外部环流反应精馏塔的分散控制方案设计

陈海胜; 王腾飞; 黄克谨; 苑杨; 钱行; 张亮

doi:10.11949/j.issn.0438-1157.20181356

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外部环流反应精馏塔的分散控制方案设计

过程系统工程 | 更新时间：2026-07-24

- 外部环流反应精馏塔的分散控制方案设计
- Decentralized control system designs for reactive distillation columns with external recycle
- 化工学报 2019年70卷第2期页码：440-449
- 作者机构：
  
  北京化工大学信息科学与技术学院，北京 100029
- 作者简介：
  
  陈海胜（1986—），男，博士，副教授，chenhs@mail.buct.edu.cn
  黄克谨（1963—），男，博士，教授，huangkj@mail.buct.edu.cn
- 基金信息：
  
  国家自然科学基金项目(21576014;21676011;21878011;21808007;61573052)
- DOI：10.11949/j.issn.0438-1157.20181356
  中图分类号： TQ 021.8
- 收稿：2018-11-16，
  
  修回：2018-11-28，
  
  网络首发：2020-06-16，
  
  纸质出版：2019-02-05
- 稿件说明：
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陈海胜, 王腾飞, 黄克谨, 苑杨, 钱行, 张亮. 外部环流反应精馏塔的分散控制方案设计[J]. 化工学报, 2019, 70(2): 440-449

CHEN Haisheng, WANG Tengfei, HUANG Kejin, YUAN Yang, QIAN Xing, ZHANG Liang. Decentralized control system designs for reactive distillation columns with external recycle[J]. CIESC Journal, 2019, 70(2): 440-449
陈海胜, 王腾飞, 黄克谨, 苑杨, 钱行, 张亮. 外部环流反应精馏塔的分散控制方案设计[J]. 化工学报, 2019, 70(2): 440-449 DOI： 10.11949/j.issn.0438-1157.20181356.

CHEN Haisheng, WANG Tengfei, HUANG Kejin, YUAN Yang, QIAN Xing, ZHANG Liang. Decentralized control system designs for reactive distillation columns with external recycle[J]. CIESC Journal, 2019, 70(2): 440-449 DOI： 10.11949/j.issn.0438-1157.20181356.

摘要

对于具有最不利相对挥发度排序（即反应物为最轻和最重组分，生成物为中间组分）的四元反应分离物系而言，在反应精馏塔的顶部和底部之间引入外部环流能够提高系统的反应分离效率，从而大幅度地降低系统的能量消耗和固定投资成本。以理想四元可逆放热反应的分离为例，研究了外部环流反应精馏塔的分散控制方案的设计问题。结果表明外部环流的引入提高了系统的反应速率，使得外部环流反应精馏塔的闭环控制效果更好（与传统反应精馏塔相比），对干扰的处理能力更强。另外，由于外部环流反应精馏塔比常规反应精馏塔有更多的操作变量（即外部环流流量），利用该变量对出料浓度进行控制，可以进一步提高系统的闭环控制效果。

Abstract

For a quaternary reaction separation system having the most unfavorable relativ

e volatility order (

i.e.

the reactant is the lightest and heaviest component

the product is the intermediate component)

an external is introduced between the top and bottom of the reactive distillation column. The seperation for an hypothetic ideal reversible exothermic reaction was taken as an illustrative example to study the problem of the decentralized control system designs. The results show that the reactive distillation columns with a top-bottom external recycle has better closed-loop control performance and stronger controll ability in the face of large disturbances as compared to the conventianal reactive distillation columns due to the fact that the introducing of external recycle enhance the system reaction rate. In addition

the processes have more operating valuable (

the external recycle flow rate) compared to conventianal reactive distillation columns; therefore

one can utilize the extra operating valuable to control the product purity. The unique control system can further enhance process closed-loop control performance.

关键词

Keywords

references

高鑫 , 赵悦 , 李洪 , 等 . 反应精馏过程耦合强化技术基础与应用研究述评 [J ] . 化工学报 , 2018 , 69 ( 1 ): 218 - 238 .

Gao X , Zhao Y , Li H , et al . Review of basic and application investigation of reactive distillation technology for process intensification [J ] . CIESC Journal , 2018 , 69 ( 1 ): 218 - 238 .

Segovia-hernandez J G , Hernandez S , Petriciolet A B . Reactive distillation: a review of optimal design using deterministic and stochastic techniques [J ] . Chem. Eng. Processing , 2015 , 97 : 134 - 143 .

Kiss A A . Distillation technology-still young and full of breakthrough opportunities [J ] . J. Chem. Tech. Bio. , 2014 , 89 ( 4 ): 479 - 498 .

Kumar M V P , Kaistha N . Decentralized control of a kinetically controlled ideal reactive distillation column [J ] . Chem. Eng. Sci. , 2008 , 63 ( 1 ): 228 - 243 .

Hung S B , Lee M J , Tang Y T , et al . Control of different reactive distillation configurations [J ] . AIChE Journal , 2006 , 52 ( 4 ): 1423 - 1440 .

Kaymak D B , Unlu H , Ofkeli T . Control of a reactive distillation column with double reactive sections for two-stage consecutive reactions [J ] . Chem. Eng. Processing , 2016 , 113 : 86 - 93 .

Cao Y , Huang K J , Yuan Y , et al . Dynamics and control of reactive distillation columns with double reactive sections: feed-splitting influences [J ] . Ind. Eng. Chem. Res. , 2017 , 56 ( 28 ): 8029 - 8040 .

Chen H S , Huang K J , Liu W , et al . Enhancing mass and energy integration by external recycle in reactive distillation columns [J ] . AIChE Journal , 2013 , 59 ( 6 ): 2015 - 2032 .

Chen H S , Huang K J , Zhang L , et al . Reactive distillation columns with a top-bottom external recycle [J ] . Ind. Eng. Chem. Res. , 2012 , 51 ( 44 ): 14473 - 14488 .

Zhang L , Chen H S , Yuan Y , et al . Adopting feed splitting in design of reactive distillation columns with two reactive sections [J ] . Chem. Eng. Processing. , 2015 , 89 : 9 - 18 .

Chen H S , Zhang L , Huang K J , et al . Reactive distillation columns with two reactive sections: feed splitting plus external recycle [J ] . Chem. Eng. Processing , 2016 , 108 : 189 - 196 .

Yao X H , Huang K J , Chen H S , et al . Employing top-bottom recycled reactive distillation to the separations of adipic acid and glutaric acid esterifications [J ] . Ind. Eng. Chem. Res. , 2013 , 52 ( 47 ): 16870 - 16879 .

陈海胜 , 黄克谨 , 王韶锋 . 一种新型的双环流反应蒸馏塔 [J ] . 中国科技论文 , 2013 , 8 ( 12 ): 1277 - 1281 .

Chen H S , Huang K J , Wang S F . A novel reactive distillation column with two external recycles [J ] . China Science Paper , 2013 , 8 ( 12 ): 1277 - 1281 .

Yu N , Li L M , Chen M Q , et al . Novel reactive distillation process with two side streams for dimethyl adipate production [J ] . Chem. Eng. Processing , 2017 , 118 : 9 - 18 .

Tung S T , Yu C C . Effects of relative volatility ranking to the design of reactive distillation [J ] . AIChE Journal , 2007 , 53 ( 5 ): 1278 - 1297 .

Niu M W , Rangaiah G P . Process retrofitting via intensification: a heuristic methodology and its application to isopropyl alcohol process [J ] . Ind. Eng. Chem. Res. , 2016 , 55 ( 12 ): 3614 - 3629 .

Long N V D , Lee M Y . Review of retrofitting distillation columns using thermally coupled distillation sequences and dividing wall columns to improve energy efficiency [J ] . J. Chem. Eng. Jap. , 2014 , 47 ( 2 ): 87 - 108 .

Luyben W L , Yu C C . Reactive Distillation Design and Control [M ] . New York : John Wiley & Sons Inc ., 2008 : 15 - 36 .

Kaymak D B , Luyben W L . Evaluation of a two-temperature control structure for a two-reactant/two-product type of reactive distillation column [J ] . Chem. Eng. Sci. , 2006 , 61 ( 13 ): 4432 - 4450 .

Kumar M V P , Kaistha N . Decentralized control of a kinetically controlled ideal reactive distillation column [J ] . Chem. Eng. Sci. , 2008 , 63 ( 1 ): 228 - 243 .

Kaymak D B , Yilmaz D , Gurer A Z . Effect of relative volatilities on inferential temperature control of reactive distillation columns [J ] . Ind. Eng. Chem. Res. , 2011 , 50 ( 13 ): 8138 - 8152 .

Mathew A K , Kaistha N , Kumar M V P . Control of quaternary ideal endothermic reactive distillation with and without internal heat integration [J ] . Chem. Eng. Tech. , 2016 , 39 ( 4 ): 775 - 785 .

Al-Arfaj M , Luyben W L . Comparison of alternative control structures for an ideal two-product reactive distillation column [J ] . Ind. Eng. Chem. Res. , 2000 , 39 ( 47 ): 3298 - 3307 .

Kumar M V P , Kaistha N . Reactive distillation column design for controllability: a case study [J ] . Chem. Eng. Processing , 2009 , 48 ( 2 ): 606 - 616 .

Sharma N , Singh K . Control of reactive distillation column: a review [J ] . Int. J. Chem. React. , 2010 , 8 ( R5 ): 1 - 55 .

陈镭 , 孙炜 . 反应精馏法生产醋酸丁酯动态模拟 [J ] . 广东化工 , 2015 , 42 ( 1 ): 5 - 8 .

Chen L , Sun W . Dynamic simulation of reactive distillation synthesis of butyl acetate [J ] . Guangdong Chem. Ind. , 2015 , 42 ( 1 ): 5 - 8 .

李洪 , 孟莹 , 李鑫钢 , 等 . 乙酸戊酯酯化反应精馏过程系统控制模拟及分析 [J ] . 化工进展 , 2015 , 34 ( 12 ): 4165 - 4171 .

Li H , Meng Y , Li X G , et al . Dynamic simulation and analysis of reactive distillation column for production of amyl acetate [J ] . Chem. Ind. Eng. Progress , 2015 , 34 ( 12 ): 4165 - 4171 .

Al-Arfaj M , Luyben W L . Comparative control study of ideal and methyl acetate reactive distillation [J ] . Chem. Eng. Sci. , 2002 , 57 ( 24 ): 5039 - 5050 .

Mansouri S S , Huusom J K , Gani R , et al . Systematic integrated process design and control of binary element reactive distillation processes [J ] . AIChE Journal , 2016 , 62 ( 9 ): 3137 - 3154 .

Luyben W L . Distillation Design and Control Using AspenTM Simulation [M ] . New York : John Wiley & Sons Inc ., 2013 : 166 - 172 .

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