MAO Shiyue, LIU Hanlan. Extraction of chlorophenols with imidazole-based hydrophobic ionic liquids[J]. CIESC Journal, 2015, (S1): 260-264.DOI: 10.11949/j.issn.0438-1157.20150191.
1-Octyl-3- methyl imidazole hexafluorophosphate ([Omim]PF6) and 1-octyl-3-methyl imidazole tetrafluoroborate ([Omim]BF4) have been synthesized. Using 2-chlorophenol
4-chlorophenol
2
4-dichlorophenol and 2
4
6-trichlorophenol as reactants
Ultraviolet spectrum analysis (USA) as test method
ultrasonic oscillation as extraction method
the performance of extraction to different chlorophenols
the impact on extraction ratio by extraction temperature
time
phase ratio(VIL:VCP) and pH have been studied and the performance of reuse has also been discussed in this paper. It is concluded that the ionic liquids achieve the best condition with 15min
1:3(VIL:VCP) phase ratio
308 K and pH <5. Under the best condition
the extraction rates of [Omim]BF4 to 2-chlorophenol
4-chlorophenol
2
4-dichlorophenol
2
4
6-trichlorophenol are 97.60%
95.20%
99.40% and 87.20%
respectively. For [Omim]PF6
however
the extraction rates are 95.80%
92.20%
98.20% and 85.40%. The mechanism of extraction is also discussed in this essay. It is also showed that the extraction rate is rising with the increase of temperature by ultrasonic oscillation