高韧性聚醚脲型苯并嗪树脂的合成及力学性能

袁伟; 钱莹; 史铁钧; 何涛; 陈杨

doi:10.11949/j.issn.0438-1157.20160656

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高韧性聚醚脲型苯并嗪树脂的合成及力学性能

材料化学工程与纳米技术 | 更新时间：2025-11-26

- 高韧性聚醚脲型苯并嗪树脂的合成及力学性能
- Synthesis and mechanical properties of high toughness benzoxazine based on polyether-urea
- 化工学报 2017年第1期页码：385-390
- 作者机构：
  
  合肥工业大学化学与化工学院,安徽,合肥,230009
- 作者简介：
- 基金信息：
- DOI：10.11949/j.issn.0438-1157.20160656
  中图分类号： 631
- 网络首发：2017-01-05，
  
  纸质出版：2017-01-05
- 稿件说明：
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袁伟, 钱莹, 史铁钧, 等. 高韧性聚醚脲型苯并嗪树脂的合成及力学性能[J]. 化工学报, 2017,(1):385-390.

YUAN Wei, QIAN Ying, SHI Tiejun, et al. Synthesis and mechanical properties of high toughness benzoxazine based on polyether-urea[J]. CIESC Journal, 2017, (1): 385-390.
袁伟, 钱莹, 史铁钧, 等. 高韧性聚醚脲型苯并嗪树脂的合成及力学性能[J]. 化工学报, 2017,(1):385-390. DOI： 10.11949/j.issn.0438-1157.20160656.

YUAN Wei, QIAN Ying, SHI Tiejun, et al. Synthesis and mechanical properties of high toughness benzoxazine based on polyether-urea[J]. CIESC Journal, 2017, (1): 385-390. DOI： 10.11949/j.issn.0438-1157.20160656.

摘要

首先用端氨基聚醚、二苯甲烷二异氰酸酯（MDI）制备出两端含有氨基的聚醚型聚脲，然后用合成的聚醚型聚脲、双酚A和多聚甲醛为原料进行曼尼希反应合成出聚醚脲型苯并（口恶）嗪（PUBZ），经高温固化后形成韧性优良的树脂。用FTIR、1H NMR分析了PUBZ的化学结构，证实了所得的目标产物；用DSC对PUBZ的固化特性进行研究；用拉伸测试分析了含不同长度聚醚链PUBZ树脂的力学性能；用DMA和TGA测试分析了含不同长度聚醚链PUBZ树脂的热性能。结果表明：聚醚链段越长，PUBZ的固化温度越高，PUBZ树脂的玻璃化转变温度越低，相反其热稳定性越好；在力学性能中端氨基聚醚D-400/PUBZ树脂的韧性最好。

Abstract

A new class of polyether-urea-based benzoxazine(PUBZ) exhibits perfect toughness properties after thermal treatment has been developed and synthesized via two steps.Firstly

amine-terminated polyether-based polyurea was synthesized using amine-terminated polyether and diphenyl methane diisocyanate(MDI) as raw materials.Secondly

PUBZ was prepared from amine-terminated polyether-based polyurea

bisphenol-A and paraformaldehyde through Mannich reaction.The structure of PUBZ has been confirmed by FTIR and 1H NMR.The curing behavior was characterized by DSC.The effect of different length of polyether chains on the mechanical properties of PUBZ has been evaluated by dynamic mechanical analysis(DMA) in a tensile deformation.Thermal properties of PUBZ have been studied by DMA and thermogravimetric analysis(TGA).The results showed that the longer polyether chains

the higher curing temperature of the PUBZ.The lower glass transition temperature of the PUBZ

the better thermal stability.When the molecular weight of amine-terminated polyether was 400 and D-400/PUBZ resin exhibited the highest toughness.

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