LI Chunlin, XIE Hua, LIU Na, et al. Preparation of monodisper microsphere by controlled droplet solidification[J]. CIESC Journal, 2015, (9): 3654-3660.
LI Chunlin, XIE Hua, LIU Na, et al. Preparation of monodisper microsphere by controlled droplet solidification[J]. CIESC Journal, 2015, (9): 3654-3660.DOI: 10.11949/j.issn.0438-1157.20150919.
Uniform size micromeres functional material gets a lot of attention in the fields of polymer chemistry
medicine and chemical industry
catalysis and separation. It is incovenient to prepare monodisperse and uniformity micrometer material by current conventional technology. With microfluidic technology
the droplet was generated in the chip and following to solidify the droplet online to prepare various of monodisperse and size uniformity microsphere. Since the droplet was a Si sol of slow-solidified
the nonporous SiO2 microsphere with a BET surface area of 572 m2·g-1 and a variance coefficient of microsphere diameters of about 2% were produced by introducing precipitator from the interface of droplet. Because the droplets were a material of fast-precipited
such as Zn
Fe
or Cu ion
a hollow microsphere consisted of hydrate oxide or mixed oxide was produced. As the droplet contains both materials of fast-precipitated and flow-solidified
such as Si sol containing of Fe ion
SiO2 microsphere with a homogeneous dispersed Fe in it was obtained by adjusting the introducing velocity of precipitator into the droplet.