磁性粉煤灰空心微珠表面印迹聚合物选择性识别头孢氨苄

毛艳丽; 罗世田; 吴俊峰; 刘彪; 康海彦; 朱慧杰; 王红强; 王巷文

doi:10.11949/j.issn.0438-1157.20160196

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磁性粉煤灰空心微珠表面印迹聚合物选择性识别头孢氨苄

分离工程 | 更新时间：2025-11-26

- 磁性粉煤灰空心微珠表面印迹聚合物选择性识别头孢氨苄
- Selective recognition of cefalexin by magnetic molecularly imprinted polymers based on magnetic fly-ash-cenosphere
- 化工学报 2016年67卷第10期页码：4273-4281
- 作者机构：
  
  1. 河南城建学院市政与环境工程学院,河南,平顶山,467036
  2. 平顶山市建设工程质量监督站,河南,平顶山,467036
  3. 华中科技大学化学与化工学院,湖北,武汉,430074
- 作者简介：
- 基金信息：
- DOI：10.11949/j.issn.0438-1157.20160196
  中图分类号： 592
- 网络首发：2016-10-05，
  
  纸质出版：2016-10-05
- 稿件说明：
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毛艳丽, 罗世田, 吴俊峰, 等. 磁性粉煤灰空心微珠表面印迹聚合物选择性识别头孢氨苄[J]. 化工学报, 2016,67(10):4273-4281.

MAO Yanli, LUO Shitian, WU Junfeng, et al. Selective recognition of cefalexin by magnetic molecularly imprinted polymers based on magnetic fly-ash-cenosphere[J]. CIESC Journal, 2016, 67(10): 4273-4281.
毛艳丽, 罗世田, 吴俊峰, 等. 磁性粉煤灰空心微珠表面印迹聚合物选择性识别头孢氨苄[J]. 化工学报, 2016,67(10):4273-4281. DOI： 10.11949/j.issn.0438-1157.20160196.

MAO Yanli, LUO Shitian, WU Junfeng, et al. Selective recognition of cefalexin by magnetic molecularly imprinted polymers based on magnetic fly-ash-cenosphere[J]. CIESC Journal, 2016, 67(10): 4273-4281. DOI： 10.11949/j.issn.0438-1157.20160196.

摘要

利用共沉淀法制备了粉煤灰空心微珠磁性复合材料（MFACs），以乙烯基改性的MFACs为基质材料，利用乳液聚合法制备磁性粉煤灰空心微珠表面印迹聚合物（MMIPs）。通过SEM、FT-IR、TGA、XRD和VSM等方法对其物理化学性质进行表征，其比表面积123.65 m2·g-1，且具有较好的热稳定性、超顺磁性（Ms=12.155 emu·g-1）。通过系列吸附实验研究表明，Langmuir等温模型能较好地拟合MMIPs对头孢氨苄（cefalexin，CFX）的吸附平衡数据，25℃时MMIPs的单分子层吸附容量为69.55 mg·g-1。准二级动力学模型能较好地描述MMIPs对CFX吸附动力学行为，选择性实验研究表明，MMIPs对CFX具有较好地选择识别性。结合高效液相色谱分析技术，MMIPs已成功应用于环境样品中痕量CFX的分离/富集。

Abstract

Magnetic fly-ash-cenospheres (MFACs) were firstly prepared via an effective coprecipitation method

and then the surface of the MFACs was endowed with reactive vinyl groups through modification with 3-(methacryloyloxy)propyl trimethoxysilane (MPS). Based on the MFACs-MPS

the magnetic molecularly imprinted polymers (MMIPs) were further synthesized for the selective recognition of cefalexin (CFX). MMIPs were characterized by SEM

FT-IR

XRD

TGA and VSM

which indicated that the MMⅡPs exhibited magnetic sensitivity (Ms=12.155 emu·g-1)

thermal stability and the larger specific surface area (123.65 m2·g-1). Batch mode adsorption studies were carried out to investigate adsorption equilibrium

kinetics and selective recognition. The Langmuir isotherm model was fitted well to the equilibrium data

and the monolayer adsorption capacity of the MMIPs was 69.55 mg·g-1 at 25℃. The selective recognition experiments demonstrated high affinity and selectivity towards CFX over structurally related antibiotic compounds. Combined with high performance liquid chromatographic analysis technology

the prepared MMⅡPs were successfully applied to the separation of CFX from environmental samples.

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