry and Physics , 1964 , 75 ( 1 ): 134 - 158
史建公 , 蒋绍洋 , 张敏宏 , 等 . 稀土β聚丙烯成核剂研究及应用进展 [J]. 化工进展 , 2010 , 29 ( 5 ): 854 - 860
Shi J G , Jiang S Y , Zhang M H , et al . Progress in research and application of rare earth beta polypropylene nucleating agent [J]. Chemical Industry and Engineering Progress , 2010 , 29 ( 5 ): 854 - 860
Papageorgiou D G , Chrissafis K , Bikiaris D N . β-Nucleated polypropylene: processing, properties and nanocomposites [J]. Polymer Reviews , 2015 , 55 ( 4 ): 596 - 629 .
Chen Y , Zhong G , Wang Y , et al . Unusual tuning of mechanical properties of isotactic polypropylene using counteraction of shear flow and β-nucleating agent on β-form nucleation [J]. Macromolecules , 2009 , 42 ( 12 ): 4343 - 4348 .
Zhu J , Ni H , Liao X , et al . Preparation and crystallization property of ternary composites of WBG/AA-RCC /PP [J/OL]. Journal of Chemistry , 2015 [ 2015 - 11 - 12 ]. http: / /dx . doi . org / 10 . 1155 / 2015 / 545016 .
Xiao W C , Wu P Y , Feng J C , et al . Influence of a novel β-nucleating agent on the structure, morphology, and nonisothermal crystallization behavior of isotactic polypropylene [J]. Journal of Applied Polymer Science , 2009 , 111 ( 2 ): 1076 - 1085 .
Xiao W , Wu P , Feng J . Effect of β-nucleating agents on crystallization and melting behavior of isotactic polypropylene [J]. Journal of Applied Polymer Science , 2008 , 108 ( 5 ): 3370 - 3379 .
Luo F , Wang K , Ning N , et al . Dependence of mechanical properties on β-form content and crystalline morphology for β-nucleated isotactic polypropylene [J]. Polymers for Advanced Technologies , 2011 , 22 ( 12 ): 2044 - 2054 .
Mohmeyer N , Schmidt H , Kristiansen P M , et al . Influence of chemical structure and solubility of bisamide additives on the nucleation of isotactic polypropylene and the improvement of its charge storage properties [J]. Macromolecules , 2006 , 39 ( 17 ): 5760 - 5767 .
Li Z , Liu Y , Nie M , et al . Self-assembly behavior of aryl amide nucleating agent under supercritical carbon dioxide and its influence on polypropylene [J]. Polymer-Plastics Technology and Engineering , 2017 , 56 ( 18 ): 1937 - 1941 .
Beck H N . Heterogeneous nucleating agents for polypropylene crystallization [J]. Journal of Applied Polymer Science , 1967 , 11 ( 5 ): 673 - 685 .
Zhang Y , Guo L , Chen H , et al . Properties and crystallization behaviors of isotactic polypropylene under action of an effective nucleating agent [J]. Journal of Macromolecular Science , Part B: Physics , 2015 , 54 ( 9 ): 1019 - 1028 .
Jiang C , Zhao S , Xin Z . Influence of a novel β-nucleating agent on the structure, mechanical properties, and crystallization behavior of isotactic polypropylene [J]. Journal of Thermoplastic Composite Materials , 2015 , 28 ( 5 ): 610 - 629 .
Cai Z , Zhao S , Shen B , et al . The effect of bicyclo[2.2.1]hept-5-ene-2, 3-dicarboxylate on the mechanical properties and crystallization behaviors of isotactic polypropylene [J]. Journal of Applied Polymer Science , 2010 , 116 ( 2 ): 792 - 800
Varga J . Supermolecular structure of isotactic polypropylene [J]. Journal of Materials Science , 1992 , 27 ( 10 ): 2557 - 2579 .
Lotz B , Wittmann J C , Lovinger A J . Structure and morphology of poly(propylenes): a molecular analysis [J]. Polymer , 1996 , 37 ( 22 ): 4979 - 4992 .
Awaya H . Morphology of different types of isotactic polypropylene spherulites crystallized from melt [J]. Polymer , 1988 , 29 ( 4 ): 591 - 596 .
Zhang Y , Xin Z . Non-isothermal crystallization kinetics of isotactic polypropylene modified by substituted aromatic heterocyclic phosphates as nucleating agent [J]. Petrochemical Technology , 2007 , 36 ( 1 ): 35 - 39 .
Feng Y , Jin X , Hay J N . Effect of nucleating agent addition on crystallization of isotactic polypropylene [J]. Journal of Applied Polymer Science , 2015 , 69 ( 10 ): 2089 - 2095 .
Nagasawa S , Fujimori A , Masuko T , et al . Crystallisation of polypropylene containing nucleators [J]. Polymer , 2005 , 46 ( 14 ): 5241 - 5250 .
Wang K F , Mai K C . Development of nucleated polynopylene [J]. China Synthetic Resin and Plastics , 1999 , 16 ( 6 ): 49 - 52 .
Zhang Y F , Xin Z . Effects of substituted aromatic heterocyclic phosphate salts on properties, crystallization, and melting behaviors of isotactic polypropylene [J]. Journal of Applied Polymer Science , 2010 , 100 ( 6 ): 4868 - 4874 .
Zhang G P , Yu J Y , Xin Z , et al . Crystallization kinetics of nucleated polypropylene with organic phosphates [J]. Journal of Macromolecular Science Part B , 2003 , 42 ( 3 / 4 ): 663 - 675 .
Zhang J . Effects of an organic phosphorus nucleating agent on crystallization behaviors and mechanical properties of poly(propylene) [J]. Polymeric Materials Science & Engineering , 2010 , 88 ( 2 ): 117 - 120 .
Tordjeman P , Robert C , Marin G , et al . The effect of α, β crystalline structure on the mechanical properties of polypropylene [J]. European Physical Journal E , 2001 , 4 ( 4 ): 459 - 465 .
Zhao S , Cai Z , Xin Z . A highly active novel β-nucleating agent for isotactic polypropylene [J]. Polymer , 2008 , 49 ( 11 ): 2745 - 2754 .
Shi Y Q , Xin Z . Adjustment of stiffness and toughness of isotactic polypropylene based on α/β compound nucleating agents [J]. Petrochemical Technology , 2011 , 40 ( 6 ): 608 - 613 .
Ozawa T . Kinetics of non-isothermal crystallization [J]. Polymer , 1971 , 12 ( 3 ): 150 - 158 .
Chuah K P , Gan S N , Chee K K . Determination of Avrami exponent by differential scanning calorimetry for non-isothermal crystallization of polymers [J]. Polymer , 1999 , 40 ( 1 ): 253 - 259 .
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