CBD方法制备的Zn(O,S)薄膜的微结构表征及性能

皇甫丽娟; 江亚晓; 张森; 许婷婷; 徐俊敏; 王新昌; 陈永生

doi:10.11949/j.issn.0438-1157.20180237

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CBD方法制备的Zn(O,S)薄膜的微结构表征及性能

材料化学工程与纳米技术 | 更新时间：2025-12-10

- CBD方法制备的Zn(O,S)薄膜的微结构表征及性能
- Microstructural characterization and properties of Zn(O,S) thin film prepared by CBD method
- 化工学报 2018年第8期页码：3732-3739
- 作者机构：
  
  郑州大学物理工程学院, 材料物理教育部重点实验室,河南,郑州,450052
- 作者简介：
- 基金信息：
- DOI：10.11949/j.issn.0438-1157.20180237
  中图分类号： B34
- 网络首发：2018-08-05，
  
  纸质出版：2018-08-05
- 稿件说明：
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皇甫丽娟, 江亚晓, 张森, 等. CBD方法制备的Zn(O,S)薄膜的微结构表征及性能[J]. 化工学报, 2018,(8):3732-3739.

HUANGFU Lijuan, JIANG Yaxiao, ZHANG Sen, et al. Microstructural characterization and properties of Zn(O,S) thin film prepared by CBD method[J]. CIESC Journal, 2018, (8): 3732-3739.
皇甫丽娟, 江亚晓, 张森, 等. CBD方法制备的Zn(O,S)薄膜的微结构表征及性能[J]. 化工学报, 2018,(8):3732-3739. DOI： 10.11949/j.issn.0438-1157.20180237.

HUANGFU Lijuan, JIANG Yaxiao, ZHANG Sen, et al. Microstructural characterization and properties of Zn(O,S) thin film prepared by CBD method[J]. CIESC Journal, 2018, (8): 3732-3739. DOI： 10.11949/j.issn.0438-1157.20180237.

摘要

对低温化学浴沉积方法制备的Zn（O，S）薄膜进行了研究，通过XPS、SEM、XRD、拉曼光谱、PL谱、紫外-可见吸收光谱等手段对薄膜的形貌、结构及组成进行系统表征，探究了其作为钙钛矿电池电子传输层的可能性。研究表明：化学浴沉积（CBD）方法制备的Zn（O，S）薄膜为ZnO、ZnS和ZnOS合金的复合膜；该薄膜对CH3NH3PbI3光吸收层具有与TiO2相当的电子抽提能力，是一种可供选择的高效柔性钙钛矿电池电子传输层材料。

Abstract

Zn(O

S) thin film has been successfully used in Cu(In

Ga)Se2 based solar cells. However

its application in perovskite solar cell has not been reported. In this paper

Zn(O

S) film prepared by low temperature chemical bath deposition has been studied. The morphology

structure and composition of the film were characterized by XPS

SEM

XRD

Raman spectra

PL spectra and UV-Visible absorption spectra. The band structure of the thin film is analyzed by UPS. The possibility of Zn(O

S) film being the electron transport layer of the perovskite solar cell is explored. The research shows that the Zn(O

S) thin film deposited by CBD belongs to the mixed membrane. The composition of the phase consists of ZnO

ZnS and ZnOS alloys. The prepared Zn(O

S) film has the equivalent electronic extraction capability to the CH3NH3PbI3 optical absorption layer with TiO2. It is a kind of high efficient flexible perovskite battery electronic transport layer material.

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