SHI Xin, MA Xiaobin, YANG Fei, et al. Effect and mechanism of BEM/PMSQ hybrid pour point depressant on Qinghai waxy crude oil[J]. CIESC Journal, 2017, (8): 3014-3022.
SHI Xin, MA Xiaobin, YANG Fei, et al. Effect and mechanism of BEM/PMSQ hybrid pour point depressant on Qinghai waxy crude oil[J]. CIESC Journal, 2017, (8): 3014-3022.DOI: 10.11949/j.issn.0438-1157.20170249.
Based on the outstanding organic compatibility and the micro spherical morphology of polymethylsilsesquioxane (PMSQ) microspheres
BEM/PMSQ hybrid pour point depressant was prepared by melt blending method. Then
the effect of BEM/PMSQ hybrid pour point depressant on the pour point
viscoelasticity
viscosity and yield value of Qinghai waxy crude oil was evaluated by rheological experiment and the morphology of wax crystals was observed by the polarizing microscope. The results showed that the pour point of the undoped crude oil was 27.0℃; compared with the same dosage of the neat BEM (100 μg·g-1)
BEM/PMSQ 2% hybrid pour point depressant has the best performance
which can further reduce the pour point of 6.0℃
the gelation point of 4.3℃
the apparent viscosity of 39.0% and G' of 62.0%. The dispersion state of PMSQ microspheres and BEM/PMSQ hybrid pour point depressant in the dodecane showed that BEM were adsorbed on the surface of PMSQ microspheres
and acted as the wax crystal nucleation templates in the crude oil
thus resulting in the formation of the compact wax crystal structure and coating with less liquid oil