LENG Yixin, TAN Qian, HUANG Chunxiang, et al. Determination of metastable zone width and induction period of L-tartaric acid aqueous solution[J]. CIESC Journal, 2016, (6): 2433-2439.
LENG Yixin, TAN Qian, HUANG Chunxiang, et al. Determination of metastable zone width and induction period of L-tartaric acid aqueous solution[J]. CIESC Journal, 2016, (6): 2433-2439.DOI: 10.11949/j.issn.0438-1157.20151174.
The crystallization metastable zone width and induction period of L-tartaric acid in water were measured by laser method at the temperature range of 20-60℃. The influences of saturation temperature
cooling rate and agitation rate on the metastable zone width and the effect of supersaturation on the induction period were explored
respectively. The results showed that the crystallization metastable zone width became narrow with rising saturation temperature and agitation rate
and decreasing cooling rate. The apparent nucleation series m and the nucleation rate equation were given. Furthermore
the experimentally measured crystallization induction period decreased with increasing supersaturation S. The solid-liquid interfacial tension of L-tartaric acid in water was calculated at 20℃ and 25℃ on basis of the classical nucleation theory and induction period data.