煤矸石和赤泥协同提取氧化铝过程矿相转变研究

郭玉梅; 曹丽琼; 郭彦霞; 燕可洲

doi:10.11949/j.issn.0438-1157.20181367

您当前的位置：

首页 >

文章列表页 >

煤矸石和赤泥协同提取氧化铝过程矿相转变研究

能源和环境工程 | 更新时间：2026-07-24

- 煤矸石和赤泥协同提取氧化铝过程矿相转变研究
- Mineral transformation in process of combined extraction of alumina from coal gangue and red mud
- 化工学报 2019年70卷第4期页码：1542-1549
- 作者机构：
  
  1.山西低附加值煤基资源高值利用协同创新中心，山西大学资源与环境工程研究所，山西太原 030006
  2.山西煤炭职业技术学院，山西太原 030001
- 作者简介：
  
  郭玉梅(1964—)，女，副教授，gym641117@sohu.com
  郭彦霞（1976—），女，博士，教授，guoyx@sxu.edu.cn
- 基金信息：
  
  山西省煤基低碳科技重大专项(MC2016-05);国家重点研发计划项目(2017YFB0603101);山西省高等学校中青年拔尖创新人才支持计划
- DOI：10.11949/j.issn.0438-1157.20181367
  中图分类号： TQ 17
- 收稿：2018-11-18，
  
  修回：2019-01-04，
  
  网络首发：2020-06-15，
  
  纸质出版：2019-04-12
- 稿件说明：
移动端阅览
郭玉梅, 曹丽琼, 郭彦霞, 燕可洲. 煤矸石和赤泥协同提取氧化铝过程矿相转变研究[J]. 化工学报, 2019, 70(4): 1542-1549

GUO Yumei, CAO Liqiong, GUO Yanxia, YAN Kezhou. Mineral transformation in process of combined extraction of alumina from coal gangue and red mud[J]. CIESC Journal, 2019, 70(4): 1542-1549
郭玉梅, 曹丽琼, 郭彦霞, 燕可洲. 煤矸石和赤泥协同提取氧化铝过程矿相转变研究[J]. 化工学报, 2019, 70(4): 1542-1549 DOI： 10.11949/j.issn.0438-1157.20181367.

GUO Yumei, CAO Liqiong, GUO Yanxia, YAN Kezhou. Mineral transformation in process of combined extraction of alumina from coal gangue and red mud[J]. CIESC Journal, 2019, 70(4): 1542-1549 DOI： 10.11949/j.issn.0438-1157.20181367.

摘要

开展了煤矸石和赤泥协同提取氧化铝研究，考察了添加赤泥对煤矸石活化提取氧化铝及对助剂碳酸钠消耗量的影响，并利用TG-DSC和XRD研究了赤泥添加对煤矸石活化过程的影响。结果表明，“煤矸石-赤泥-Na

”混合样中氧化铝的溶出率随Na/Al摩尔比和煅烧温度的增加而增加，在Al/Si摩尔比为1的条件下，当Na/Al摩尔比为1.2、煅烧温度为850℃时，混合样的氧化铝溶出率可达到91.7%，与碳酸钠直接活化煤矸石相比，碳酸钠消耗量可降低77.9%。TG-DSC和XRD的结果表明，煤矸石、赤泥以及碳酸钠在低于700℃时相互作用比较弱，在高于800℃时三者发生相互作用，赤泥的加入由于调整了样品中的Al/Si摩尔比，使反应的最终物相选择性地向Na∶Al∶Si摩尔比为1∶1∶1的霞石和沸石相转化。

Abstract

Combined extraction of alumina from coal gang

ue and red mud was studied. The effect of red mud on the alumina extraction of coal gangue and the consumption of Na

was investigated. The effect of the red mud on the activation process of coal gangue by Na

calcination was studied by way of TG-DSC and XRD. The results showed that the dissolution of alumina for the mixed “coal gangue-red mud-Na

” sample increased with the Na/Al molar ratio and the calcination temperature. The alumina dissolution of the mixed sample reached 91.7% when the Na/Al molar ratio was 1.2 and the calcination temperature was 850℃ at the Al/Si molar ratio of 1. The consumption of Na

decreased 77.9% at this condition by comparison with that of coal gangue activated directly by Na

. The results of TG-DSC and XRD showed that the interactions among coal gangue

red mud and Na

were weak at

700℃ and were strengthened at

800℃. The addition of red mud would make the phases in the mixed sample selectively transformed into nepheline and zeolite with a Na∶Al∶Si molar ratio of 1∶1∶1 owing to the adjustment of the Al/Si molar ratio of the sample.

关键词

Keywords

references

国家发展改革委 . 中国资源综合利用年度报告 [J ] . 中国经贸导刊 , 2014 , 30 ( 10 ): 49 - 56 .

National Development and Reform Commission . Annual report on comprehensive utilization of resources in China [J ] . China Economic and Trade Guide , 2014 , 30 ( 10 ): 49 - 56 .

田秀青 , 杨凤玲 , 马志斌 , 等 . 气氛对煤矸石中矿物质高温碳热还原反应的影响 [J ] . 硅酸盐通报 , 2018 , 37 ( 4 ): 1370 - 1376 .

Tian X Q , Yang F L , Ma Z B , et al . Effect of atmosphere on the carbothermal reduction reaction of mineral matters in coal gangue at high temperature [J ] . Bulletin of the Chinese Ceramic Society , 2018 , 37 ( 4 ): 1370 - 1376 .

李庆文 , 张向东 , 李桂秀 , 等 . 自燃煤矸石轻骨料混凝土碳化深度研究 [J ] . 环境工程学报 , 2016 , 10 ( 5 ): 2616 - 2620 .

Li Q W , Zhang X D , Li G X , et al . Study on carbonation depth of spontaneous combustion coal gangue lightweight aggregate concrete [J ] . Chinese Journal of Enviromental Engineering , 2016 , 10 ( 5 ): 2616 - 2620 .

曹艳芝 , 郭少青 , 翟晋栋 . 煤矸石中汞和砷的赋存形态研究 [J ] . 煤田地质与勘探 , 2017 , 45 ( 1 ): 26 - 30 .

Cao Y Z , Guo S Q , Zhai J D . The mode of occurrence of mercury and arsenic in coal gangues [J ] . Coal Geology & Exploration , 2017 , 45 ( 1 ): 26 - 30 .

徐岩 , 彭德强 , 刘静宇 , 等 . 影响煤矸石中氧化铝浸出效果的因素探索 [J ] . 选煤技术 , 2018 , ( 1 ): 20 - 22 .

Xu Y , Peng D Q , Liu J Y , et al . Study on the factors affecting the leaching-out of alumina from coal refuse [J ] . Coal Preparation Technology , 2018 , ( 1 ): 20 - 22 .

Cui L , Guo Y X , Wang X M , et al . Dissolution kinetics of aluminum and iron from coal mining waste by hydrochloric acid [J ] . Chinese Journal of Chemical Engineering , 2015 , 23 ( 3 ): 590 - 596 .

Qiao X C , Si P , Yu J G . A systematic investigation into the extraction of aluminum from coal spoil through kaolinite [J ] . Environmental Science & Technology , 2008 , 42 ( 22 ): 8541 - 8546 .

刘博 , 刘墨祥 , 陈晓平 . 用废弃煤矸石制备高比表面积的SiO 2 -Al 2 O 3 二元复合气凝胶 [J ] . 化工学报 , 2017 , 68 ( 5 ): 2096 - 2104 .

Liu B , Liu M X , Chen X P . Preparation of SiO 2 -Al 2 O 3 composite aerogel with high specific surface area by sol-gel method from coal gangue [J ] . CIESC Journal , 2017 , 68 ( 5 ): 2096 - 2104 .

王凯功 , 王飞 . 煤矸石提取氧化铝技术的进展 [J ] . 矿产综合利用 , 2018 , ( 5 ): 21 - 24 .

Wang K G , Wang F . Technology development of alumina extraction from coal gangue [J ] . Multipurpose Utilization of Mineral Resources , 2018 , ( 5 ): 21 - 24 .

Cheng F Q , Cui L , Miller J D , et al . Aluminum leaching from calcined coal waste using hydrochloric acid solution [J ] . Mineral Processing & Extractive Metallurgy Review , 2012 , 33 ( 6 ): 391 - 403 .

Guo Y X , Yan K Z , Cui L , et al . Improved extraction of alumina from coal gangue by surface mechanically grinding modification [J ] . Powder Technology , 2016 , 302 ( 11 ): 33 - 41 .

司鹏 , 乔秀臣 , 于建国 . 机械力化学效应对高岭石铝氧多面体的影响 [J ] . 武汉理工大学学报 , 2011 , 33 ( 5 ): 22 - 26 .

Si P , Qiao X C , Yu J G . Influence of mechanochemical effect on Al-(O, OH) polyhedron of kaolinite [J ] . Journal of Wuhan University of Technology , 2011 , 33 ( 5 ): 22 - 26 .

胡芳华 , 王万绪 , 杨效益 , 等 . 活化煤矸石离子溶出特性初探 [J ] . 煤炭转化 , 2008 , 31 ( 4 ): 98 - 101 .

Hu F H , Wang W X , Yang X Y , et al . Ions dissolving properties of activated coal gangue [J ] . Coal Conversion , 2008 , 31 ( 4 ): 98 - 101 .

崔莉 , 郭彦霞 , 曹丽琼 , 等 . 活化煤矸石酸浸过程中金属离子的溶出 [J ] . 煤炭转化 , 2016 , 39 ( 3 ): 86 - 91 .

Cui L , Guo Y X , Cao L Q , et al . Dissolution of metal ions from avtivated coal gangue in HCl leaching process [J ] . Coal Conversion , 2016 , 39 ( 3 ): 86 - 91 .

纪利春 , 相亚军 , 任根宽 . 酸碱联合法从低温活化煤矸石提取硅铝铁 [J ] . 非金属矿 , 2014 , 37 ( 3 ): 12 - 14 .

Ji L C , Xiang Y J , Ren G K . Extraction of iron and aluminum and silicon from low-temperature activated coal gangue with acid and alkafi combination method [J ] . Non-Metallic Mines , 2014 , 37 ( 3 ): 12 - 14 .

Guo Y X , Yan K Z , Li Y Y , et al . Effect of Na 2 CO 3 additive on the activation of coal gangue for alumina extraction [J ] . International Journal of Mineral Processing , 2014 , 131 ( 10 ): 51 - 57 .

郭彦霞 , 方莉 , 程芳琴 , 等 . 一种从粉煤灰中提取氧化铝和白炭黑的方法 : 201310038565.4 [P ] . 2013-04-24 .

Guo Y X , Fang L , Cheng F Q , et al . A method for extracting alumina and silica from fly ash : 201310038565.4 [P ] . 2013-04-24 .

程芳琴 , 郭彦霞 , 崔莉 , 等 . 利用赤泥活化处理煤矸石和/或粉煤灰的方法 : 201310337154.5 [P ] . 2013-12-04 .

Cheng F Q , Guo Y X , Cui L , et al . Activation method of coal gangue and / or fly ash by the addition of red mud : 201310337154.5 [P ] . 2013-12-04 .

Guo Y X , Zhao Q , Li Y Y , et al . Novel process for alumina extraction via the coupling treatment of coal gangue and bauxite red mud [J ] . Industrial Engineering Chemistry＆Research , 2014 , 53 ( 11 ): 4518 - 4521 .

Zhou C , Liu G , Yan Z , et al . Transformation behavior of mineral composition and trace elements during coal gangue combustion [J ] . Fuel , 2012 , 97 ( 7 ): 644 - 650 .

Ptáček P , Šoukal F , Opravil T , et al . The kinetics of Al-Si spinel phase crystallization from calcined kaolin [J ] . Journal of Solid State Chemistry , 2010 , 183 ( 11 ): 2565 - 2569 .

Cao Z , Cao Y D , Dong H J , et al . Effect of calcination condition on the microstructure and pozzolanic activity of calcined coal gangue [J ] . International Journal of Mineral Processing , 2016 , 146 : 23 - 28 .

Ptáček P , Opravil T , Šoukal F , et al . The influence of structure order on the kinetics of dehydroxylation of kaolinite [J ] . Journal of Europian Ceramirica Society , 2013 , 33 ( 13/14 ): 2793 - 2799 .

Li L X , Zhang Y M , Zhang Y F , et al . The thermal activation process of coal gangue selected from Zhungeer in China [J ] . Journal of Thermal Analysis and Calorimetry , 2016 , 126 ( 3 ): 1559 - 1566 .

Zhang Y Y , Zhang Z Z , Zhu M M , et al . Interactions of coal gangue and pine sawdust during combustion of their blends studied using differential thermogravimetric analysis [J ] . Bioresource Technology , 2016 , 214 : 396 - 403 .

Wu C , Liu D . Mineral phase and physical properties of red mud calcined at different temperatures [J ] . Journal of Nanomaterials , 2012 , Article ID 628592 .

Agatzini-Leonardou S , Oustadakis P , Tsakiridis P E , et al . Titanium leaching from red mud by diluted sulfuric acid at atmospheric pressure [J ] . Journal of Hazardous Material , 2008 , 157 ( 2/3 ): 579 - 586 .

Wang P , Liu D Y . Physical and chemical properties of sintering red mud and bayer red mud and the implications for beneficial utilization [J ] . Materials , 2012 , 5 : 1800 - 1810 .

Zhang N , Sun H , Liu X , et al . Early-age characteristics of red mud-coal gangue cementitious material [J ] . Journal of Hazardous Material , 2009 , 167 ( 1/2/3 ): 927 - 932 .

Pascual J , Corpas F A , López-Beceiro J , et al . Thermal characterization of a spanish red mud [J ] . Journal of Thermal Analysis and Calorimetry , 2009 , 96 ( 2 ): 407 - 412 .

Atasoy A . An investigation on characterization and thermal analysis of the aughinish red mud [J ] . Journal of Thermal Analysis and Calorimetry , 2005 , 81 : 357 - 361 .

浏览量

下载量

CSCD

文章被引用时，请邮件提醒。

提交

工具集

关联资源

用废弃煤矸石制备高比表面积的SiO2-Al2O3二元复合气凝胶

K-B-Al体系对磷矿熔融特性及玻璃结构的影响

常温条件下赤泥同时脱硫脱硝实验研究

煤矸石中有价关键金属活化提取研究进展

煤矸石/粉煤灰对赤泥钠化还原焙烧反应的影响机制