多孔胺基化氧化石墨烯基材料对CO<sub>2</sub>的吸附性能研究

刘亚敏; 彭蕾; 苏凤英; 王湘湘; 黄艺真; 林在春; 喻晓静; 裴义山

doi:10.11949/j.issn.0438-1157.20190018

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多孔胺基化氧化石墨烯基材料对CO₂的吸附性能研究

材料化学工程与纳米技术 | 更新时间：2026-07-24

- 多孔胺基化氧化石墨烯基材料对CO₂的吸附性能研究
- Study of CO₂ adsorption on amine functionalized graphene oxide porous materials
- 化工学报 2019年70卷第5期页码：91570400-91570408
- 作者机构：
  
  1.福建工程学院生态环境与城市建设学院，福建福州 350118
  2.福建省室内环境工程技术研究中心，福建福州 350118
- 作者简介：
  
  及第一作者：刘亚敏（1972—），男，博士，副教授，mingjing2000@126.com
- 基金信息：
  
  福建省自然科学基金项目(2017J01472，2019J01061133);福建工程学院科研启动基金项目(GY-Z0872)
- DOI：10.11949/j.issn.0438-1157.20190018
  中图分类号： TQ 465.92
- 收稿：2019-01-07，
  
  修回：2019-03-01，
  
  网络首发：2026-07-24，
  
  纸质出版：2019-05-05
- 稿件说明：
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刘亚敏, 彭蕾, 苏凤英, 王湘湘, 黄艺真, 林在春, 喻晓静, 裴义山. 多孔胺基化氧化石墨烯基材料对CO₂的吸附性能研究[J]. 化工学报, 2019, 70(5): 2016-2024 DOI: 10.11949/j.issn.0438-1157.20190018.

LIU Yamin, PENG Lei, SU Fengying, WANG Xiangxiang, HUANG Yizhen, LIN Zaichun, YU Xiaojing, PEI Yishan. Study of CO₂ adsorption on amine functionalized graphene oxide porous materials[J]. CIESC Journal, 2019, 70(5): 2016-2024 DOI: 10.11949/j.issn.0438-1157.20190018.
刘亚敏, 彭蕾, 苏凤英, 王湘湘, 黄艺真, 林在春, 喻晓静, 裴义山. 多孔胺基化氧化石墨烯基材料对CO₂的吸附性能研究[J]. 化工学报, 2019, 70(5): 2016-2024 DOI: 10.11949/j.issn.0438-1157.20190018. DOI：

LIU Yamin, PENG Lei, SU Fengying, WANG Xiangxiang, HUANG Yizhen, LIN Zaichun, YU Xiaojing, PEI Yishan. Study of CO₂ adsorption on amine functionalized graphene oxide porous materials[J]. CIESC Journal, 2019, 70(5): 2016-2024 DOI: 10.11949/j.issn.0438-1157.20190018. DOI：

摘要

以乙二胺(EDA)、二乙烯三胺(DETA)、四乙烯五胺(TEPA)、聚乙烯亚胺(PEI)等多胺基化合物为

表面改性剂，氧化石墨烯(GO)材料为载体，采用嫁接法辅以超声处理制备了表面胺基功能化多孔吸附材料，用于CO

气体的吸附捕集。所制备的多孔吸附材料孔径约为1.35~4.34 nm，比表面积约为98.032~210.465 m

/g。制备的四种吸附材料中，以PEI功能化吸附材料对CO

的吸附容量最大，70℃下达到了1.5 mmol/g，且经过20次循环吸附/脱附实验后，其CO

吸附量基本不变。吸附过程的吸附等温线线型为Ⅰ型优惠型，另外吸附实验数据与Avrami模型模拟结果符合性较好。

Abstract

adsorbents were prepared by chemical grafting ethylenediamine(EDA)

diethylenetriamine(DETA)

tetraethylenepentamime(TEPA)

and polyethyleneimine(PEI) onto surface of graphene oxide combined with the ultrasound treatment. The pore diameter of amine functionalized GO is 1.35—4.34 nm

and the surface area is 98.032—210.465 m

/g. Among the four amine functionalized GO

the PEI functionalized GO has the largest CO

adsorption capacity

reaching 1.5 mmol/g at 70°C. Besides

the adsorbent also exhibited stable cyclic adsorption-regeneration performance with almost unchanged adsorption capacity after 20 cycles. The type of isothermal adsorption line is type Ⅰ

and the Avrami simulation results agree well with the adsorption experimental data.

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references

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多孔胺基化氧化石墨烯基材料对CO2的吸附性能研究

Study of CO2 adsorption on amine functionalized graphene oxide porous materials

DOI：10.11949/j.issn.0438-1157.20190018

摘要

Abstract

关键词

Keywords

references

多孔胺基化氧化石墨烯基材料对CO₂的吸附性能研究

Study of CO₂ adsorption on amine functionalized graphene oxide porous materials