合肥工业大学化学与化工学院,安徽 合肥 230009
朱顺(1995—),男,硕士研究生,zhushun0825@163.com
杨庆春(1990—),男,博士,讲师,ceqcyang@hfut.edu.cn
收稿:2018-09-17,
修回:2018-10-16,
网络首发:2020-06-16,
纸质出版:2019-02-05
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朱顺, 郭琦, 张大伟, 杨庆春. 集成CO2高效利用的煤制乙二醇过程设计与系统分析[J]. 化工学报, 2019, 70(2): 772-779 DOI: 10.11949/j.issn.0438-1157.20181044.
ZHU Shun, GUO Qi, ZHANG Dawei, YANG Qingchun. Conceptual design and system analysis coal to ethylene glycol process integrated with efficient utilization of CO2[J]. CIESC Journal, 2019, 70(2): 772-779 DOI: 10.11949/j.issn.0438-1157.20181044.
朱顺, 郭琦, 张大伟, 杨庆春. 集成CO2高效利用的煤制乙二醇过程设计与系统分析[J]. 化工学报, 2019, 70(2): 772-779 DOI: 10.11949/j.issn.0438-1157.20181044. DOI:
ZHU Shun, GUO Qi, ZHANG Dawei, YANG Qingchun. Conceptual design and system analysis coal to ethylene glycol process integrated with efficient utilization of CO2[J]. CIESC Journal, 2019, 70(2): 772-779 DOI: 10.11949/j.issn.0438-1157.20181044. DOI:
为减少传统煤制乙二醇过程资源利用效率低和CO
2
排放量高等问题,提出了一种集成CO
2
高效利用的煤制乙二醇过程,并对其进行了全流程建模及系统分析。与传统过程不同,新过程利用焦炉气来提高其资源利用率和能量效率,集成甲烷干重整与湿重整技术降低CO
2
排放。在全流程建模的基础之上,对新工艺的关键操作参数进行了分析与优化。结果表明,焦炉气的最佳进料比和甲烷蒸汽重整反应的分配比为0.68和0.74。与传统过程相比,新工艺的CO
2
排放降低了94.05%,同时㶲效率提高了15.17%。
In the momentum of reducing CO
2
emission of coal to ethylene glycol process
a novel carbon dioxide utilized coal to ethylene glycol (CUCtEG) process is proposed
simulated
and optimized. The novel process is assisted with coke oven gas to enhance resource and energy efficiencies as well as reduce CO
2
emission by integrating with dry/steam-mixed methane reforming technologies. Based on the rigorous steady-state simulation of the process
key operational parameters of the novel process are investigated and optimized. The optimal feed ratio of coke oven gas to coal and the split ratio of that for steam methane reforming react
ion are 0.68 and 0.74. Compared with the traditional process
the CO
2
emission of the new process is reduced by 94.05%
and the exergy efficiency is increased by 15.17%.
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