JI Ruijun, XU Wenqing, WANG Jian, et al. Research progress of ozone oxidation denitrification technology[J]. CIESC Journal, 2018, (6): 2353-2363.DOI: 10.11949/j.issn.0438-1157.20171596.
Ozone oxidation denitrification technology first oxidizes NO into water-soluble nitrogen oxides such as NO2 and N2O5
followed by absorption process for denitration
which is different from reduction denitration technologies. It has been widely used in NOx emission control of catalytic cracking and industrial boiler flue gases. The technological characteristics and reaction kinetics of ozone oxidation denitrification technology were discussed
the oxidation selectivities of NO in complex flue gases were analyzed
and the effects of ozone and NO molar ratio
reaction temperature and residence time on the composition of oxidation products were studied. After that
the influence of absorbents
absorption gas compositions and additives on absorption efficiencies was analyzed by elaborating the principle of synergistic absorption of sulfur dioxide and nitrogen oxides in both wet and semi dry desulfurization processes. Based on the above discussion
the deficiencies in the research of ozone oxidation denitration technology were put forward and the future development of this technology was proposed.