YANG Xiaoli, SU Xiong, YANG Xiaofeng, et al. Stabilization mechanism of supported metal catalyst[J]. CIESC Journal, 2016, (1): 73-82.DOI: 10.11949/j.issn.0438-1157.20151556.
Supported metal catalysts play a pivotal role for many reactions in industrial processes
including petroleum refining
environmental protection and materials synthesis. However
the active metal centers suffer from severe sintering under real working condition
which will subsequently lead to a loss of its activity. Therefore
the stability of supported catalysts becomes a critical issue to its catalytic application. In this review
the aggregation and stabilization mechanisms of supported metal catalyst were briefly discussed according to the two different aggregation models of metal particles
i.e.
Ostwald ripening and coalescence of smaller particles. Accordingly
the corresponding stabilization strategies
including physical methods based on encapsulation and chemical methods by forming chemical bonds
were introduced. The understanding of stabilization mechanism of supported metal catalyst would not only benefit for the development of new catalysts with promoted stability
but also provide theoretical guidance for the optimization of industrial catalysts.