WANG Xingdong, LI Chunxing, YOU Futian, et al. Migration and transformation of nitrogen in sewage sludge during hydrothermal treatment[J]. CIESC Journal, 2018, (6): 2688-2696.
WANG Xingdong, LI Chunxing, YOU Futian, et al. Migration and transformation of nitrogen in sewage sludge during hydrothermal treatment[J]. CIESC Journal, 2018, (6): 2688-2696.DOI: 10.11949/j.issn.0438-1157.20171403.
Hydrothermal treatment of sewage sludge was conducted by using a stainless steel autoclave reactor at different temperature. This study aims to investigate the influence of reaction temperature on the migration and transformation of nitrogen in sewage sludge during hydrothermal treatment. The pathway of nitrogen transformation during hydrothermal treatment was also comprehensively analyzed. The results showed that nitrogen was mainly distributed into solid and liquid products after hydrothermal treatment. The percentage of nitrogen distribution in liquid products was increased with the increasing reaction temperature. During hydrothermal treatment
the inorganic nitrogen in sewage sludge was almost completely hydrolyzed to ammonia nitrogen and nitrates nitrogen. The labile protein was decomposed into organic nitrogen and ammonia nitrogen
and the organic nitrogen was further decomposed to ammonia nitrogen. However
the stable protein can be transformed into the forms of pyridine nitrogen
pyrrole nitrogen
quaternary nitrogen and nitrile nitrogen. Each form of nitrogen can be decomposed into ammonia nitrogen at a high reaction temperature. In summary
the nitrogen in sewage sludge was gradually transformed from solid products to liquid samples with the increasing hydrothermal reaction temperature
and the nitrogen remained in liquid samples major in the form of organ nitrogen and ammonia nitrogen.