DING Jing, HUANG Chenglong, DU Lichan, et al. Thermal conductivity of liquid carbonate salt doped with magnesium powder[J]. CIESC Journal, 2017, (11): 4407-4413.
DING Jing, HUANG Chenglong, DU Lichan, et al. Thermal conductivity of liquid carbonate salt doped with magnesium powder[J]. CIESC Journal, 2017, (11): 4407-4413.DOI: 10.11949/j.issn.0438-1157.20170042.
In order to improve the low thermal conductivity performance of carbonate molten salt
it is proposed to dope metal magnesium powder with ternary carbonate molten salt (Li2CO3-Na2CO3-K2CO3) to strengthen the thermal conductivity. The static melting method was used to prepare the composite carbonate salts with 1%(mass) or 2%(mass) magnesium powder. The morphology
structure
liquid density
specific heat capacity
and thermal diffusivity were characterized by the scanning electron microscope-energy dispersive X-ray spectrometer (SEM-EDX)
Archimedes method
the differential scanning calorimeter (DIN specific heat measure standard) and the laser flash method
respectively. The thermal conductivity was finally calculated based on the density
specific heat capacity
and thermal diffusivity. The results showed that the introducing of magnesium powder changed the morphology of pure eutectic (ternary carbonate salt)
a large number of spherical particles (2-5 μm) were detected in the composite salts. Comparison with the pure eutectic
the liquid density
thermal diffusivity and thermal conductivity of salt compound doped magnesium powder were enhanced
and the liquid specific heat capacity was diminished. The mean thermal conductivity of salt compound doped with 1% or 2% magnesium powder was enhanced by 21.67% and 19.07%
respectively. So
the 1% salt composite should be the promising HTF due to the enhancement of density