SHEN Peng, LI Juan, YANG Xingcheng, et al. Change in microstructures of hard elastic HDPE cast film during cold-stretching process[J]. CIESC Journal, 2016, (7): 3063-3070.
SHEN Peng, LI Juan, YANG Xingcheng, et al. Change in microstructures of hard elastic HDPE cast film during cold-stretching process[J]. CIESC Journal, 2016, (7): 3063-3070.DOI: 10.11949/j.issn.0438-1157.20151398.
The hard elastic high density polyethylene(HDPE)cast film was cold-stretched uniaxially with different stretching ratios and rates in a process of preparing HDPE microporous membranes. AFM
FE-SEM and WAXD were used to observe the variations in the lamellar structure during the cold-stretching processes
and the microporous structure of resulting microporous membranes was evaluated with measurements of porosity and permeability. It was found that increasing cold-stretching ratio could promote the separation of row-nucleated lamellar structure in the films
and be beneficial to the increase of porosity and permeability in the microporous membranes. However
over high cold-stretching ratio led to the collapse of the lamellae
destroying the microporous structure. With the increase of stretching rates
the lamellae was separated to a greater extent
resulting in generation of more micropores and more uniform distribution. During the cold-stretching
the broken micro-second crystals at the lamellae edge and the crystallized long tie chains between lamellae converted to bridges connecting separated lamellae.