离子液体在氨气分离回收中的应用及展望

曾少娟; 尚大伟; 余敏; 陈昊; 董海峰; 张香平

doi:10.11949/j.issn.0438-1157.20181067

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离子液体在氨气分离回收中的应用及展望

综述与专论 | 更新时间：2026-07-24

- 离子液体在氨气分离回收中的应用及展望
- Applications and perspectives of NH₃ separation and recovery with ionic liquids
- 化工学报 2019年70卷第3期页码：791-800
- 作者机构：
  
  1.中国科学院过程工程研究所，多相复杂系统国家重点实验室，离子液体清洁过程北京市重点实验室，北京 100190
  2.郑州大学化工与能源学院，河南郑州 450001
  3.郑州中科新兴产业技术研究院，河南郑州 450000
- 作者简介：
  
  曾少娟（1982—），女，博士，副研究员，sjzeng@ipe.ac.cn
  张香平（1969—），女，博士，研究员，xpzhang@ipe.ac.cn
- 基金信息：
  
  国家自然科学基金项目(21425625,U1662122,21506219,21838010);北京市自然科学基金项目(2182071)
- DOI：10.11949/j.issn.0438-1157.20181067
  中图分类号： TQ 530.11
- 收稿：2018-09-25，
  
  修回：2018-12-07，
  
  网络首发：2026-07-24，
  
  纸质出版：2019-03-05
- 稿件说明：
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曾少娟, 尚大伟, 余敏, 陈昊, 董海峰, 张香平. 离子液体在氨气分离回收中的应用及展望[J]. 化工学报, 2019, 70(3): 791-800

ZENG Shaojuan, SHANG Dawei, YU Min, CHEN Hao, DONG Haifeng, ZHANG Xiangping. Applications and perspectives of NH₃ separation and recoverywith ionic liquids[J]. CIESC Journal, 2019, 70(3): 791-800 DOI: 10.11949/j.issn.0438-1157.20181067.
曾少娟, 尚大伟, 余敏, 陈昊, 董海峰, 张香平. 离子液体在氨气分离回收中的应用及展望[J]. 化工学报, 2019, 70(3): 791-800 DOI： 10.11949/j.issn.0438-1157.20181067.

ZENG Shaojuan, SHANG Dawei, YU Min, CHEN Hao, DONG Haifeng, ZHANG Xiangping. Applications and perspectives of NH₃ separation and recoverywith ionic liquids[J]. CIESC Journal, 2019, 70(3): 791-800 DOI: 10.11949/j.issn.0438-1157.20181067. DOI：

摘要

氨（NH

）是典型有毒有害工业气态污染物，也是形成PM2.5中二次颗粒物的根本原因之一，大量含氨气体的排放严重威胁人类的生活环境和健康。采用传统的酸法或水法，通常存在腐蚀性强、污染重、能耗高等问题，且难以回收利用氨资源。离子液体因其极低的挥发性、较好的化学/热稳定性、酸碱可调及高的氨溶解度等特点，为高效低能耗NH

分离提供了新途径。综述了近年来国内外离子液体在NH

分离中的研究进展，重点总结了常规离子液体、功能离子液体及离子液体溶剂/材料对NH

的吸收/吸附性能，阐明

了阴阳离子、功能基团对NH

吸收性能的影响规律及其吸收机理，并探讨了该方向的研究和发展趋势。

Abstract

As one of the typical alkaline and poisonous pollutants

ammonia (NH

) is widely considered as a primary factor for the formation of fog and haze

which has caused a wide range of environmental problems and serious harm to human health. The traditional technologies for NH

separation

like water scrubbing and acid scrubbing

have been applied in industries. However

some inherent drawbacks

such as severe corrosion

heavy pollution

high energy consumption

and hard to recover NH

resources come with yet. Ionic liquids (ILs) provide a novel way for efficient and energy-saving separation of NH

owing to their extremely low vapour pressure

good chemical/thermal stability and tuneable acidity and alkalinity. In this review

the recent advances on conventional ILs

functionalized ILs and IL-based solvents and materials for NH

absorption/adsorption have been overviewed. The NH

absorption capacities in different ILs were summarized and the effect of cations

anions and functional groups on NH

absorption and the mechanisms have been discussed

and the research and development trend of this direction are discussed.

关键词

Keywords

references

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