JIN Yulong, ZHAO Ning, CHENG Ruihua, et al. Research progress of bimetallic catalysts for bimodal polyethylene synthesis[J]. CIESC Journal, 2017, (2): 485-495.
JIN Yulong, ZHAO Ning, CHENG Ruihua, et al. Research progress of bimetallic catalysts for bimodal polyethylene synthesis[J]. CIESC Journal, 2017, (2): 485-495.DOI: 10.11949/j.issn.0438-1157.20161172.
Bimodal polyethylene are widely used to produce high performance pipes
such as PE100 and PE100RC
and shows increasing importance in polyethylene market because of their excellent mechanical and processing properties. Nowadays
commercialized bimodal polyethylene is synthesized primarily in tandem-reactor process
which needs high energy consumption and capital investment in equipment
beside
the technology is under monopoly of foreign companies. By contrast
bimodal polyethylene synthesis using bimetallic catalyst in single reactor process is becoming research hotspot in domestic and abroad
because this process is more environment friendly and needs much lower cost in equipment investment and operation. Recent work in this group on Cr-based bimetallic catalysts is reviewed. Development on other bimetallic catalysts is also introduced and future trend is prospected.