厨余垃圾水热液化制取生物燃料

张冀翔; 王东; 蒋宝辉; 魏耀东

doi:10.11949/j.issn.0438-1157.20151344

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厨余垃圾水热液化制取生物燃料

能源和环境工程 | 更新时间：2025-12-10

- 厨余垃圾水热液化制取生物燃料
- Hydrothermal liquefaction of kitchen waste for bio-oil production
- 化工学报 2016年第4期页码：1475-1482
- 作者机构：
  
  中国石油大学(北京)重质油国家重点实验室,北京,102249
- 作者简介：
- 基金信息：
- DOI：10.11949/j.issn.0438-1157.20151344
  中图分类号： K6
- 网络首发：2016-04-05，
  
  纸质出版：2016-04-05
- 稿件说明：
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张冀翔, 王东, 蒋宝辉, 等. 厨余垃圾水热液化制取生物燃料[J]. 化工学报, 2016,(4):1475-1482.

ZHANG Jixiang, WANG Dong, JIANG Baohui, et al. Hydrothermal liquefaction of kitchen waste for bio-oil production[J]. CIESC Journal, 2016, (4): 1475-1482.
张冀翔, 王东, 蒋宝辉, 等. 厨余垃圾水热液化制取生物燃料[J]. 化工学报, 2016,(4):1475-1482. DOI： 10.11949/j.issn.0438-1157.20151344.

ZHANG Jixiang, WANG Dong, JIANG Baohui, et al. Hydrothermal liquefaction of kitchen waste for bio-oil production[J]. CIESC Journal, 2016, (4): 1475-1482. DOI： 10.11949/j.issn.0438-1157.20151344.

摘要

以厨余垃圾为原料进行水热液化

考察了反应温度和料液比对产物分布的影响。温度320℃、料液比1:15时

生物油产率最高为16.7%

继续升高温度或降低料液比将促进气体产物生成。与重质原油、常减压渣油相比

生物油氧、氮元素含量较高

热值为32.33~34.82 MJ·kg-1

其中汽油和煤柴油馏分超过50%。利用GC-MS、FT-IR和FT-ICR MS对生物油化学组成、官能团和杂原子组成进行了表征。生物油是一种复杂混合物体系

已检测出烃类、酸类、醛类、酮类、酯类、胺类、酚类、醇类和含氮杂环类等多种物质

对其酸性组分进一步分析显示

含氧组分主要是O2、O3类化合物

含氮组分主要是N1O2、N1O3和N1O4类化合物。

Abstract

Hydrothermal liquefaction of kitchen waste was processed for bio-oil production. The effects of reaction temperature and solid-liquid ratio on products distribution and bio-oil properties were investigated systematically. The highest bio-oil yield of 16.7% was obtained at 320℃ and 1:15. Further increasing temperature or decreasing solid-liquid ratio would promote gas formation. Bio-oil had higher oxygen and nitrogen content compared to heavy oil or residue oil. Over 50% of bio-oil fraction was in the naphtha

kerosene and AGO range. The higher heating value of bio-oil was 32.33—34.82 MJ·kg-1. Bio-oil was characterized using GC-MS

FT-IR and FT-ICR MS. Bio-oil was a complex mixture composed of hydrocarbons

acids

aldehydes

ketones

esters

amines

phenols

alcohols and N-heterocyclic compounds. Further analysis on the acidic compounds in bio-oil indicated that oxygenated compounds were primarily comprised of O2 and O3 species

nitrogenous compounds were mainly N1O2、N1O3 and N1O4 species.

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