ZHU Guojian, FAN Tianfeng, WANG Dehai, et al. Quantitative description of oxygen inhibition in radical UV-curing[J]. CIESC Journal, 2018, (8): 3740-3746.
ZHU Guojian, FAN Tianfeng, WANG Dehai, et al. Quantitative description of oxygen inhibition in radical UV-curing[J]. CIESC Journal, 2018, (8): 3740-3746.DOI: 10.11949/j.issn.0438-1157.20180155.
Curing rate curve was multimodally fitted by the peak separation method based on the consideration that free radical UV-curing process is generally caused by multiple active centers. A parameter of tV-inh
which is the intersection of abscissa and the tangent line of the inflection point of curing rate curve
is assigned to evaluate oxygen inhibition extent. The results showed a more oxygen-sensitive curing reaction could be isolated by overlapping peak resolving
and the relationship between tV-inh and initiator content x turned out to be fulfilled the algebraic expression of tV-inh=A/x+B optimally
and the value of (A+B) could be used to describe the oxygen inhibition trend for a given curing formula.