LI Ji, ZHOU Jiabei, ZHU Jiahua, et al. Mechanism and model of ammonia-based carbon dioxide trapping enhanced by gypsum particles[J]. CIESC Journal, 2015, (8): 3218-3224.
LI Ji, ZHOU Jiabei, ZHU Jiahua, et al. Mechanism and model of ammonia-based carbon dioxide trapping enhanced by gypsum particles[J]. CIESC Journal, 2015, (8): 3218-3224.DOI: 10.11949/j.issn.0438-1157.20150741.
a mass transfer model of gas-liquid reaction absorption enhanced by reactive particles was established for the absorption of CO2 into aqueous ammonia suspension with gypsum particles. The absorption enhancement factor was derived theoretically as E=1/λ*+qβλ*/2 with the dimensionless reaction position λ* as the characteristic parameter. The validation experiments of CO2 absorption into the suspension was carried out in a thermostatic reactor and the enhancement factors were measured with different solids loadings at selected speeds. The results showed that the enhancement factor increased from 1.69 to 2.10 when the solids loadings varied from 5% to 30% (mass); and it changed sparingly from 1.75 to 1.80 as the stirred speed varied from 150 to 300 r·min-1. It revealed that the enhancement factors were controlled by the solids loading and dissolution rate of gypsum particles. The experimental data agreed well with the model prediction