ZHANG Hedong, GAO Zuopeng, AO Wenya, et al. Characterization and analysis of textile sludge char from moving bed pyrolyser under microwave irradiation[J]. CIESC Journal, 2017, (6): 2510-2518.
ZHANG Hedong, GAO Zuopeng, AO Wenya, et al. Characterization and analysis of textile sludge char from moving bed pyrolyser under microwave irradiation[J]. CIESC Journal, 2017, (6): 2510-2518.DOI: 10.11949/j.issn.0438-1157.20170003.
The paper investigated pyrolysis of textile sludge in a moving bed pyrolyser under microwave irradiation. Microwave power
temperature
gas and solid residence times
and catalysts were studied. Elemental analysis
scanning electron microscopy (SEM)
BET surface area analysis
X-ray fluorescence spectroscopy (XRF)
X-ray diffraction (XRD) and inductively coupled plasma mass spectrometry (ICP-MS) were conducted and analyzed. It showed that the sludge char (SC) yield decreased and non-condensable gas yield increased as temperature increased. At 750℃
the SC yield was 63.87%(mass). Addition of CaO and Fe increased SC yield
and the H2
CO and CH4 contents
and decreased CO2 content in the non-condensable gas. Maximum H2 content was up to 64.17%. The contents of C
H and O in SC decreased as temperature increased
while S content increased. The BET surface area reached the maximum at 550℃
which was consistent with the SEM observation. The ICP-MS results showed that the heavy metals in SC met the requirements of emissions standards in China. The moving bed pyrolyser under microwave irradiation provided a promising prospect to efficiently treat and dispose TS.