HUO Jiangbo, WANG Xiaoyi, ZHAO Jingqiang, et al. Application of air sample tubes of ionic liquid[J]. CIESC Journal, 2015, (S1): 326-331.DOI: 10.11949/j.issn.0438-1157.20141891.
The semi-volatile organic compounds(SVOCs) in air can be enriched by ionic liquids. However
during the study of air sample tubes
fog and black phenomenon often appeared in the sample tubes. At the same time
analysis process was disturbed by high background values and impurity peak. To investigate the reasons above
1-methyl acetate-3-methyl imidazolium bis(trifluoromethanesulfonyl) imides was used to improve the air-sample tubes and a series of experiments were designed. And on the basis of the ionic liquid sample tubes reuse
the sorbent tubes were desorbed at 220℃ and 50 ml He·min-1 for 15 min. The vapors from the primary desorption were collected at 0℃ in the cold trap without sorbent. The cold trap was flash heated to 280℃ at 40℃·s-1 (temperature of 250℃ for the valve
no inlet split or outlet split) and the vapors were transferred via the heated transfer line (250℃) to the GC. The GC temperature program was 100℃ (held for 1 min) then increased at 10℃·min-1 to 200℃ and finally increased at 5℃·min-1 to 250℃ (held for 4 min). When the mesh of stainless steel substituted for glass fiber
the data indicates the mesh gives the better result.