乙炔加氢制乙烯浆态床反应器的CFD模拟

苏武; 石孝刚; 吴迎亚; 高金森; 蓝兴英

doi:10.11949/j.issn.0438-1157.20181245

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乙炔加氢制乙烯浆态床反应器的CFD模拟

过程系统工程 | 更新时间：2026-07-24

- 乙炔加氢制乙烯浆态床反应器的CFD模拟
- CFD simulation on hydrogenation of acetylene to ethylene in slurry bed
- 化工学报 2019年70卷第5期页码：1858-1867
- 作者机构：
  
  中国石油大学（北京）重质油国家重点实验室，北京 102249
- 作者简介：
  
  苏武（1993—），男，博士研究生，suwucup@163.com
  蓝兴英（1977—），女，博士，教授，lanxy@cup.edu.cn
- 基金信息：
  
  国家自然科学基金项目(21622609，21808239)
- DOI：10.11949/j.issn.0438-1157.20181245
  中图分类号： TQ 021.1
- 收稿：2018-10-22，
  
  修回：2019-02-21，
  
  网络首发：2026-07-24，
  
  纸质出版：2019-05-05
- 稿件说明：
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苏武, 石孝刚, 吴迎亚, 高金森, 蓝兴英. 乙炔加氢制乙烯浆态床反应器的CFD模拟[J]. 化工学报, 2019, 70(5): 1858-1867

SU Wu, SHI Xiaogang, WU Yingya, GAO Jinsen, LAN Xingying. CFD simulation on hydrogenation of acetylene to ethylene in slurry bed[J]. CIESC Journal, 2019, 70(5): 1858-1867
苏武, 石孝刚, 吴迎亚, 高金森, 蓝兴英. 乙炔加氢制乙烯浆态床反应器的CFD模拟[J]. 化工学报, 2019, 70(5): 1858-1867 DOI： 10.11949/j.issn.0438-1157.20181245.

SU Wu, SHI Xiaogang, WU Yingya, GAO Jinsen, LAN Xingying. CFD simulation on hydrogenation of acetylene to ethylene in slurry bed[J]. CIESC Journal, 2019, 70(5): 1858-1867 DOI： 10.11949/j.issn.0438-1157.20181245.

摘要

对浆态床反应器中乙炔加氢制乙烯过程进行了模拟研究，采用TFM-PBM耦合方法描述浆态床内气相与浆态相的流动，并耦合乙炔加氢反应动力学建立流动-反应综合模型。通过小试实验对该模型进行验证，并将验证后的模型应用于浆态床中试装置中内构件作用机制与操作条件影响的模拟分析。结果表明，在浆态床反应器放大时，可通过设置竖管内构件，以破碎气泡，抑制气相径向运动，使乙炔加氢过程均匀、充分地进行。乙炔加氢制乙烯过程与气相停留时间和反应温度密切相关，在反应器放大中需严格控制温度，并可通过改变反应器内液位高度实现对气相停留时间的调控，从而可在保证乙炔充分转化的同时获得更高的乙烯选择性。

Abstract

The simulation of hydrogenation of acetylene in slurry reactor was carried out. The TFM-PBM coupling method was used to describe the flow of gas phase and slurry phase in slurry bed

and the kinetics of acetylene hydrogenation reaction was coupled to establish flow-reaction synthesis. The model was validated in a lab-scale slurry bed reactor and was then applied to the simulation of a bench-scale slurry bed reactor with respect to the function mechanisms of internals and the effects of operating conditions. Simulation results showed that vertical tube in the bench-scale reactor can break up bubbles and suppress the radial flow of gas phase

which benefits the uniform and sufficient conversion of acetylene. The conversion of acetylene is closely related to the residence time of gas phase and the reaction temperature. In order to obtain complete conversion of acetylene and high selectivity of ethylene when the slurry bed reactor was scaled-up to an industrial scale

it is critical to control the reaction temperature and the residence time of gas phase which can be regulated by changing the height of the liquid phase.

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references

段东红 , 刘世斌 , 李一兵 , 等 . 一种乙炔加氢制乙烯的浆态床工艺及其装置: 102489225A [P ] . 2011-12-10 .

Duan D H , Liu S B , Li Y B , et al . A slurry bed reactor for the selective hydrogenation of acetylene: 102489225A [P ] . 2011-12-10 .

陈艳君 , 陈吉祥 . 乙炔选择加氢催化剂研究进展 [J ] . 化学工业与工程 , 2017 , 34 ( 4 ): 18 - 26 .

Chen Y J , Chen J X . Advances in catalysts for selective hydrogenation of acetylene [J ] . Chemical Industry and Engineering , 2017 , 34 ( 4 ): 18 - 26 .

张东平 , 王功华 . 乙炔加氢反应器的模拟与分析 [J ] . 石油化工 , 2003 , 32 ( 5 ): 414 - 417 .

Zhang D P , Wang G H . Simulation and analysis of reactor for selective hydrogenation of acetylene [J ] . Petrochemical Technology , 2003 , 32 ( 5 ): 414 - 417 .

Borodzinski A , Cybulski A . The kinetic model of hydrogenation of acetylene–ethylene mixtures over palladium surface covered by carbonaceous deposits [J ] . Applied Catalysis A: General , 2000 , 198 ( 1 / 2 ): 51 - 66 .

Sarkany A . Formation of C 4 oligomers in hydrogenation of acetylene over Pd/Al 2 O 3 and Pd/TiO 2 catalysts [J ] . Reaction Kinetics and Catalysis Letters , 2001 , 74 ( 2 ): 299 - 307 .

Edvinsson R K , Holmgren A M , Irandoust S . Liquid-phase hydrogenation of acetylene in a monolithic catalyst reactor [J ] . Industrial & Engineering Chemistry Research , 1995 , 34 ( 1 ): 94 - 100 .

Ruta M , Laurenczy G , Dyson P J , et al . Pd nanoparticles in a supported ionic liquid phase: highly stable catalysts for selective acetylene hydrogenation under continuous-flow conditions [J ] . The Journal of Physical Chemistry C , 2008 , 112 ( 46 ): 17814-17819 .

Herrmann T , Rößmann L , Lucas M , et al . High-performance supported catalysts with an ionic liquid layer for the selective hydrogenation of acetylene [J ] . Chemical Communications , 2011 , 47 ( 45 ): 12310-12312 .

Shitova N B , Shlyapin D A , Afonasenko T N , et al . Liquid-phase hydrogenation of acetylene on the Pd/sibunit catalyst in the presence of carbon monoxide [J ] . Kinetics and Catalysis , 2011 , 52 ( 2 ): 251 - 257 .

余海鹏 , 史雪君 , 刘周恩 , 等 . 用于乙炔选择性加氢制乙烯的浆态床反应器及反应系统: 104826558A [P ] . 2015-08-05 .

Yu H P , Shi X J , Liu Z E , et al . A slurry bed reactor and reaction system for the selective hydrogenation of acetylene: 104826558A [P ] . 2015-08-05 .

Hou R J , Wang T F , Lan X C . Enhanced selectivity in the hydrogenation of acetylene due to the addition of a liquid phase as a selective solvent [J ] . Industrial & Engineering Chemistry Research , 2013 , 52 ( 37 ): 13305-13312 .

Hou R J , Lan X C , Wang T F . Selective hydrogenation of acetylene on Pd/SiO 2 in bulk liquid phase: a comparison with solid catalyst with ionic liquid layer (SCILL) [J ] . Catalysis Today , 2015 , 251 : 47 - 52 .

余牛杰 . 浆态床高浓度乙炔选择加氢合成乙烯的研究 [D ] . 太原 : 太原理工大学 , 2012 .

Yu N J . Study on the performance of slurry reactor for ethylene synthesis by selective hydrogenation of acetylene [D ] . Taiyuan : Taiyuan University of Technology , 2012 .

Wang T F , Wang J F , Jin Y . Slurry reactors for gas-to-liquid processes: a review [J ] . Industrial & Engineering Chemistry Research , 2007 , 46 ( 18 ): 5824 - 5847 .

卢佳 . 浆态床费托合成反应器二维分布模型 [D ] . 杭州 : 浙江大学 , 2010 .

Lu J . Two-dimensional model of the slurry bubble column reactor for Fischer-Tropsch synthesis [D ] . Hangzhou : Zhejiang University , 2010 .

Xu L J , Xia Z H , Guo X F , et al . Application of population balance model in the simulation of slurry bubble column [J ] . Industrial & Engineering Chemistry Research , 2014 , 53 ( 12 ): 4922 - 4930 .

Pan H , Chen X Z , Liang X F , et al . CFD simulations of gas-liquid-solid flow in fluidized bed reactors—a review [J ] . Powder Technology , 2016 , 299 : 235 - 258 .

Li H , Prakash A . Influence of slurry concentrations on bubble population and their rise velocities in a three-phase slurry bubble column [J ] . Powder Technology , 2000 , 113 ( 1 / 2 ): 158 - 167 .

Wang T F , Wang J F , Jin Y . Theoretical prediction of flow regime transition in bubble columns by the population balance model [J ] . Chemical Engineering Science , 2005 , 60 ( 22 ): 6199 - 6209 .

Ekambara K , Nandakumar K , Joshi J B . CFD simulation of bubble column reactor using population balance [J ] . Industrial & Engineering Chemistry Research , 2008 , 47 ( 21 ): 8505 - 8516 .

Wang T F , Wang J F , Jin Y . Population balance model for gas-liquid flows: influence of bubble coalescence and breakup models [J ] . Industrial & Engineering Chemistry Research , 2005 , 44 ( 19 ): 7540 - 7549 .

Guo X F , Zhou Q , Li J , et al . Implementation of an improved bubble breakup model for TFM-PBM simulations of gas–liquid flows in bubble columns [J ] . Chemical Engineering Science , 2016 , 152 : 255 - 266 .

Chen P , Sanyal J , Dudukovic M P . CFD modeling of bubble columns flows: implementation of population balance [J ] . Chemical Engineering Science , 2004 , 59 ( 22 / 23 ): 5201 - 5207 .

Laborde-Boutet C , Larachi F , Dromard N , et al . CFD simulation of bubble column flows: investigations on turbulence models in RANS approach [J ] . Chemical Engineering Science , 2009 , 64 ( 21 ): 4399 - 4413 .

Tomiyama A . Struggle with computational bubble dynamics [J ] . Multiphase Science and Technology , 1998 , 10 ( 4 ): 369 - 405 .

Bhole M R , Joshi J B , Ramkrishna D . CFD simulation of bubble columns incorporating population balance modeling [J ] . Chemical Engineering Science , 2008 , 63 ( 8 ): 2267 - 2282 .

Tomiyama A , Tamai H , Zun I , et al . Transverse migration of single bubbles in simple shear flows [J ] . Chemical Engineering Science , 2002 , 57 ( 11 ): 1849 - 1858 .

Fleischer C , Becker S , Eigenberger G . Detailed modeling of the chemisorption of CO 2 into NaOH in a bubble column [J ] . Chemical Engineering Science , 1996 , 51 ( 10 ): 1715 - 1724 .

邢楚填 . 鼓泡床反应器实验研究及CFD-PBM耦合模型数值模拟 [D ] . 北京 : 清华大学 , 2014 .

Xing C T . Experimental study and numerical simulation of bubble column with a CFD-PBM coupled model [D ] . Beijing : Tsinghua University , 2014 .

Luo H , Svendsen H F . Theoretical model for drop and bubble breakup in turbulent dispersions [J ] . AIChE Journal , 1996 , 42 ( 5 ): 1225 - 1233 .

Luo H . Coalescence, breakup and liquid circulation in bubble column reactors [D ] . Trondheim : Norwegian University of Science and Technology , 1993 .

王功华 . 乙炔加氢动力学研究及反应器模拟计算 [D ] . 北京 : 北京化工大学 , 2003 .

Wang G H . Simulation and kinetic study of hydrogenation acetylene of acetylene [D ] . Beijing : Beijing University of Chemical Technology , 2014 .

Kumar S B , Moslemian D , Duduković M P . Gas‐holdup measurements in bubble columns using computed tomography [J ] . AIChE Journal , 1997 , 43 ( 6 ): 1414 - 1425 .

Chen P , Sanyal J , Duduković M P . Numerical simulation of bubble columns flows: effect of different breakup and coalescence closures [J ] . Chemical Engineering Science , 2005 , 60 ( 4 ): 1085 - 1101 .

Chen P , Duduković M P , Sanyal J . Three‐dimensional simulation of bubble column flows with bubble coalescence and breakup [J ] . AIChE Journal , 2005 , 51 ( 3 ): 696 - 712 .

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