反溶剂沉淀法合成Fe<sup>3+</sup>掺杂ZnO纳米结构及其可见光催化性能

段云彪; 徐存英; 王祥; 刘海; 黄梦婷

doi:10.11949/j.issn.0438-1157.20181233

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反溶剂沉淀法合成Fe³⁺掺杂ZnO纳米结构及其可见光催化性能

材料化学工程与纳米技术 | 更新时间：2026-07-24

- 反溶剂沉淀法合成Fe³⁺掺杂ZnO纳米结构及其可见光催化性能
- Synthesis of Fe³⁺-doped ZnO nanostructures by antisolvent precipitation method and their visible photocatalytic activity
- 化工学报 2019年70卷第3期页码：1198-1207
- 作者机构：
  
  1.昆明理工大学材料科学与工程学院，云南昆明 650093
  2.昆明理工大学冶金与能源工程学院，云南昆明 650093
  3.复杂有色金属资源清洁利用国家重点实验室，云南昆明 650093
- 作者简介：
  
  段云彪（1963—），男，高级实验师，1037550651@qq.com
  徐存英（1971—），女，博士，教授，xucunying@foxmail.com
- 基金信息：
  
  国家自然科学基金项目(51764027)
- DOI：10.11949/j.issn.0438-1157.20181233
  中图分类号： TQ 426.8
- 收稿：2018-10-19，
  
  修回：2018-12-05，
  
  网络首发：2026-07-24，
  
  纸质出版：2019-03-05
- 稿件说明：
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段云彪, 徐存英, 王祥, 刘海, 黄梦婷. 反溶剂沉淀法合成Fe³⁺掺杂ZnO纳米结构及其可见光催化性能[J]. 化工学报, 2019, 70(3): 1198-1207 DOI: 10.11949/j.issn.0438-1157.20181233.

DUAN Yunbiao, XU Cunying, WANG Xiang, LIU Hai, HUANG Mengting. Synthesis of Fe³⁺-doped ZnO nanostructures by antisolvent precipitation method and their visible photocatalytic activity[J]. CIESC Journal, 2019, 70(3): 1198-1207 DOI: 10.11949/j.issn.0438-1157.20181233.
段云彪, 徐存英, 王祥, 刘海, 黄梦婷. 反溶剂沉淀法合成Fe³⁺掺杂ZnO纳米结构及其可见光催化性能[J]. 化工学报, 2019, 70(3): 1198-1207 DOI: 10.11949/j.issn.0438-1157.20181233. DOI：

DUAN Yunbiao, XU Cunying, WANG Xiang, LIU Hai, HUANG Mengting. Synthesis of Fe³⁺-doped ZnO nanostructures by antisolvent precipitation method and their visible photocatalytic activity[J]. CIESC Journal, 2019, 70(3): 1198-1207 DOI: 10.11949/j.issn.0438-1157.20181233. DOI：

摘要

以氯化胆碱-草酸低共熔溶剂(ChCl-OA DES)为溶剂，ZnO和Fe

为原料，通过简单的反溶剂沉淀法制备出不同掺杂浓度的Fe

掺杂ZnO(Fe-ZnO)纳米结构。采用SEM、XRD、拉曼光谱、XPS等手段对所制Fe-ZnO结构与形貌进行了表征。结果表明，Fe-ZnO是由直径为20～30 nm纳米晶组装而成的微米棒。不同掺杂浓度的Fe-ZnO纳米晶均为六方铅锌矿结构，Fe

很好地进入ZnO晶格。同时考察了所制Fe-ZnO的光吸收特性和光催化活性，发现Fe

掺杂使其吸收峰红移至可见光范围，有效增强了可见光区域的催化活性。当Fe掺杂量为1.0%(atom)时，样品的光催化活性最好，比ZnO增大了约102倍。这说明Fe

掺杂可改善ZnO对可见光光子的捕获能力。

Abstract

-doped ZnO (Fe-ZnO) nanostructures with different dopant concentrations were successfully synthesized by a simple anti

solvent precipitation method from the choline chloride-oxalic acid deep eutectic solvent (ChCl-OA DES). The structure and morphology of the prepared Fe-ZnO were characterized by SEM

XRD

Raman spectroscopy and XPS. The as-prepared Fe

-doped ZnO sample was micro-rods that were composed of nanoparticles with diameter of 20—30 nm. All of Fe

-doped ZnO samples with various Fe

-doping concentration were hexagonal wurtzite structure and the Fe

ions were well incorporated into the ZnO crystal lattice. In addition

the optical properties and photocatalytic activities of the samples were investigated based on ultraviolet-visible (UV-Vis) spectra analysis as well as the degradation of Rhodamine B in aqueous solution under visible light. Compared with ZnO catalysts

the threshold wavelength of Fe

-doped ZnO nanostructure was shifted to the full visible light region (red shift) and their absorption in the visible region increased with increasing of Fe

-doping concentration from 0 to 5.0%(atom). The content of iron ion was found to be significant to the photocatalytic efficiency of Fe-ZnO nanostructures. The results demonstrated that the most optimal Fe

-doping concentration was 1.0% (atom)

and its photocatalytic activity was increased by 102% compared with ZnO under visible light. The enhanced photoactivity of the Fe

-doped ZnO nanostructure was mainly due to the improved visible photon harvesting achieved by Fe

doping.

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反溶剂沉淀法合成Fe3+掺杂ZnO纳米结构及其可见光催化性能

Synthesis of Fe3+-doped ZnO nanostructures by antisolvent precipitation method and their visible photocatalytic activity

DOI：10.11949/j.issn.0438-1157.20181233

摘要

Abstract

关键词

Keywords

references

反溶剂沉淀法合成Fe³⁺掺杂ZnO纳米结构及其可见光催化性能

Synthesis of Fe³⁺-doped ZnO nanostructures by antisolvent precipitation method and their visible photocatalytic activity