反应精馏隔壁塔制甲缩醛过程模拟与分析

杨杰; 祁江羽; 沙勇

doi:10.11949/j.issn.0438-1157.20180623

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反应精馏隔壁塔制甲缩醛过程模拟与分析

分离工程 | 更新时间：2026-07-24

- 反应精馏隔壁塔制甲缩醛过程模拟与分析
- Simulation and analysis of reactive dividing-wall column for methylal production process
- 化工学报 2019年70卷第3期页码：960-968
- 作者机构：
  
  厦门大学化学化工学院化学工程与生物工程系，福建厦门 361005
- 作者简介：
  
  杨杰（1991—），男，硕士研究生,13476075820@163.com
  沙勇（1971—），男，博士，副教授，ysha@xmu.edu.cn
- 基金信息：
- DOI：10.11949/j.issn.0438-1157.20180623
  中图分类号： TQ 224.1
- 收稿：2018-06-07，
  
  修回：2018-11-06，
  
  网络首发：2026-07-24，
  
  纸质出版：2019-03-05
- 稿件说明：
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杨杰, 祁江羽, 沙勇. 反应精馏隔壁塔制甲缩醛过程模拟与分析[J]. 化工学报, 2019, 70(3): 960-968

YANG Jie, QI Jiangyu, SHA Yong. Simulation and analysis of reactive dividing-wall column for methylal production process[J]. CIESC Journal, 2019, 70(3): 960-968
杨杰, 祁江羽, 沙勇. 反应精馏隔壁塔制甲缩醛过程模拟与分析[J]. 化工学报, 2019, 70(3): 960-968 DOI： 10.11949/j.issn.0438-1157.20180623.

YANG Jie, QI Jiangyu, SHA Yong. Simulation and analysis of reactive dividing-wall column for methylal production process[J]. CIESC Journal, 2019, 70(3): 960-968 DOI： 10.11949/j.issn.0438-1157.20180623.

摘要

甲缩醛（methylal）是一种重要的化工基本原料，广泛应用于化工中间体、溶剂、涂料及燃料添加剂等的生产中。目前，反应精馏技术是用于以甲醇和甲醛为原料制取甲缩醛的主要方法。利用Aspen Plus过程模拟软件模拟了常规的双进料甲缩醛反应精馏工艺流程，同时提出并模拟了反应精馏隔壁塔（RDWC）工艺制备甲缩醛的流程，通过对比来探究RDWC流程的优越性。结果表明，采用RDWC制备甲缩醛可避免中间组分在塔内的返混效应，同时可使年度总费用降低8.09%，显著提高过程的经济性。

Abstract

Methylal is an important raw material used for the production of chemical intermediates

solvents

paints and fuel additives

etc

. At present

reactive distillation technology is the main method for preparing methylal from methanol and formaldehyde. In this work

the reactive distillation with a dividing-wall column for producing methylal was proposed and simulated. The results show that the preparation of methylal by such a process can avoid the back mixing effect of the middle component in the column and reduce the total cost by 8.09% annually

then significantly improve the economics of the process.

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references

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