矿石资源中锂的提取与回收研究进展

苏慧; 朱兆武; 王丽娜; 齐涛

doi:10.11949/j.issn.0438-1157.20180465

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矿石资源中锂的提取与回收研究进展

综述与专论 | 更新时间：2020-06-24

- 矿石资源中锂的提取与回收研究进展
- Research progress in extraction and recovery of lithium from hard-rock ores
- 化工学报 2019年70卷第1期页码：10-23
- 作者机构：
  
  1.中国科学院过程工程研究所湿法冶金清洁生产技术国家工程实验室，北京 100190
  2.中国科学院绿色过程与工程重点实验室，北京 100190
  3.中国科学院大学化工学院，北京 101408
- 作者简介：
  
  苏慧（1993—），女，博士研究生, suhuipiaoliang@163.com
  朱兆武（1966—），男，研究员，zhwzhu@ipe.ac.cn
  齐涛（1966—），男，研究员，tqi@ipe.ac.cn
- 基金信息：
  
  中国科学院前沿科学重点研究项目(QYZDJ-SSW-JSC021);中国科学院创新交叉团队项目;国家自然科学基金项目(51774260;21506233;21606241)
- DOI：10.11949/j.issn.0438-1157.20180465
  中图分类号： TF 046
- 收稿：2018-05-03，
  
  修回：2018-10-08，
  
  纸质出版：2019-01-05
- 稿件说明：
移动端阅览
苏慧, 朱兆武, 王丽娜, 齐涛. 矿石资源中锂的提取与回收研究进展[J]. 化工学报, 2019, 70(1): 10-23

SU Hui, ZHU Zhaowu, WANG Lina, QI Tao. Research progress in extraction and recovery of lithium from hard-rock ores[J]. CIESC Journal, 2019, 70(1): 10-23
苏慧, 朱兆武, 王丽娜, 齐涛. 矿石资源中锂的提取与回收研究进展[J]. 化工学报, 2019, 70(1): 10-23 DOI： 10.11949/j.issn.0438-1157.20180465.

SU Hui, ZHU Zhaowu, WANG Lina, QI Tao. Research progress in extraction and recovery of lithium from hard-rock ores[J]. CIESC Journal, 2019, 70(1): 10-23 DOI： 10.11949/j.issn.0438-1157.20180465.

摘要

近年来锂的开发随着新型能源的大规模应用得到快速发展。锂矿石是提取锂产品的主要来源之一，矿石提锂高效清洁工艺开发与资源综合利用是该领域发展的必然趋势。在分析锂矿石组成及结构特点的基础上，对酸法、碱法、盐法等典型提锂工艺进行了综述，重点讨论了锂生产过程中存在的环境污染及资源综合利用问题。酸法提锂工艺中锂回收率高，但酸性浸出液成分复杂，纯化步骤流程长，含氟矿石产生含氟气体污染环境。碱法和盐法工艺选择性好，但锂回收率较低、成本高、渣量大。除此以外，其他方法都存在明显的优缺点，如高温氯化法回收率高，渣的利用具有一定优势，但设备腐蚀严重。因此，矿石提锂新工艺的开发重点在于减少废渣的产出，并实现伴生资源的综合回收。

Abstract

Lithium is widely used in new types of energy materials and the applications are growing fast. Lithium hard-rock ores are the main resources for lithium production. The trend of lithium recovery from the ores is to realize cleaning and effective production

and resource comprehensive utilizations. Based on the composition and structure analysis of various kinds of lithium ores

its recovery by a variety of methods

such as

typically

acidic

alkaline

salt were reviewed. Future development for the techniques of lithium recovery from ores was also discussed. It is shown that the lithium extraction by acidic methods was usually high. However

the composition of the acidic leachate was complex

resulting in a long process of purification of lithium. It also could cause environmental pollution by off-gas when processing the ores containing fluorine. Alkali and salt based processes had good lithium selectivity

but its extraction was low and the cost was high

and large amounts of solid wastes were generated difficult to store and re-use. Some other methods have both advantages and disadvantages

such as high-temperature chlorination method which has high metal recovery and ready solid residue utilization but has high corrosiveness to the equipment. Therefore

the development of new processes for extracting lithium from ore is focused on reducing the output of waste residue and achieving comprehensive recovery of associated resources.

关键词

Keywords

references

Jewell S , Kimball S . Mineral Commodity Summaries 2016 [R]. U.S . Geological Survey : Reston VA , 2016 .

Zhou Z Y , Qin W , Fei W Y . Extraction equilibria of lithium with tributyl phosphate in three diluents [J]. Journal of Chemical and Engineering Data , 2011 , 56 ( 9 ): 3518 - 3522 .

贺理珀 , 孙淑英 , 于建国 . 退役锂离子电池中有价金属回收研究进展 [J]. 化工学报 , 2018 , 69 ( 1 ): 327 - 340 .

He L P , Sun S Y , Yu J G . Review on processes and technologies for recovery of valuable metals from spent lithium-ion batteries [J]. CIESC Journal , 2018 , 69 ( 1 ): 327 - 340 .

李芳芳 , 李忠 . 全球锂资源储量及碳酸锂供求状况分析 [J]. 江西化工 , 2016 , ( 6 ): 11 - 13 .

Li F F , Li Z . Global lithium resources reserves and analysis of lithium carbonate supply and demand [J]. Jiangxi Chemical Industry , 2016 , ( 6 ): 11 - 13 .

Vikström H , Davidsson S , Höök M . Lithium availability and future production outlooks [J]. Applied Energy , 2013 , 110 ( 110 ): 252 - 266 .

Speirs J , Contestabile M , Houari Y , et al . The future of lithium availability for electric vehicle batteries [J]. Renewable & Sustainable Energy Reviews , 2014 , 35 : 183 - 193 .

Cabeza L F , Gutierrez A , Barreneche C , et al . Lithium in thermal energy storage: a state-of-the-art review [J]. Renewable & Sustainable Energy Reviews , 2015 , 42 ( 42 ): 1106 - 1112 .

Ober J A . Mineral Commodity Summaries 2017 [R]. U.S . Geological Survey : Reston VA , 2017 .

朱丽丽 , 杨贝贝 , 杨雪松 . 基于复杂网络视角下中国碳酸锂国际贸易地位分析 [J]. 资源与产业 , 2016 , 18 ( 5 ): 14 - 20 .

Zhu L L , Yang B B , Yang X S . China s global lithium carbonate trading position based on complex network [J]. Resources & Industries , 2016 , 18 ( 5 ): 14 - 20 .

李神勇 , 康莲薇 , 刘建军 , 等 . 锂资源分布及提取技术研究 [J]. 广东化工 , 2016 , 43 ( 24 ): 81 - 82 .

Li S Y , Kang L W , Liu J J , et al . Research on distribution and extraction technology of lithium resources [J]. Guangdong Chemical Industry , 2016 , 43 ( 24 ): 81 - 82 .

Choubey P K , Kim M S , Srivastava R R , et al . Advance review on the exploitation of the prominent energy-storage element: lithium(Ⅰ): From mineral and brine resources [J]. Minerals Engineering , 2016 , 89 : 119 - 137 .

Meshram P , Pandey B D , Mankhand T R . Extraction of lithium from primary and secondary sources by pre-treatment, leaching and separation: a comprehensive review [J]. Hydrometallurgy , 2014 , 150 : 192 - 208 .

Swain B . Recovery and recycling of lithium: a review [J]. Separation & Purification Technology , 2016 , 172 : 388 - 403 .

Kesler S E , Gruber P W , Medina P A , et al . Global lithium resources: relative importance of pegmatite, brine and other deposits [J]. Ore Geology Reviews , 2012 , 48 ( 5 ): 55 - 69 .

Lagache M , Sebastian A . Experimental study of Li-rich granitic pegmatites (Ⅱ): Spodumene + albite + quartz equilibrium [J]. American Mineralogist , 1991 , 76 ( 3 ): 611 - 616 .

胡晓洪 , 张庆今 . 锂辉石的工业应用 [J]. 中国陶瓷 , 1995 , 31 ( 3 ): 37 - 39 .

Hu X H , Zhang Q J . The application of spodumene to industry [J]. China Ceramics , 1995 , 31 ( 3 ): 37 - 39 .

Wietelmann U , Bauer R J . Lithium and Lithium Compounds [M]. Germany : Wiley-VCH , 2000 : 22 .

唐尧 . 世界锂生产消费格局及资源安全保障分析 [J]. 世界有色金属 , 2015 , ( 8 ): 21 - 25 .

Tang Y . The world s lithium production and consumption patterns and resource security analysis [J]. World Nonferrous Metals , 2015 , ( 8 ): 21 - 25 .

Bai F , Feng H Y , Zou S J , et al . A mineralogical study of spodumene from Guanpo pegmatites in Lushi, Henan province [J]. Acta Petrologica Et Mineralogica , 2011 , 30 ( 2 ): 281 - 285 .

蔡艳龙 , 李建武 . 全球锂资源开发利用形势分析及启示 [J]. 地球学报 , 2017 , 38 ( 1 ): 25 - 29 .

Cai Y L , Li J W . The analysis and enlightenment of exploitation situation of global lithium resources [J]. Acta Geoscientica Sinica , 2017 , 38 ( 1 ): 25 - 29 .

Martin G , Schneider A , Voigt W , et al . Lithium extraction from the mineral zinnwaldite(Ⅱ): Lithium carbonate recovery by direct carbonation of sintered zinnwaldite concentrate [J]. Minerals Engineering , 2017 , 110 : 75 - 81 .

Garrett D E . Handbook of Lithium and Natural Calcium Chloride [M]. London : Elsevier , 2004 : 221 .

张玉玉 , 张如柏 . 湖北通城透锂长石伟晶岩中锂辉石的发现 [J]. 矿物岩石 , 2008 , 28 ( 3 ): 37 - 40 .

Zhang Y Y , Zhang R B . The discovery of spodumene in petalite pegmatite, Tong Cheng, Hubei China [J]. Journal of Mineralogy and Petrology , 2008 , 28 ( 3 ): 37 - 40 .

Hao H , Liu Z , Zhao F , et al . Material flow analysis of lithium in China [J]. Resources Policy , 2017 , 51 : 100 - 106 .

唐平 . 四川某锂辉石矿工艺矿物学及其提锂工艺研究 [D]. 成都 : 成都理工大学 , 2016 .

Tang P . Process mineralogy and lithium extraction technology study on spodumene ore in Sichuan province [D]. Chengdu : Chengdu University of Technology , 2016 .

游清治 . 锂辉石的转型焙烧 [J]. 新疆有色金属 , 1989 , ( 1 ): 27 - 32 .

You Q Z . Transformation roasting of spodumene [J]. Xinjiang Nonferrous Metals , 1989 , ( 1 ): 27 - 32 .

郭慧 . 锂云母氟化学法提锂反应机理及浸取液硫酸盐体系成矾除铝的研究 [D]. 福州 : 福州大学 , 2014 .

Guo H . The investigation on reaction mechanism of fluorine chemical method to extract lithium from lepidolite and separation technology to recover aluminum in the leaching solution [D]. Fuzhou : Fuzhou University , 2014 .

Vieceli N , Nogueira C A , Pereira M F C , et al . Optimization of lithium extraction from lepidolite by roasting using sodium and calcium sulfates [J]. Mineral Processing & Extractive Metallurgy Review , 2016 , 38 ( 1 ): 10 - 14 .

Guggenheim S , Bailey S W . The refinement of zinnwaldite-lM in subgroup symmetry [J]. American Mineralogist , 1977 , 62 : 1158 - 1167 .

Beitone L , Guillou N , Millange F , et al . Structural characterizations of lithium gallium phosphates, analogous to the amblygonite-montebrasite series [J]. Cheminform , 2003 , 4 ( 8 ): 1061 - 1065 .

Ross N , Zhao J , Spencer E , et al . Petalite under pressure [J]. Acta Crystallographica , 2014 , 70 ( a1 ): C76 - C76 .

Momma K , Izumi F . VESTA 3 for three-dimensional visualization of crystal, volumetric and morphology data [J]. Journal of Applied Crystallography , 2011 , 44 ( 6 ): 1272 - 1276 .

Koltsov V Y , Novikov P Y , Sarychev G A , et al . Experimental investigations during the technology development of sulfuric acid processing of spodumene concentrate [J]. Tsvetnye Metally , 2016 , ( 4 ): 18 - 22 .

Xiao M S , Wang S H , Zhang Q F , et al . Leaching mechanism of the spodumene sulphuric acid process [J]. Rare Metals , 1997 , 16 ( 1 ): 37 - 45 .

杨晶晶 , 秦身钧 , 张健雅 , 等 . 锂提取方法研究进展与展望 [J]. 化工矿物与加工 , 2012 , 41 ( 6 ): 44 - 46 .

Yang J J , Qin S J , Zhang J Y , et al . Research and progress on lithium extraction [J]. Industrial Minerals & Processing , 2012 , 41 ( 6 ): 44 - 46 .

孟广寿 . 矿石提锂与盐湖卤水提锂将并存发展 [J]. 世界有色金属 , 2008 , ( 2 ): 67 - 69 .

Meng G S . Co-existence of extracting lithium from ores and salt lake brines [J]. World Nonferrous Metals , 2008 , ( 2 ): 67 - 69 .

费文斌 . 利用锂渣代替黏土烧制水泥熟料的试验 [J]. 水泥 , 1999 , ( 1 ): 4 - 106 .

Fei W B . Experiment of cement clinker preparation by calcination using lithium recovery residues instead of clay [J]. Cement , 1999 , ( 1 ): 4 - 106 .

陈悦娣 . 锂渣的综合回收利用 [J]. 新疆有色金属 , 2014 , 37 ( 4 ): 72 - 74 .

Chen Y D . Comprehensive recovery and utilisation of lithium recovery residues [J]. Xinjiang Nonferrous Metals , 2014 , 37 ( 4 ): 72 - 74 .

吕天宝 , 武文焕 , 冯怡利 , 等 . 利用锂盐渣配制生料煅烧硅酸盐水泥熟料的方法 : 106966615A [P]. 2017-07-21 .

Lyu T B , Wu W H , Feng Y L , et al . A method for preparing cement clinker by calcining raw materials of lithium recovery residues : 106966615A [P]. 2017-07-21 .

李春红 , 费文斌 . 锂渣在水泥工业中的应用研究 [J]. 水泥技术 , 2001 , ( 5 ): 57 - 58 .

Li C H , Fei W B . Lithium residue utilization in cement industry [J]. Cement Technology , 2001 , ( 5 ): 57 - 58 .

张兰芳 , 陈剑雄 , 岳瑜 , 等 . 锂渣高强混凝土的试验研究 [J]. 新型建筑材料 , 2005 , ( 3 ): 29 - 31 .

Zhang L F , Chen J X , Yue Y , et al . Study on the high-strength concrete prepared with lithium slag [J]. New Building Materials , 2005 , ( 3 ): 29 - 31 .

翟梦怡 , 赵计辉 , 王栋民 . 锂渣粉作为辅助胶凝材料在水泥基材料中的研究进展 [J]. 材料导报 , 2017 , 31 ( 5 ): 139 - 144 .

Zhai M Y , Zhao J H , Wang D M . Applying lithium slag powders to cement-based materials as supplementary cementitious component: an overview [J]. Materials Review , 2017 , 31 ( 5 ): 139 - 144 .

Rosales G D , Ruiz M D C , Rodriguez M H . Novel process for the extraction of lithium from beta-spodumene by leaching with HF [J]. Hydrometallurgy , 2014 , 147 : 1 - 6 .

Kumar M , Babu M N , Mankhand T R , et al . Precipitation of sodium silicofluoride (Na 2 SiF 6 ) and cryolite (Na 3 AlF 6 ) from HF/HCl leach liquors of alumino-silicates [J]. Hydrometallurgy , 2010 , 104 ( 2 ): 304 - 307 .

张竞争 . 锂辉石氟硅酸法制备碳酸锂工艺的研究 [D]. 青岛 : 山东科技大学 , 2014 .

Zhang J Z . Study on extraction of lithium carbonate from spodumene by H 2 SiF 6 method [D]. Qingdao : Shandong University of Science and Technology , 2014 .

游清治 . 锂渣的综合利用 [J]. 新疆有色金属 , 1985 , ( 2 ): 28 - 36 .

You Q Z . Comprehensive utilization of lithium residue [J]. Xinjiang Nonferrous Metals , 1985 , ( 2 ): 28 - 36 .

薛彦辉 . 一种锂渣综合利用生产化工原料的方法 : 103601230A [P]. 2014-02-26 .

Xue Y H . A method for comprehensive utilization of lithium slag to produce raw chemical materials : 103601230A [P]. 2014-02-26 .

冯恒毅 . 河南官坡伟晶岩中锂辉石的矿物学及提锂工艺研究 [D]. 北京 : 中国地质大学 , 2009 .

Feng H Y . Study on mineralogy and preparation of lithium carbonate of spodumene from pegmatite deposits in Guanpo Henan province [D]. Beijing : China University of Geosciences , 2009 .

Chen Y , Tian Q , Chen B , et al . Preparation of lithium carbonate from spodumene by a sodium carbonate autoclave process [J]. Hydrometallurgy , 2011 , 109 ( 1 ): 43 - 46 .

陈亚 , 廖婷 , 陈白珍 , 等 . 纯碱压煮法从锂辉石中提取锂的研究 [J]. 有色金属(冶炼部分) , 2011 , ( 9 ): 21 - 32 .

Chen Y , Liao T , Chen B Z , et al . Extraction of lithium from spodumene by sodium carbonate autoclave process [J]. Nonferrous Metals (Extractive Metallurgy) , 2011 , ( 9 ): 21 - 32 .

田千秋 . 锂辉石矿提取碳酸锂工艺研究 [D]. 长沙 : 中南大学 , 2012 .

Tian Q Q . Research on the extraction of lithium carbonate from spodumene [D]. Changsha : Central South University , 2012 .

Olivier C A , Panneton J J , Perusse J . Continuous production of lithium carbonate : GB1576130 [P]. 1978-02-16 .

Arne S K , Johan W S . Method of recovering lithium salts from lithium-containing minerals : US 24041638 A [P]. 1941-01-28 .

Barbosa L I , González J A , Ruiz M D C . Extraction of lithium from β-spodumene using chlorination roasting with calcium chloride [J]. Thermochimica Acta , 2015 , 605 : 63 - 67 .

Barbosa L I , Valente G , Orosco R P , et al . Lithium extraction from beta-spodumene through chlorination with chlorine gas [J]. Minerals Engineering , 2014 , 56 : 29 - 34 .

Barbosa L I , Valente N G , González J A . Kinetic study on the chlorination of β-spodumene for lithium extraction with Cl 2 gas [J]. Thermochimica Acta , 2013 , 557 : 61 - 67 .

李根 , 杨洁 , 杨静 . 锂云母分解及溶出锂工艺的研究进展评述 [J]. 硅酸盐通报 , 2017 , 36 ( 5 ): 1599 - 1604 .

Li G , Yang J , Yang J . Literature review of extracting lithium from lepidolite [J]. Bulletin of the Chinese Ceramic Society , 2017 , 36 ( 5 ): 1599 - 1604 .

冯文平 , 谢晶磊 , 汤建良 , 等 . 硫酸浸取锂云母提锂方法的研究 [J]. 精细化工中间体 , 2016 , 46 ( 3 ): 66 - 69 .

Feng W P , Xie J L , Tang J L , et al . Study on extraction of lithium from lepidolite [J]. Fine Chemical Intermediates , 2016 , 46 ( 3 ): 66 - 69 .

李良彬 , 刘明 , 彭爱平 , 等 . 锂云母提锂工艺及工业化应注意的问题 [J]. 世界有色金属 , 2014 , ( 8 ): 37 - 39 .

Li L B , Liu M , Peng A P , et al . Problems in the process of lithium recovery from lepidolite and its comercialisation [J]. World Nonferrous Metals , 2014 , ( 8 ): 37 - 39 .

舒启溢 . 锂云母浸取锂制备碳酸锂的工艺研究 [D]. 南昌 : 南昌大学 , 2012 .

Shu Q Y . Study of leaching lithium from lepidolite and preparation of lithium carbonate [D]. Nanchang : Nanchang University , 2012 .

Kuang G , Li H , Hu S , et al . Recovery of aluminium and lithium from gypsum residue obtained in the process of lithium extraction from lepidolite [J]. Hydrometallurgy , 2015 , 157 : 214 - 218 .

旷戈 , 郭慧 , 刘善军 , 等 . 锂云母矿石提锂浸取液体系中除铝的研究 [J]. 稀有金属 , 2014 , 38 ( 1 ): 102 - 107 .

Kuang G , Guo H , Liu S J , et al . Aluminum recovery in leaching solution of lepidolite after lithium extraction [J]. Chinese Journal of Raremetals , 2014 , 38 ( 1 ): 102 - 107 .

伍习飞 . 宜春锂云母提锂工艺及机理研究 [D]. 长沙 : 中南大学 , 2012 .

Wu X F . Study on the mechanism of lithium extraction process of lepidolite in Yichun [D]. Changsha : Central South University , 2012 .

杨仁武 , 肖根正 , 黎云龙 , 等 . 叔BAMBP萃取分离铷、铯新工艺 [J]. 江西冶金 , 1986 , 6 ( 2 ): 14 - 16 .

Yang R W , Xiao G Z , Li Y L , et al . A new process for the separation of cesium and rhodium using tertiary BAMBP extraction [J]. Jiangxi Metallurgy , 1986 , 6 ( 2 ): 14 - 16 .

肖艳 , 王武尚 , 李华 . 氯铝酸离子液体催化合成 t -BAMBP [J]. 核化学与放射化学 , 2010 , 32 ( 2 ): 93 - 98 .

Xiao Y , Wang W S , Li H . Synthesis of t -BAMBP in chloride-aluminium (Ⅲ) chloride ionic liquids [J]. Journal of Nuclear and Radiochemistry , 2010 , 32 ( 2 ): 93 - 98 .

邓飞跃 , 甘文文 . 锂云母提锂母液中钾铷铯的综合利用 [J]. 矿冶工程 , 1999 , 19 ( 1 ): 50 - 52 .

Deng F Y , Gan W W . Comprehensive utilization of potassium, rubdium and cesium in mother liquor after extracting lithium from lepidolite [J]. Mining and Metallurgical Engineering , 1999 , 19 ( 1 ): 50 - 52 .

石颖 . 石灰石法锂云母综合冶炼工艺流程 [J]. 稀有金属 , 1982 , ( 3 ): 9 - 13 .

Shi Y . Limestone method lepidolite comprehensive smelting process [J]. Chinese Journal of Rare Metals , 1982 , ( 3 ): 9 - 13 .

徐瑞锋 , 黄少文 , 罗琦 , 等 . 锂云母提锂渣对水泥基装饰砂浆性能的影响 [J]. 非金属矿 , 2018 , 41 ( 1 ): 27 - 29 .

Xu R F , Huang S W , Luo Q , et al . Influenced research of lithium slag extracted from lithium mica on the properties of decorative mortar [J]. Non-Metallic Mines , 2018 , 41 ( 1 ): 27 - 29 .

颜群轩 . 锂云母中有价金属的高效提取研究 [D]. 长沙 : 中南大学 , 2012 .

Yan Q X . Extraction of valuable metals from lepidolite [D]. Changsha : Central South University , 2012 .

王丁 , 陈树 , 刘昕昕 , 等 . 锂云母碱溶法提锂新工艺研究 [J]. 无机盐工业 , 2014 , 46 ( 9 ): 26 - 28 .

Wang D , Chen S , Liu X X , et al . New process of lithium extraction from lepidolite by alkali dissolution [J]. Inorganic Chemicals Industry , 2014 , 46 ( 9 ): 26 - 28 .

Yan Q , Li X , Wang Z , et al . Extraction of valuable metals from lepidolite [J]. Hydrometallurgy , 2012, s 117 / 118 ( 4 ): 116 - 118 .

王林生 , 汪发波 , 文小强 . P204萃取法对锂云母浸出液的除杂效果研究 [J]. 稀有金属与硬质合金 , 2013 , 41 ( 1 ): 24 - 27 .

Wang L S , Wang F B , Wen X Q . Study on impurity removal efficiency of the extraction process with P204 from lepidolite leaching solution [J]. Rare Metals Cemented Carbides , 2013 , 41 ( 1 ): 24 - 27 .

吴宋超 . 锂云母提锂一次净化渣制取硫酸铝的研究 [D]. 南昌 : 江西理工大学 , 2011 .

Wu S C . Study on aluminum sulfate preparation from lithium recovry residue of lepidolite [D]. Nanchang : Jiangxi University of Science and Technology , 2011 .

Yan Q X , Xin-Hai L I , Wang Z X , et al . Extraction of lithium from lepidolite using chlorination roasting-water leaching process [J]. Transactions of Nonferrous Metals Society of China , 2012 , 22 ( 7 ): 1753 - 1759 .

仇世源 , 张景怀 , 阚素荣 , 等 . 宜春锂云母食盐压煮法制取碳酸锂新工艺 [J]. 新疆有色金属 , 1996 , ( 1 ): 44 - 48 .

Qiu S Y , Zhang J H , Kan S R , et al . Lithium carbonate preparation from Yichun lepidolite by high pressure thermohydrolysis method with sodium chloride [J]. Xinjiang Nonferrous Metals , 1996 , ( 1 ): 44 - 48 .

Martin G , Pätzold C , Bertau M . Integrated process for lithium recovery from zinnwaldite [J]. International Journal of Mineral Processing , 2017 , 160 : 8 - 15 .

Bertau M , Voigt W , Schneider A , et al . Lithium recovery from challenging deposits: zinnwaldite and magnesium-rich salt lake brines [J]. Chemie Ingenieur Technik , 2017 , 69 ( 1 ): 11 - 13 .

Jandova J , Dvorak P , Vu H N . Processing of zinnwaldite waste to obtain Li 2 CO 3 [J]. Hydrometallurgy , 2010 , 103 ( 1 / 2 / 3 / 4 ): 12 - 18 .

Jandová J , Dvořák P , Formánek J , et al . Recovery of rubidium and potassium alums from lithium-bearing minerals [J]. Hydrometallurgy , 2012, 119 / 120 ( 5 ): 73 - 76 .

Jandova J , Vu H N , Belkova T , et al . Obtaining Li 2 CO 3 from zinnwaldite wastes [J]. Ceramics-Silikaty , 2009 , 53 ( 2 ): 108 - 112 .

Siame E , Pascoe R D . Extraction of lithium from micaceous waste from china clay production [J]. Minerals Engineering , 2011 , 24 ( 14 ): 1595 - 1602 .

Schneider A , Schmidt H , Meven M , et al . Lithium extraction from the mineral zinnwaldite (I): Effect of thermal treatment on properties and structure of zinnwaldite [J]. Minerals Engineering , 2017 , 111 : 55 - 67 .

Sitando O , Crouse P L . Processing of a zimbabwean petalite to obtain lithium carbonate [J]. International Journal of Mineral Processing , 2012 , 102 : 45 - 50 .

Siegens H , Roder O . Process for the production of lithium salts : US 73402734 A [P]. 1936-05-12 .

Harold M , Cohen S L , Schafer G H . Use of amblygonite as an additive in the lime-roasting of lithium-aluminosilicate ores : US 54918655 A [P]. 1957-01-01 .

Frevel L K , Kressley L J . Separation of lithium from lithium bearing micas and amblygonite : US 79424159 A [P]. 1962-05-01 .

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