强非共沸工质R134a/R23/R14汽液相平衡和压焓图的构建及应用

张庆庆; 张华; 娄江峰; 李佳; 赵巍; 王袭; 刘占杰

doi:10.11949/j.issn.0438-1157.20141676

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强非共沸工质R134a/R23/R14汽液相平衡和压焓图的构建及应用

热力学 | 更新时间：2025-11-26

- 强非共沸工质R134a/R23/R14汽液相平衡和压焓图的构建及应用
- Construction and application for VLE and pressure-enthalpy diagrams of R134a/R23/R14 zeotropic mixtures
- 化工学报 2015年66卷第7期页码：2387-2394
- 作者机构：
  
  1. 上海理工大学制冷与低温工程研究所,上海,200093
  2. 海尔集团技术研发中心,山东,青岛,266101
- 作者简介：
- 基金信息：
- DOI：10.11949/j.issn.0438-1157.20141676
  中图分类号： B657.3
- 网络首发：2015-07-05，
  
  纸质出版：2015-07-05
- 稿件说明：
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张庆庆, 张华, 娄江峰, 等. 强非共沸工质R134a/R23/R14汽液相平衡和压焓图的构建及应用[J]. 化工学报, 2015,66(7):2387-2394.

ZHANG Qingqing, ZHANG Hua, LOU Jiangfeng, et al. Construction and application for VLE and pressure-enthalpy diagrams of R134a/R23/R14 zeotropic mixtures[J]. CIESC Journal, 2015, 66(7): 2387-2394.
张庆庆, 张华, 娄江峰, 等. 强非共沸工质R134a/R23/R14汽液相平衡和压焓图的构建及应用[J]. 化工学报, 2015,66(7):2387-2394. DOI： 10.11949/j.issn.0438-1157.20141676.

ZHANG Qingqing, ZHANG Hua, LOU Jiangfeng, et al. Construction and application for VLE and pressure-enthalpy diagrams of R134a/R23/R14 zeotropic mixtures[J]. CIESC Journal, 2015, 66(7): 2387-2394. DOI： 10.11949/j.issn.0438-1157.20141676.

摘要

基于PR状态方程

分模块模拟计算了三级自动复叠制冷系统中R134a/R23/R14三元混合工质的热物理特性参数

得到非共沸混合工质的汽液平衡数据、两相组分

并利用干度计算焓熵值

构建了典型配比下混合工质的压焓图和汽液相平衡图。二元R134a/R23和R32/R134a混合工质的泡点压力和气相组分的计算值与实验测试值的误差分别小于1.3%、1.2%和1.0%、2.4%;三元R32/R125/R134a混合工质95%的计算值与实验值的偏差在±5%之内

表明该模型能满足工程计算需要。利用理论模型

结合实验系统

对R134a/R23/R14三级自动复叠制冷系统进行详细的组分等热物性分析

并在空间压焓图上进行了详细表述。

Abstract

The thermodynamic properties of R134a/R23/R14 ternary mixtures used in three-stage auto-cascade refrigeration systems were calculated based on the PR equation

and enthalpy and entropy were calculated by using dryness. The diagrams of pressure-enthalpy and VLE of R134a/R23/R14 mixture under the typical composition were given. The deviations of bubble pressure and vapor composition between simulation results and the experimental data were less than 1.3% and 1.2% for R134a/R23

1.0% and 2.4% for R32/R134a

respectively. The deviations of 95% calculated values of R32/R125/R134a were between ±5%. The simulation results could meet the requirements of engineering calculation. Based on the experiment

the thermodynamic properties of the auto-cascade refrigeration system were analyzed in detail. The pressure-enthalpy diagrams of R134a/R23

R23/R14 and R134a/R23/R14 under the operating compositions were given

and the diagram of spatial pressure-enthalpy described the circle of this system clearly. This simulation program could analyze the system circle effectively.

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