MnO<italic style="font-style: italic"><sub>x</sub></italic>/ZrO<sub>2</sub>催化剂制备及催化臭氧氧化降解甲基橙

于海斌; 刘强; 周立坤; 陈赞; 罗超; 张贯艳; 乔利娜; 王建杰

doi:10.11949/j.issn.0438-1157.20181346

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MnO_x/ZrO₂催化剂制备及催化臭氧氧化降解甲基橙

催化、动力学与反应器 | 更新时间：2026-07-24

- MnO_x/ZrO₂催化剂制备及催化臭氧氧化降解甲基橙
- Preparation of MnO_x/ZrO₂ catalyst and catalytic ozonation degradation of methylorange
- 化工学报 2019年70卷第4期页码：1436-1445
- 作者机构：
  
  1.河北工业大学化工学院，天津 300132
  2.中海油天津化工研究设计院有限公司，天津 300131
  3.天津大学化工学院，天津 300072
- 作者简介：
  
  于海斌（1970—），男，教授级高级工程师，yuhaibin9227@163.com
- 基金信息：
  
  天津市科技计划项目(18YFZCSF01440)
- DOI：10.11949/j.issn.0438-1157.20181346
  中图分类号： TQ 028.8
- 收稿：2018-11-15，
  
  修回：2019-02-27，
  
  网络首发：2020-06-15，
  
  纸质出版：2019-04-12
- 稿件说明：
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于海斌, 刘强, 周立坤, 陈赞, 罗超, 张贯艳, 乔利娜, 王建杰. MnO_x/ZrO₂催化剂制备及催化臭氧氧化降解甲基橙[J]. 化工学报, 2019, 70(4): 1436-1445 DOI: 10.11949/j.issn.0438-1157.20181346.

YU Haibin, LIU Qiang, ZHOU Likun, CHEN Zan, LUO Chao, ZHANG Guanyan, QIAO Lina, WANG Jianjie. Preparation of MnO_x/ZrO₂ catalyst and catalytic ozonation degradation of methylorange[J]. CIESC Journal, 2019, 70(4): 1436-1445 DOI: 10.11949/j.issn.0438-1157.20181346.
于海斌, 刘强, 周立坤, 陈赞, 罗超, 张贯艳, 乔利娜, 王建杰. MnO_x/ZrO₂催化剂制备及催化臭氧氧化降解甲基橙[J]. 化工学报, 2019, 70(4): 1436-1445 DOI: 10.11949/j.issn.0438-1157.20181346. DOI：

YU Haibin, LIU Qiang, ZHOU Likun, CHEN Zan, LUO Chao, ZHANG Guanyan, QIAO Lina, WANG Jianjie. Preparation of MnO_x/ZrO₂ catalyst and catalytic ozonation degradation of methylorange[J]. CIESC Journal, 2019, 70(4): 1436-1445 DOI: 10.11949/j.issn.0438-1157.20181346. DOI：

摘要

以商品化ZrO

为载体，采用等体积浸渍法制备MnO

/ZrO

催化剂，对目标污染物甲基橙溶液进行催化臭氧降解效果研究。比较不同焙烧温度（350、400、500和550℃）、不同MnO

负载量（5%、10%、15%和18%）等制备条件对催化剂活性的影响，结果表明：在400℃，MnO

负载量为15%时，催化剂对催化臭氧降解甲基橙溶液表现出最好的活性。反应进行60 min后，甲基橙溶液的脱色率达92.8%，较单独臭氧氧化提高了36.1%。催化剂15%MnO

/ZrO

（400℃）的酸碱使用范围（pH为2.7、6.5、8.7、10.8）实验表明：甲基橙溶液不同初始pH条件同样会影响催化剂的活性，且pH=2.7时表现出最好的催化效果，甲基橙脱色率可达95%。循环实验表明，15%MnO

/ZrO

（400℃）具有较好的稳定性，催化剂循环使用三次后，甲基橙溶液脱色率仍保持在85%以上，且活性组分的流失是降低催化剂活性的一个重要原因。

Abstract

The MnO

/ZrO

catalyst was prepared by the equal volume impregnation method with commercial ZrO

as carrier

and the catalytic ozone degradation effect of the target pollutant methyl orange solution was studied. The factors of calcination temperature and MnO

loading content were studied to determine the optimal catalyst preparation condition. It turned out that

the catalyst would get

the best catalytic activity with 15% MnO

loading and being calcined at 400℃

and the decolorization efficiency of methyl orange was 92.8% over the catalyst of 15%MnO

/ZrO

(400℃)

which increased by 36.1% compared with that in the ozonation without catalyst after 60 min of reaction. Also

the initial pH of methyl orange solution (pH =2.7

6.5

8.7

10.8) was investigated during the catalytic ozonation process. The 15%MnO

/ZrO

(400℃) catalyst performed a higher catalytic efficiency of 95% at pH=2.7 than that value of 6.5 without adjustment by acid or alkali. The catalyst cycle test showed a better stability for 15%MnO

/ZrO

(400℃)

and the decolorization rate of methyl orange slightly drop down to about 85% after three times reuse. Moreover，the loss of MnO

was an important reason for the descent of catalyst activity by characterization experiments.

关键词

Keywords

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MnOx/ZrO2催化剂制备及催化臭氧氧化降解甲基橙

Preparation of MnOx/ZrO2 catalyst and catalytic ozonation degradation of methylorange

DOI：10.11949/j.issn.0438-1157.20181346

摘要

Abstract

关键词

Keywords

references

MnO_x/ZrO₂催化剂制备及催化臭氧氧化降解甲基橙

Preparation of MnO_x/ZrO₂ catalyst and catalytic ozonation degradation of methylorange