用于丙烷催化燃烧的Pd<italic style="font-style: italic"><sub>x</sub></italic>Pt<italic style="font-style: italic"><sub>y</sub></italic>-ZSM-5/Cordierite整体式催化剂

唐铨; 郭杨龙; 詹望成; 郭耘; 王丽; 王筠松

doi:10.11949/j.issn.0438-1157.20181110

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用于丙烷催化燃烧的Pd_xPt_y-ZSM-5/Cordierite整体式催化剂

催化、动力学与反应器 | 更新时间：2026-07-24

- 用于丙烷催化燃烧的Pd_xPt_y-ZSM-5/Cordierite整体式催化剂
- Catalytic combustion of propane over Pd_xPt_y-ZSM-5/Cordierite monolithic catalyst
- 化工学报 2019年70卷第3期页码：944-950
- 作者机构：
  
  华东理工大学工业催化研究所，上海 200237
- 作者简介：
  
  唐铨（1993—），女，硕士研究生，809704109@qq.com
  郭杨龙（1970—），男，博士，教授，ylguo@ecust.edu.cn
- 基金信息：
  
  国家重点研发计划项目(2016YFC0204300)
- DOI：10.11949/j.issn.0438-1157.20181110
  中图分类号： TE 991.1
- 收稿：2018-10-02，
  
  修回：2018-11-01，
  
  网络首发：2026-07-24，
  
  纸质出版：2019-03-05
- 稿件说明：
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唐铨, 郭杨龙, 詹望成, 郭耘, 王丽, 王筠松. 用于丙烷催化燃烧的Pd_xPt_y-ZSM-5/Cordierite整体式催化剂[J]. 化工学报, 2019, 70(3): 944-950 DOI: 10.11949/j.issn.0438-1157.20181110.

TANG Quan, GUO Yanglong, ZHAN Wangcheng, GUO Yun, WANG Li, WANG Yunsong. Catalytic combustion of propane over Pd_xPt_y-ZSM-5/Cordierite monolithic catalyst[J]. CIESC Journal, 2019, 70(3): 944-950 DOI: 10.11949/j.issn.0438-1157.20181110.
唐铨, 郭杨龙, 詹望成, 郭耘, 王丽, 王筠松. 用于丙烷催化燃烧的Pd_xPt_y-ZSM-5/Cordierite整体式催化剂[J]. 化工学报, 2019, 70(3): 944-950 DOI: 10.11949/j.issn.0438-1157.20181110. DOI：

TANG Quan, GUO Yanglong, ZHAN Wangcheng, GUO Yun, WANG Li, WANG Yunsong. Catalytic combustion of propane over Pd_xPt_y-ZSM-5/Cordierite monolithic catalyst[J]. CIESC Journal, 2019, 70(3): 944-950 DOI: 10.11949/j.issn.0438-1157.20181110. DOI：

摘要

以ZSM-5分子筛、铝溶胶、硝酸钯、硝酸铂和水为原料制备分子筛浆料，采用真空抽提-一次涂覆法在堇青石蜂窝陶瓷载体表面制备出Pd

-ZSM-5/Cordierite整体式催化剂，考察了Pd负载量、ZSM-5分子筛的硅铝比和Pd/Pt质量比对整体式催化剂的丙烷催化燃烧性能的影响，并用超声波振荡、SEM、XRD、H

-TPR和C

-TPD等手段对整体式催化剂进行了表征。当球磨时间为60 min，分子筛浆料固含量为38%时，整体式催化剂的涂层上载量可达到178 g‧L

-1

，涂层脱落率低于0.5%。Pd

-ZSM-5/Cordierite整体式催化剂（贵金属总负载量为1.2 g‧L

-1

）对于丙烷的催化燃烧具有较好的催化活性（

=259℃，

=323℃）和稳定性，具有良好的工业应用前景，其中较低的ZSM-5分子筛硅铝比以及Pd和Pt之间的相互作用增加了对丙烷的吸附能力和表面活性氧物种的数量，从而提高了整体式催化剂的催化活性。

Abstract

-ZSM-5/Cordierite monolithic catalysts were prepared on the

surface of the cordierite honeycomb supports

via

vacuum extraction and one coating method

in which ZSM-5 molecular sieve

alumina sol

platinum or palladium nitrates and water were used as raw materials to prepare molecular sieve slurry. Effects of Pd loading

Si/Al ratio of ZSM-5

the mass ratio of Pd/Pt on the catalytic performance of the monolithic catalysts for the catalytic combustion of propane were investigated. The monolithic catalysts were characterized by ultrasonic oscillation

SEM

XRD

-TPR and C

-TPD. When the ball milling time is 60 min and the molecular sieve slurry solid content is 38%

the coating amount of the monolith catalyst can reach 178 g‧L

-1

and the coating detachment rate is less than 0.5%. Pd

-ZSM-5/Cordierite catalyst (total loading of noble metals of 1.2 g‧L

-1

) exhibits better catalytic activity and stability (

=259℃

=323℃) for the catalytic combustion of propane

which has better industrial application prospect. Lower Si/Al ratio of ZSM-5 and the interaction between Pd and Pt increase the amounts of adsorbed propane and surface active oxygen species

thus increases the catalytic performance of the monolithic catalyst.

关键词

Keywords

references

Duan J C , Tan J H , Yang L , et al . Concentration, sources and ozone formation potential of volatile organic compounds (VOCs) during ozone episode in Beijing [J ] . Atmospheric Research , 2008 , 88 ( 1 ): 25 - 35 .

Huang B B , Lei C , Wei C H , et al . Chlorinated volatile organic compounds (Cl-VOCs) in environment-sources, potential human health impacts, and current remediation technologies [J ] . Environment International , 2014 , 71 ( 4 ): 118 - 138 .

Liotta L F . Catalytic oxidation of volatile organic compounds on supported noble metals [J ] . Applied Catalysis B: Environmental , 2010 , 100 ( 3 / 4 ): 403 - 412 .

Li W B , Wang J X , Gong H . Catalytic combustion of VOCs on non-noble metal catalysts [J ] . Catalysis Today , 2009 , 148 ( 1 / 2 ): 81 - 87 .

Zhang Z , Jiang Z , Shangguan W . Low-temperature catalysis for VOCs removal in technology and application: a state-of-the-art review [J ] . Catalysis Today , 2016 , 264 : 270 - 278 .

Kamal M S , Razzak S A , Hossain M M . Catalytic oxidation of volatile organic compounds (VOCs) — a review [J ] . Atmospheric Environment , 2016 , 140 : 117 - 134 .

Xie Y J , Yu Y Y , Gong X Q , et al . Effect of the crystal plane figure on the catalytic performance of MnO 2 for the total oxidation of propane [J ] . CrystEngComm , 2015 , 17 ( 15 ): 3005 - 3014 .

Xie Y J , Guo Y , Guo Y L , et al . A highly effective Ni-modified MnO x catalyst for total oxidation of propane: the promotional role of nickel oxide [J ] . RSC Advances , 2016 , 6 ( 55 ): 50228-50237 .

Xie Y J , Guo Y , Guo Y L , et al . A highly-efficient La-MnO x catalyst for propane combustion: the promotional role of La and the effect of the preparation method [J ] . Catalysis Science & Technology , 2016 , 6 ( 23 ): 8222 - 8233 .

Hu Z , Qiu S , You Y , et al . Hydrothermal synthesis of NiCeO x nanosheets and its application to the total oxidation of propane [J ] . Applied Catalysis B: Environmental , 2018 , 225 : 110 - 120 .

Hu Z , Wang Z , Guo Y , et al . Total oxidation of propane over a Ru/CeO 2 catalyst at low temperature [J ] . Environmental Science & Technology , 2018 , 52 ( 16 ): 9531 - 9541 .

Okal J , Zawadzki M , Tylus W . Microstructure characterization and propane oxidation over supported Ru nanoparticles synthesized by the microwave-polyol method [J ] . Applied Catalysis B: Environmental , 2011 , 101 ( 3 / 4 ): 548 - 559 .

Okal J , Zawadzki M . Combustion of propane over novel zinc aluminate-supported ruthenium catalysts [J ] . Applied Catalysis B: Environmental , 2011 , 105 ( 1 / 2 ): 182 - 190 .

Zhu Z Z , Lu G Z , Zhang Z G , et al . Highly active and stable Co 3 O 4 /ZSM-5 catalyst for propane oxidation: effect of the preparation method [J ] . ACS Catalysis , 2013 , 3 ( 6 ): 1154 - 1164 .

Hu Z , Liu X F , Meng D M , et al . Effect of ceria crystal plane on the physicochemical and catalytic properties of Pd/ceria for CO and propane oxidation [J ] . ACS Catalysis , 2016 , 6 ( 4 ): 2265 - 2279 .

Zhu Z Z , Lu G Z , Guo Y , et al . High performance and stability of the Pt-W/ZSM-5 catalyst for the total oxidation of propane: the role of tungsten [J ] . Chemcatchem , 2013 , 5 ( 8 ): 2495 - 2503 .

Avila M S , Vignatti C R , Apesteguía C R , et al . Effect of support on the deep oxidation of propane and propylene on Pt-based catalysts [J ] . Chemical Engineering Journal , 2014 , 241 : 52 - 59 .

Park J E , Kim K B , Seo K W , et al . Propane combustion over supported Pt catalysts [J ] . Research on Chemical Intermediates , 2011 , 37 ( 9 ): 1135 - 1143 .

Maillet T , Solleau C , Barbier J Jr , et al . Oxidation of carbon monoxide, propene, propane and methane over a Pd/Al 2 O 3 catalyst. Effect of the chemical state of Pd [J ] . Applied Catalysis B Environmental , 1997 , 14 ( 1 / 2 ): 85 - 95 .

Maillet T , Barbier J Jr , Duprez D . Reactivity of steam in exhaust gas catalysis(Ⅲ): Steam and oxygen/steam conversions of propane on a Pd/Al 2 O 3 catalyst [J ] . Applied Catalysis B Environmental , 1996 , 9 ( 1 / 2 / 3 / 4 ): 251 - 266 .

Yazawa Y , Takagi N , Yoshida H , et al . The support effect on propane combustion over platinum catalyst: control of the oxidation-resistance of platinum by the acid strength of support materials [J ] . Applied Catalysis A General , 2002 , 233 ( 1 / 2 ): 103 - 112 .

Garetto T F , Rincón E , Apesteguía C R . Deep oxidation of propane on Pt-supported catalysts: drastic turnover rate enhancement using zeolite supports [J ] . Applied Catalysis B: Environmental , 2004 , 48 ( 3 ): 167 - 174 .

单学蕾 , 关乃佳 , 曾翔 , 等 . 不同硅铝比的Cu-ZSM-5/堇青石整体式催化剂的NO分解反应性能 [J ] . 催化学报 , 2001 , 22 ( 3 ): 242 - 244 .

Shan X L , Guan N J , Zeng X , et al . NO decomposition on Cu-ZSM-5/cordierite monolithic catalyst samples with different Si/Al ratios [J ] . Chinese Journal of Catalysis , 2001 , 22 ( 3 ): 242 - 244 .

Wang S N , Cui Y J , Lan L , et al . A new monolithic Pt-Pd-Rh motorcycle exhaust catalyst to meet future emission standards [J ] . Chinese Journal of Catalysis , 2014 , 35 ( 9 ): 1482 - 1491 .

Deugd R M D , Kapteijn F , Moulijn J A . Using monolithic catalysts for highly selective Fischer-Tropsch synthesis [J ] . Catalysis Today , 2003 , 79 / 80 ( 3 ): 495 - 501 .

Schneider R , Kießling D , Wendt G . Cordierite monolith supported perovskite-type oxides — catalysts for the total oxidation of chlorinated hydrocarbons [J ] . Applied Catalysis B: Environmental , 2000 , 28 ( 3 / 4 ): 187 - 195 .

Colman-Lerner E , Peluso M A , Sambeth J , et al . Cerium, manganese and cerium/manganese ceramic monolithic catalysts. Study of VOCs and PM removal [J ] . Journal of Rare Earths , 2016 , 34 ( 7 ): 675 - 682 .

江浩 , 郭杨龙 , 张志刚 , 等 . Ni对单Pd型挥发性有机废气净化催化剂的助催化作用 [J ] . 无机化学学报 , 2006 , 22 ( 7 ): 1210 - 1214 .

Jiang H , Guo Y L , Zhang Z G , et al . Promotion of Ni on performance of Pd-only catalyst for destractive removal of volatile organic wastes [J ] . Chinese Journal of Inorganic Chemistry , 2006 , 22 ( 7 ): 1210 - 1214 .

Mitra B , Kunzru D . Washcoating of different zeolites on cordierite monoliths [J ] . Journal of the American Ceramic Society , 2008 , 91 ( 1 ): 64 - 70 .

Carvalho L S , Pieck C L , Rangel M C , et al . Trimetallic naphtha reforming catalysts(I):Properties of the metal function and influence of the order of addition of the metal precursors on Pt-Re-Sn/γ-Al 2 O 3 -Cl [J ] . Applied Catalysis A: General , 2004 , 269 ( 1 / 2 ): 91 - 103 .

Zhu Z Z , Lu G Z , Guo Y , et al . Influences of Pd precursors and preparation method on the catalytic performances of Pd-only close-coupled catalysts [J ] . Journal of Industrial and Engineering Chemistry , 2012 , 18 ( 6 ): 2135 - 2140 .

Elangovan S P , Ogura M , Ernst S , et al . A comparative study of zeolites SSZ-33 and MCM-68 for hydrocarbon trap applications [J ] . Microporous & Mesoporous Materials , 2006 , 96 ( 1 / 2 / 3 ): 210 - 215 .

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DOI：10.11949/j.issn.0438-1157.20181110

摘要

Abstract

关键词

Keywords

references

用于丙烷催化燃烧的Pd_xPt_y-ZSM-5/Cordierite整体式催化剂

Catalytic combustion of propane over Pd_xPt_y-ZSM-5/Cordierite monolithic catalyst