碱对镀锌铁表面CaCO<sub>3</sub>污垢生长特性的影响机理研究

梁爱国; 蒋华义; 蔡航航; 张定周; 孙娜娜; 种新民

doi:10.11949/j.issn.0438-1157.20180884

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碱对镀锌铁表面CaCO₃污垢生长特性的影响机理研究

表面与界面工程 | 更新时间：2020-06-24

- 碱对镀锌铁表面CaCO₃污垢生长特性的影响机理研究
- Effect of alkali about growth characteristics of CaCO₃ on galvanized iron surface
- 化工学报 2019年70卷第1期页码：170-178
- 作者机构：
  
  1.西安石油大学石油工程学院，陕西西安 710065
  2.克拉玛依红山油田有限责任公司，新疆克拉玛依 834000
  3.新疆油田采油一厂，新疆克拉玛依 834000
- 作者简介：
  
  蒋华义（1973—），男，博士，教授，hyjiang@xsyu.edu.cn
- 基金信息：
  
  陕西省自然科学基础研究计划一般项目（青年）项目(2018JQ5206)
- DOI：10.11949/j.issn.0438-1157.20180884
  中图分类号： TE 357.61
- 收稿：2018-08-01，
  
  修回：2018-11-01，
  
  纸质出版：2019-01-05
- 稿件说明：
移动端阅览
蒋华义, 蔡航航, 梁爱国, 张定周, 孙娜娜, 种新民. 碱对镀锌铁表面CaCO₃污垢生长特性的影响机理研究[J]. 化工学报, 2019, 70(1): 170-178 DOI: 10.11949/j.issn.0438-1157.20180884.

JIANG Huayi, CAI Hanghang, LIANG Aiguo, ZHANG Dingzhou, SUN Nana, CHONG Xinmin. Effect of alkali about growth characteristics of CaCO₃ on galvanized iron surface[J]. CIESC Journal, 2019, 70(1): 170-178 DOI: 10.11949/j.issn.0438-1157.20180884.
蒋华义, 蔡航航, 梁爱国, 张定周, 孙娜娜, 种新民. 碱对镀锌铁表面CaCO₃污垢生长特性的影响机理研究[J]. 化工学报, 2019, 70(1): 170-178 DOI: 10.11949/j.issn.0438-1157.20180884. DOI：

JIANG Huayi, CAI Hanghang, LIANG Aiguo, ZHANG Dingzhou, SUN Nana, CHONG Xinmin. Effect of alkali about growth characteristics of CaCO₃ on galvanized iron surface[J]. CIESC Journal, 2019, 70(1): 170-178 DOI: 10.11949/j.issn.0438-1157.20180884. DOI：

摘要

为解决因水结垢造成的管线堵塞问题，提出了变被动结垢为主动结垢的思路。针对某油田注入水，以镀锌铁为研究基质，综合动态模拟剪切实验以及SEM、EDS和浊度测试，探究碱类型和浓度对CaCO

污垢生长特性的影响机理。结果表明5种常用碱——碳酸钠Na

、碳酸氢钠NaHCO

、三乙醇胺TEOA、氢氧化钙Ca(OH)

和氧化钙CaO对污垢结垢量、失钙率及结垢诱导期影响各异，其中Na

对失钙速率影响显著，而CaO对结垢速率影响较为明显。其次，不同碱促使污垢形成不同的晶型晶貌，其中方块状和层状垢物易于在材料表面堆积，即有利于结垢。最后，碱浓度对污垢生长影响具有双重性，存在抑垢和促垢浓度区间。

Abstract

In order to solve the problem of pipeline blockage due to the water scaling

the key idea that the crystallization fouling process was changed from passive to active was proposed in this research. In view of the injected water form oil field

galvanized iron was selected as the substrate. The mechanisms of the influences of alkali types and concentrations on crystal growth were revealed using dynamic simulation experiments，SEM

EDS and liquid turbidity tests. These results were showed that: The effects of five kinds of alkalis (such as Na

NaHCO

TEOA

Ca(OH)

and CaO) on scale mass gains

calcium loss rate and scaling induction periods were different. Among them Na

has a significant effeet on the loss of calcium loss

while CaO has a significant effect on the rate of fouling. Secondly

the morphology of the crystal is correlated with the alkali types. If the surface of the material was capable of forming a blocky shape scale or a layered fouling

this material was beneficial for the aggregation and deposition of crystals. Finally

the alkali concentration played a twofold role in the growth of fouling

that was

to promote the aggregation of crystal and to inhibit the scale growth. In other words

there would be a preferred range of alkali concentrations.

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碱对镀锌铁表面CaCO3污垢生长特性的影响机理研究

Effect of alkali about growth characteristics of CaCO3 on galvanized iron surface

DOI：10.11949/j.issn.0438-1157.20180884

摘要

Abstract

关键词

Keywords

references

碱对镀锌铁表面CaCO₃污垢生长特性的影响机理研究

Effect of alkali about growth characteristics of CaCO₃ on galvanized iron surface