LIU Juan, CHI Yong, SHU Di. Effects of process parameters on hydrothermal carbonization of cellulose[J]. CIESC Journal, 2015, (12): 4980-4987.DOI: 10.11949/j.issn.0438-1157.20150793.
Biomass is the fourth largest source of energy and conventional incineration will not only pollute the environment
but also is a waste of energy. Hydrothermal carbonization (HTC) is a novel biomass conversion technology
yielding carbonaceous products (HTC char) favorable for wider range of applications. The impact of temperature and reaction time on hydrothermal carbonization of microcrystalline cellulose and carbon distribution was studied
and physical
chemical
thermal and structural characteristics of HTC char also investigated. The results show that during hydrothermal carbonization of microcrystalline cellulose a significant fraction of initially present carbon
about 71%-75%
is stayed in HTC char
while only a small fraction of the carbon is transferred the liquid and gas-phases. As the temperature and reaction time increase
the HTC char yield and O/C atom ratio decrease
and its heat value increases. SEM images show that HTC char consists of aggregates of microspheres. FTIR spectra indicate that dehydration and aromatization processes take place during hydrothermal carbonization and HTC char possesses hydroxyl groups and carbonyl groups.